Silver halide emulsion and silver halide photographic light-sensitive material
View Patent ↗A silver halide emulsion, which is chemically sensitized by a compound of formula (1): wherein Ch represents a sulfur, selenium, or tellurium atom; X 1 represents NR 1 or N + (R 2 )R 3 Y − ; R 1 represents a hydrogen atom or a substituent; R 2 and R 3 each represent an alkyl group or another substituent; Y − represents an anionic ion; X 2 represents OR 4 , N(R 5 )R 6 , or another substituent; R 4 to R 6 each represent a hydrogen atom or a substituent; and E is a group selected from groups represented by formula (2) to (5): wherein, in formulas (2) to (5), Z represents a hydrogen atom or a substituent; A 1 and A 2 each represent an oxygen atom, etc.; and R 10 to R 16 each represent a hydrogen atom or a substituent; W represents a substituent; n is an integer from 0 to 4; L represents a divalent linking group; and EWG represents an electron withdrawing group.
1. A silver halide emulsion, which is chemically sensitized by a compound represented by formula (I):
wherein, in formula (1), Ch represents a sulfur atom, a selenium atom, or a tellurium atom; X 1 represents NR 1 , or N + (R 2 )R 3 Y − , in which R 1 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group, and R 2 and R 3 each independently represent an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group, and Y − represents an anionic ion; X 2 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, OR 4 , or N(R 5 )R 6 , in which R 4 , R 5 , and R 6 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group; and E is a group selected from groups represented by formula (2), (3), (4), or (5):
wherein, in formula (2), Z represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, OR 7 , or N(R 8 )R 9 , in which R 7 , R 8 , and R 9 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group;
wherein, in formula (3), A 1 represents an oxygen atom, a sulfur atom, or NR 13 ; and R 10 , R 11 , R 12 , and R 13 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group;
wherein, in formula (4), A 2 represents an oxygen atom, a sulfur atom, or NR 17 ; R 14 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or an acyl group; R 15 , R 16 , and R 17 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group; W represents a substituent; n is an integer from 0 to 4; when n is 2 or more, Ws may be the same or different; and
wherein, in formula (5), L represents a divalent linking group; and EWG represents an electron withdrawing group.
2. The silver halide emulsion as claimed in claim 1 , X 2 represents N(R 5 )R 6 .
3. The silver halide emulsion as claimed in claim 2 , wherein E is a group selected from the groups represented by formula (3) or (4).
4. The silver halide emulsion as claimed in claim 3 , wherein Ch is a selenium atom.
5. The silver halide emulsion as claimed in claim 1 , wherein X 1 represents NR 1 .
6. The silver halide emulsion as claimed in claim 1 , wherein, in formula (1), Ch is a sulfur atom or a selenium atom; X 1 represents NR 1 or N + (R 2 )R 3 ; X 2 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, OR 4 , or N(R 5 )R 6 ; and E is selected from the groups represented by formula (3) or (4).
7. The silver halide emulsion as claimed in claim 1 , wherein the compound represented by formula (1) is used in an amount of 1×10 −7 to 5×10 −3 mol per mol of silver halide.
8. The silver halide emulsion as claimed in claim 1 , which is further sensitized by a gold sensitizer.
9. The silver halide emulsion as claimed in claim 1 , which comprises silver halide grains composed of cubic, tetradecahedral, or octahedral crystal grains, substantially having (100) planes, which grains may be rounded at the apexes thereof and may have planes of higher order, and wherein the proportion of said silver halide grains accounts for 50% or more in terms of the total projected area of all the silver halide grains contained in the emulsion.
10. The silver halide emulsion as claimed in claim 9 , wherein a silver chloride content of the silver halide emulsion is 95% or more.
11. The silver halide emulsion as claimed in claim 1 , which comprises silver halide grains composed of tabular grains having an aspect ratio of 2 or more and being composed of (100) or (111) planes as the main face, and wherein the proportion of said silver halide grains accounts for 50% or more in terms of the total projected area of all the silver halide grains contained in the emulsion.
12. The silver halide emulsion as claimed in claim 11 , wherein the tabular grains are silver iodobromide or chloroiodobromide tabular grains.
13. A silver halide photographic light-sensitive material having, on a support, at least one silver halide emulsion layer, wherein at least one layer of said at least one silver halide emulsion layer contains the silver halide emulsion according to claim 1 .