IP Library Granted Patent US 7,465,819
Granted Patent B2
US 7,465,819 · App. 11/337,441 · Granted Dec 16, 2008

Bisbiphenylacylphosphine oxide and preparation method therefore

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Quick Facts
Patent No.
US 7,465,819
App. No.
11/337,441
Granted
Dec 16, 2008
Kind
B2
Abstract

A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.

Claims (3)

1. A bisbiphenylacylphosphine oxide represented by the following structural formula (I):

wherein —Ar— is a phenyl group.

2. The bisbiphenylacylphosphine oxide of claim 1 wherein the phenyl group is selected from the group consisting of a

Assignments (1)
CHANGE OF NAME Recorded Apr 17, 2015
From: CHUNG-SHAN INSTITUTE OF SCIENCE AND TECHNOLOGY
To: NATIONAL CHUNG SHAN INSTITUTE OF SCIENCE AND TECHNOLOGY
Reel/Frame 035453/0240 →