Polypropylene resin composition and formed article
Disclosed is a polypropylene resin composition including: 100 parts by weight of (A) a propylene-based block copolymer including polymer components (I) and (II), wherein the polymer component (I) is a propylene polymer having an intrinsic viscosity [η] I of 0.1-5 dl/g, the polymer component (II) is a propylene polymer comprising propylene units and units of at least one comonomer selected from the group consisting of ethylene and α-olefins having 4-12 carbon atoms and having an intrinsic viscosity [η] II of from 1-20 dl/g and the content of the polymer component (II) is 1-70% by weight; and 0.001-5 parts by weight of (B) a nucleating agent composed of particles having an average particle diameter, as measured by the laser diffraction method, of 0.01-3 mm wherein particles having particle diameters of not less than 10 mm account for less than 5% by weight of all the particles of the nucleating agent.
1. A polypropylene resin composition comprising:
(A) a propylene-based block copolymer satisfying requirements (a), (b), (c) and (d) defined below, and
(B) from 0.01 to 1.0 part by weight, based on 100 parts by weight of (A), of aluminum hydroxy-di-(p-tert-butylbenzoate) particles having an average particle diameter, as measured by the laser diffraction method, of from 0.01 to 3 μm wherein particles having particle diameters of not less than 10 μm account for less than 5% by weight of all the particles of aluminum hydroxy-di-(p-tert-butylbenzoate);
requirement (a): propylene-based block copolymer (A) is a propylene-based block copolymer including a polymer component (I) and a polymer component (II), wherein the polymer component (I) is a propylene polymer having an intrinsic viscosity as measured in Tetralin at 135° C., of from 0.1 to 5 dl/g and the polymer component (II) is a propylene polymer comprising propylene units and units of at least one comonomer selected from the group consisting of ethylene and α-olefins having 4-12 carbon atoms and having an intrinsic viscosity [η] II , as measured in Tetralin at 135° C., of from 1 to 20 dl/g,
requirement (b): the polymer component (I) has an isotactic pentad fraction, as measured by 13 C-NMR, of 0.98 or more,
requirement (c): the content of the units derived from at least one comonomer selected from the group consisting of ethylene and α-olefins having 4-12 carbon atoms included in the polymer component (II) is from 1 to 80% by weight, provided that the overall amount of the polymer component (II) is 100% by weight, and
requirement (d): the content of the polymer component (II) is from 1 to 70% by weight, provided that the weight of the propylene-based block copolymer (A) is 100% by weight,
wherein the polymer component (I) is a propylene-based polymer component composed of from 0.01 to 30% by weight, based on the overall amount of the polymer component (I), of units derived from at least one comonomer selected from the group consisting of ethylene and α-olefin having 4-12 carbon atoms and units derived from propylene and the content of 20° C. xylene-soluble component in the polymer component (I) less than 1.0% by weight.
2. The polypropylene resin composition according to claim 1 , wherein in the propylene-based block copolymer (A) the ratio of the intrinsic viscosity [η] II of the polymer component (II) to the intrinsic viscosity [η] I of the polymer component (I) is from 1 to 20 and the content of the polymer component (II) is from 10 to 50% by weight and wherein the propylene-based block copolymer (A) has a melt flow rate, as measured at 230° C., of from 0.1 to 400 g/10 min.
3. A formed article made from the polypropylene resin composition according to claim 1 .
4. A formed article made from the polypropylene resin composition according to claim 2 .
5. The polypropylene resin composition according to claim 1 , wherein the content of the aluminum hydroxy-di-(p-tert-butylbenzoate) particles (B) is from 0.01 to 0.5 parts by weight based on 100 parts by weight of the propylene-based block copolymer (A).
6. A formed article made from the propylene resin composition according to claim 5 .