Photothermographic material and image forming method
A photothermographic material comprising, at least an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on at least one side of a support, wherein a content of AgI in the photosensitive silver halide is 5% by mole or more, the binder contains polymer latex in an amount of 60% by weight or more, and the reducing agent is represented by the following formula (R): wherein R 11 and R 11′ each independently represent an alkyl group having 1 to 20 carbon atoms, R 12 , R 12′ , X1 and X1 1 each independently represent a hydrogen atom or a substituent, L represents a —S— group or a —CHR 13 — group, and R 13 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms.
1 . A photothermographic material comprising, at least an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on at least one side of a support, wherein a content of silver iodide in the photosensitive silver halide is 5% by mole or more, the binder contains polymer latex in an amount of 60% by weight or more, and the reducing agent is a compound represented by the following formula (R):
wherein R 11 and R 11′ each independently represent an alkyl group having 1 to 20 carbon atoms, R 12 and R 12′ each independently represent a hydrogen atom or a group capable of substituting for a hydrogen on a benzene ring, L represents a —S— group or a —CHR 13 — group, R 13 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and X1 and X1 1 each independently represent a hydrogen atom or a group capable of substituting for a hydrogen on a benzene ring.
2 . The photothermographic material according to claim 1 , wherein the polymer latex is a polymer having a glass transition temperature of −20° C. to 60° C.
3 . The photothermographic material according to claim 1 , wherein the polymer latex contains a styrene-butadiene copolymer.
4 . The photothermographic material according to claim 1 , wherein the binder contains polymer latex copolymerized using 10% by weight to 70% by weight of the monomer represented by the following formula (M):
CH 2 ═CR 01 —CR 02 ═CH 2 Formula (M)
wherein R 01 and R 02 are each independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom or a cyano group, provided that R 01 and R 02 are not both hydrogen atoms.
5 . The photothermographic material according to claim 4 , wherein, in formula (M), R 01 is a hydrogen atom and R 02 is a methyl group.
6 . The photothermographic material according to claim 4 , wherein the polymer latex is copolymerized using 1% by weight to 20% by weight of a monomer having an acidic group.
7 . The photothermographic material according to claim 4 , wherein a glass transition temperature of the polymer latex is −30° C. to 70° C.
8 . The photothermographic material according to claim 4 , wherein a glass transition temperature of the polymer latex is −10° C. to 35° C.
9 . The photothermographic material according to claim 4 , wherein the polymer latex contains a halogen ion in the latex solution in an amount of 500 ppm or less thereof.
10 . The photothermographic material according to claim 4 , wherein the polymer latex is a styrene-isoprene copolymer latex.
11 . The photothermographic material according to claim 1 , wherein R 11 and R 11′ are each independently a secondary or a tertiary alkyl group having 3 to 15 carbon atoms, in the reducing agent represented by formula (R).
12 . The photothermographic material according to claim 1 , further comprising a development accelerator.
13 . The photothermographic material according to claim 12 , wherein the development accelerator contains a compound represented by the following formula (A-1):
Q 1 -NHNH-Q 2 Formula (A-1)
wherein Q 1 is an aromatic group bonding to —NHNH-Q 2 via a carbon atom, or is a heterocyclic group; and Q 2 is a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group, or a sulfamoyl group.
14 . The photothermographic material according to claim 12 , wherein the development accelerator contains a compound represented by the following formula (A-2):
wherein R 1 represents an alkyl group, an acyl group, an acylamino group, a sulfonamide group, an alkoxycarbonyl group, or a carbamoyl group; R 2 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyloxy group, or a carbonic ester group; and R 3 and R 4 each independently represent a hydrogen atom or a group which can be substituted for a hydrogen on the benzene ring 4 , and may join to each other to form a naphthalene ring.
15 . The photothermographic material according to claim 1 , further comprising an organic polyhalogen compound as an antifoggant.
16 . The photothermographic material according to claim 15 , wherein the organic polyhalogen compound is represented by the following formula (H):
Q-(Y) n —C(Z 1 )(Z 2 )X Formula (H)
wherein Q is an alkyl group, an aryl group, or a heterocyclic group;, Y is a divalent linking group; n is 0 or 1; Z 1 and Z 2 are each a halogen atom; and X is a hydrogen atom or an electron attractive group.
17 . The photothermographic material according to claim 1 , wherein the content of the silver iodide in the photosensitive silver halide is 40% by mole or more.
18 . The photothermographic material according to claim 1 , wherein an average grain size of the photosensitive silver halide is 5 nm to 80 nm.
19 . The photothermographic material according to claim 1 , wherein an average grain size of the photosensitive silver halide is 5 nm to 40 nm.
20 . The photothermographic material according to claim 1 , wherein the photosensitive silver halide is formed in the absence of the non-photosensitive organic silver salt.
21 . The photothermographic material according to claim 1 , further containing a compound that can be one-electron-oxidized to provide a one-electron oxidation product which releases one or more electrons.
22 . An image forming method using the photothermographic material according to claim 1 , wherein the photothermographic material is exposed by scanning with a laser beam.
23 . The image forming method according to claim 22 , wherein the laser is emitted from a laser diode.
24 . The image forming method according to claim 23 , wherein the laser diode has a peak strength in a wavelength of 350 nm to 440 nm, and has an intensity of 1 mW/mm 2 to 50 W/mm 2 .
25 . The image forming method according to claim 23 , wherein the laser diode has a peak strength in a wavelength of 380nm to 410 nm.
26 . The photothermographic material according to claim 1 , wherein the silver iodide content of the photosensitive silver halide is 80% by mole or more.
27 . The photothermographic material according to claim 1 , wherein the silver iodide content of the photosensitive silver halide is 90% by mole or more.
28 . The photothermographic material according to claim 14 , wherein the R 3 and R 4 in the formula (A-2) join to each other to form a naphthalene ring.
29 . The photothermographic material according to claim 14 , wherein the R 1 is a carbamoyl group.