Room temperature curable organopolysiloxane compositions
An RTV organopolysiloxane composition is provided comprising (A) an organopolysiloxane having the formula: HO(R 1 2 SiO) x H wherein R 1 is a monovalent hydrocarbon group and x is an integer of at least 10, (B) an alkoxysilane compound having on the average at least two silicon-bonded hydrolyzable groups and/or a partial hydrolyzate thereof, (C) organoxy titanium, and (D) an organic compound having at least one hydroxyl group bonded to a benzene ring. The color of the composition tinted with components (C) and (D) fades or changes upon curing of the composition, by which a degree of curing is visually observable. The composition has improved storage stability and resin adhesion.
1 . A room temperature curable organopolysiloxane composition comprising
(A) 100 parts by weight of at least one organopolysiloxane selected from the group consisting of an organopolysiloxane having the general formula (1):
HO(R 1 2 SiO) x H (1)
wherein R 1 is each independently a substituted or unsubstituted monovalent hydrocarbon group and x is an integer of at least 10, an organopolysiloxane having the general formula (2):
wherein R 1 and x are as defined above, Me is methyl, Y is an oxygen atom or an alkylene group of 1 to 5 carbon atoms, and n is independently an integer of 0 or 1, and an organopolysiloxane having the general formula (3):
wherein R 1 , Me, Y and n are as defined above, R 2 is a branch chain containing a hydrolyzable group having the general formula (4):
—Y—Si(OMe) 3-n (4)
wherein Y, Me and n are as defined above, x′ is an integer of at least 9, z is an integer of at least 1, and x′+z=x,
(B) 0.1 to 20 parts by weight of an alkoxysilane compound having on the average at least two silicon-bonded hydrolyzable groups per molecule or a partial hydrolyzate thereof or a mixture thereof,
(C) 0.5 to 15 parts by weight of an organoxy titanium having the general formula (5):
Ti(OR 3 ) 4 (5)
wherein R 3 is each independently a monovalent hydrocarbon group of 2 to 10 carbon atoms,
(D) 0.01 to 10 parts by weight of an organic compound having at least one hydroxyl group bonded to a benzene ring per molecule, and
(E) 0 to 10 parts by weight of a silane coupling agent,
wherein the color of the composition tinted with components (C) and (D) fades or changes upon curing of the composition, by which a degree of curing is visually observable.
2 . The composition of claim 1 , wherein component (D) is a phenol, cresol or hydroquinone.
3 . The composition of claim 1 , further comprising (F) 1 to 500 parts by weight of at least one filler.
4 . The composition of claim 1 , further comprising (G) an inert silicone fluid.