Conductive organic/inorganic composite composition and organic electroluminescent device comprising the same

1. An organic electroluminescent device, comprising:

a substrate;

an anode on a substrate;

a hole injection layer on the anode;

a hole transport layer on the hole injection layer;

an emission layer on the hole transport layer; and

a cathode on the emission layer;

wherein at least one of the anode, the hole injection layer, the hole transport layer and the cathode comprises a conductive organic/inorganic complex film formed from a conductive organic/inorganic complex composition, the conductive organic/inorganic complex composition comprising;

a conductive polymeric monomer;

an oxidizing agent;

a first alcohol solvent; and

a silica sol solution comprising an organosilicon compound, water, an acid catalyst, and a second alcohol solvent.

2. The organic electroluminescent device of claim 1 , wherein the first alcohol solvent and the second alcohol solvent are the same.

3. The organic electroluminescent device of claim 1 , wherein the conductive polymeric monomer include at least one compound selected from the group consisting of 3,4-ethylenedioxythiophen (EDOT), thiophen, aniline, pyrrole and a derivative thereof.

4. The organic electroluminescent device of claim 1 , wherein the oxidizing agent include at least one compound selected from the group consisting of iron chloride (FeCl 3 ), iron perchlorate (Fe(ClO 4 ) 3 ), ferric toluenesulfonate, ferric dodecyl bezenesulfonate, ferric anthraquinone sulfonate, and ammonium persulfate.

5. The organic electroluminescent device of claim 1 , wherein the organosilicon compound has formula 1:

SiR 1 ×R 2 4-X   (1)

wherein R 1 radicals are each independently a hydrogen atom, a fluorine atom, aryl, vinyl, allyl, or an unsubstituted or fluorine-substituted linear or branched C1-4 alkyl, R 2 radicals are each independently acetoxy, hydroxy, or a linear or branched C1-4 alkoxy, and x is an integer from 0 to 2.

6. The organic electroluminescent device of claim 1 , wherein the acid catalyst include at least one compound selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, hydrofluoric acid, formic acid, and acetic acid.

7. The organic electroluminescent device of claim 1 , the first alcohol solvent and the second alcohol solvent include at least one compound selected from the group consisting of n-butanol, isopropanol, ethanol, and methanol.

8. The organic electroluminescent device of claim 1 , further comprising at least one oxidation stabilizer selected from the group consisting of imidazole, dicyanohexylamine, and 1,8-diazabicyclo[5,4,0]undec-7-en (DBU).

9. The organic electroluminescent device of claim 1 , wherein a molar ratio of the conductive polymeric monomer and the organosilicon compound is 1:0.01 to 1:100.

10. The organic electroluminescent device of claim 1 , wherein a molar ratio of the conductive polymeric monomer and the oxidizing agent is 1:0.01 to 1:100.

11. The organic electroluminescent device of claim 1 , wherein the concentration of the water in the silica sol solution is 0.5 to 100 mol per mol of silicon atom.

12. The organic electroluminescent device of claim 1 , wherein the conductive organic/inorganic complex film is prepared by forming a coat of the conductive organic/inorganic complex composition and thermally polymerizing the coat.

13. The organic electroluminescent device of claim 12 , wherein the thermal polymerization is performed at 0-200° C.

14. The organic electroluminescent device of claim 12 , wherein the conductive organic/inorganic complex film has a conductivity of 10 −8 to 10 5 S/cm.

15. An organic electroluminescent device comprising:

a conductive organic/inorganic complex film prepared by forming a coat of a conductive organic/inorganic complex composition and thermally polymerizing the coat, the conductive organic/inorganic complex composition comprising;

a conductive polymeric monomer;

an oxidizing agent;

a first alcohol solvent; and

a silica sol solution comprising an organosilicon compound, water, an acid catalyst, and a second alcohol solvent.

16. The organic electroluminescent device of claim 15 , wherein at least one selected from the group consisting of an anode electrode, a hole injection layer, a hole transport layer, a charge transport layer, a charge injection layer, and a cathode electrode comprises the conductive organic/inorganic complex film.

17. A method of preparing an organic electroluminescent device, comprising:

forming an anode electrode on a substrate;

forming a hole injection layer on the anode electrode;

forming a hole transport layer on the hole injection layer;

forming an emission layer on the hole transport layer; and

forming a cathode electrode on the emission layer,

wherein at least one selected from the group consisting of the anode electrode, the hole injection layer, the hole transport layer, and the cathode electrode comprises a conductive organic/inorganic complex film prepared by coating a conductive organic/inorganic complex composition and thermally polymerizing the coating, the conductive organic/inorganic complex composition comprising a conductive polymeric monomer, an oxidizing agent, a first alcohol solvent, and a silica sol solution comprising an organosilicon compound, water, an acid catalyst, and a second alcohol solvent.

18. The method of claim 17 , further comprising exposing the conductive organic/inorganic complex film to light to decrease a conductivity of the conductive organic/inorganic complex film.

19. A method of preparing an organic electroluminescent device, comprising:

preparing a conductive organic/inorganic complex composition, the preparation comprising:

obtaining a silica sol solution by mixing an organosilicon compound, water, an acid catalyst, and a first alcohol solvent; and

mixing the silica sol solution with a mixed solution comprising a conductive polymeric monomer, an oxidizing agent, and an second alcohol solvent;

forming a coat of the conductive organic/inorganic complex composition; and

thermally polymerizing the coat.

20. The method of claim 19 , wherein the first alcohol solvent and the second alcohol solvent are the same.

21. The method of claim 19 , wherein the silica sol solution is obtained by reacting the organosilicon compound, the water, the acid catalyst, and the second alcohol solvent at 0 to 100° C.