Process for the oxidative purification of terephthalic acid

1. A process to produce a purified carboxylic acid composition said process comprising:

(a) oxidizing an aromatic feedstock in a primary oxidation zone to form a crude carboxylic acid slurry;

(b) oxidizing said crude carboxylic acid slurry in a staged oxidation zone to form a staged oxidation composition; wherein said staged oxidation zone comprises at least one staged oxidation reactor operated at a temperature of about 150° C. to about 280° C.;

(c) crystallizing in a crystallization zone said staged oxidation composition to form a crystallized composition;

(d) removing in a solid liquid displacement zone impurities from said crystallized composition to form said purified carboxylic acid slurry; wherein said impurities comprise 4-carboxybenzaldehyde, trimellitic acid, and 2,6-dicarboxyfluorenone; wherein said solid liquid displacement zone comprises a solid liquid separator that is operated at a temperature between 110° C. and 200° C.;

(e) cooling said purified carboxylic acid slurry in a cooling zone to form a cooled purified carboxylic acid slurry; and

(f) filtering and drying said cooled purified carboxylic slurry in a filtration and drying zone to produce said purified carboxylic acid composition.

2. The process according to claim 1 wherein said solid liquid displacement zone comprises a solid liquid separator that is operated at a temperature between about 110° C. to about 200° C.

3. The process according to claim 1 wherein said crude carboxylic acid slurry comprises terephthalic acid, catalyst, and acetic acid; wherein said catalyst comprises cobalt compounds, manganese compounds, and bromine compounds.

4. The process according to claim 1 wherein said solid liquid displacement zone comprises a solid liquid separator selected from the group consisting of a belt filter, a rotary vacuum filter and a rotary disk pack centrifuge.

5. The process according to claim 1 wherein said purified carboxylic acid slurry has a b* of less than about 3.5.

6. The process according to claim 1 further comprising the step of flash cooling said purified carboxylic acid slurry to form said cooled purified carboxylic acid slurry.

7. The process according to claim 1 wherein said staged oxidation reactor is operated at a temperature of about 190° C. to about 280° C.

8. A process to produce a purified carboxylic acid composition said process comprising:

(a) oxidizing an aromatic feedstock in a primary oxidation zone to form a crude carboxylic acid slurry;

(b) oxidizing said crude carboxylic acid slurry in a staged oxidation zone to form a staged oxidation composition; wherein said staged oxidation zone comprises at least one staged oxidation reactor operated at a temperature of about 150° C. to about 280° C.;

(c) removing in a solid liquid displacement zone impurities from said staged oxidation composition to form a purified carboxylic acid slurry; wherein said impurities comprise 4-carboxybenzaldehyde, trimellitic acid, and 2,6-dicarboxyfluorenone; wherein said solid liquid displacement zone comprises a solid liquid separator that is operated at a temperature between 110° C. and 200° C.;

(d) crystallizing in a crystallization zone said staged oxidation composition to form a crystallized composition;

(e) cooling said crystallized composition in a cooling zone to form a cooled purified carboxylic acid slurry; and

(f) filtering and drying said cooled purified carboxylic acid slurry in a filtration and drying zone to produce said purified carboxylic acid composition.

9. The process according to claim 8 wherein said crude carboxylic acid slurry comprises terephthalic acid, catalyst, and acetic acid; wherein said catalyst comprises cobalt compounds, manganese compounds, and bromine compounds.

10. The process according to claim 8 wherein said solid liquid displacement zone comprises a solid liquid separator selected from the group consisting of a belt filter, a rotary vacuum filter and a rotary disk pack centrifuge.

11. The process according to claim 8 wherein said purified carboxylic acid slurry is formed without a process for separating impurities from oxidation solvent or hydrogenation step.

12. The process according to claim 8 wherein said purified carboxylic acid slurry has a b* of less than about 3.5.

13. The process according to claim 8 further comprising the step of flash cooling said purified carboxylic acid slurry to form a cooled purified carboxylic acid slurry.

14. The process according to claim 8 wherein said staged oxidation reactor is operated at a temperature of about 190° C. to about 280° C.

15. A process to produce a purified carboxylic acid composition comprising:

(a) oxidizing an aromatic feedstock in a primary oxidation zone to form a crude carboxylic acid slurry; wherein said oxidizing is conducted at a temperature between about 110° C. to about 200° C.;

(b) oxidizing said crude carboxylic acid slurry in a staged oxidation zone to form a staged oxidation composition; wherein said oxidizing is conducted at a temperature between about 150° C. to about 280° C.; and wherein said oxidizing is at a higher temperature in said staged oxidation zone than in said primary oxidation zone;

(c) crystallizing said staged oxidation composition in a crystallization zone to form a crystallized composition;

(d) removing in a solid liquid displacement zone impurities from said crystallized composition to form said purified carboxylic acid slurry; wherein said solid liquid displacement zone comprises a solid liquid separator that is operated at a temperature between about 110° C. to about 200° C.; wherein said impurities comprise 4-carboxybenzaldehyde, trimellitic acid, and 2,6-dicarboxyfluorenone;

(b) cooling said purified carboxylic acid slurry in a cooling zone to form a cooled purified carboxylic acid slurry; and

(c) filtering and drying said cooled purified carboxylic acid slurry in a filtration and drying zone to produce said purified carboxylic acid composition.

16. The process according to claim 15 further comprising the step of flash cooling said purified carboxylic acid slurry to form a cooled purified carboxylic acid slurry.

17. The process according to claim 1 , 8 or 15 further comprising decolorizing in a reactor zone said purified carboxylic acid slurry or a carboxylic acid that has been esterified.

18. The process according to claim 15 wherein said staged oxidation zone comprises at least one staged oxidation reactor operated at a temperature of about 190° C. to about 280° C.