IP Library Granted Patent US 7,485,280
Granted Patent B2
US 7,485,280 · App. 11/346,437 · Granted Feb 3, 2009

Carbon black

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Quick Facts
Patent No.
US 7,485,280
App. No.
11/346,437
Granted
Feb 3, 2009
Kind
B2
Abstract

To provide carbon black which improves the electrical conductivity and flowability of a resin composition. Carbon black characterized by having the following characteristics: 24M4DBP absorption: At least 130 cm 3 /100 g (1,500° C.×30 min) dehydrogenation amount: At most 1.2 mg/g Crystallite size Lc: From 10 to 17 Å More preferably, it has the following characteristics: Nitrogen adsorption specific surface area: from 150 to 300 m 2 /g Average particle diameter: from 14 to 24 nm CTAB adsorption specific surface area: from 120 to 220 m 2 /g DBP absorption: from 150 to 400 cm 3 /100 g Oxygen-containing functional group density: at most 3 μmol/m 2 .

Claims (15)

1. Carbon black, which has:

(a) a 24M4DBP absorption of at least 131 cm 3 /100 g;

(b) a (1,500° C.×30 min) dehydrogenation amount of at most 1.2 mg/g;

(c) a crystallite size Lc of from 10 to 17 Å;

(d) a nitrogen adsorption specific surface area of from 150 to 300 m 2 /g;

(e) a ratio of the Stokes mode diameter, D mod , in nm, to the 24M4DBP absorption, in cm 3 /100 g, of from 0.6 to 0.9 nm·100 g/cm 3 ; and

(f) an average particle diameter as measured by a transmission electron microscope of from 14 to 24 nm.

2. The carbon black according to claim 1 , which has a CTAB (cetyltrimethylammonium bromide) adsorption specific surface area of from 120 to 220 m 2 /g.

3. The carbon black according to claim 1 , which has a DBP absorption of from 150 to 400 cm 3 /100 g.

4. The carbon black according to claim 1 , which has an oxygen-containing functional group density of at most 3 μmol/m 2 , wherein said oxygen-containing functional group density is defined by the following formula:

Oxygen-containing functional group density (μmol/m 2 )=[(1,500° C.×30 min) CO generation (μmol/g)+(1,500° C.×30 min) CO 2 generation (μmol/g)]/nitrogen adsorption specific surface area (m 2 /g).

5. The carbon black according to claim 1 , which is oil furnace carbon black.

6. The carbon black according to claim 1 , which has a 24M4DBP absorption of at least 130 cm 3 /100 g.

7. The carbon black according to claim 1 , which has a 24M4DBP absorption of at least 140 cm 3 /100 g.

8. The carbon black according to claim 1 , which has a nitrogen adsorption specific surface area of from 200 to 290 m 2 /g.

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 5, 2006
From: MATSUKI, AKIHIRO; KANAMARU, SHINICHI; FUKUYAMA, YUTAKA; MISE, NOBUTAKE; TAKAMURA, EIHACHI
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 017875/0955 →