IP Library Patent Application 11357013
Patent Application
App. No. 11/357,013

Photothermographic material

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Quick Facts
Patent No.
US None
App. No.
11/357,013
Abstract

A photothermographic material including, on a support, at least two image forming layers each including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, wherein the image forming layers have spectral sensitivities that are different from each other, at least one layer of the image forming layers is a silver image forming layer which forms an image substantially constituted by a silver image, and at least one other layer of the image forming layers is a color image forming layer including a color image forming material. A photothermographic material which records a composite image made up of a silver image and a color image of different kinds of image information is provided. Particularly, a photothermographic material capable of forming a fusion image useful as a medical diagnosis image is provided.

Claims (18)

1 . A photothermographic material comprising, on a support, at least two image forming layers each comprising at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, wherein the image forming layers have spectral sensitivities that are different from each other, at least one layer of the image forming layers is a silver image forming layer which forms an image substantially constituted by a silver image, and at least one other layer of the image forming layers is a color image forming layer comprising a color image forming material.

2 . The photothermographic material according to claim 1 , wherein the color image forming material is a coupler which reacts with an oxidation product of the reducing agent to form a dye.

3 . The photothermographic material according to claim 1 , wherein the reducing agent contained in the silver image forming layer and the reducing agent contained in the color image forming layer are different from each other.

4 . The photothermographic material according to claim 3 , wherein the reducing agent contained in the silver image forming layer comprises a compound represented by the following formula (R):

wherein R 11 and R 11′ each independently represent an alkyl group having 1 to 20 carbon atoms; R 12 and R 12′ each independently represent a hydrogen atom or a group substituting for a hydrogen atom on a benzene ring; L represents an —S— group or a —CHR 13 — group; R 13 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; and X 1 and X 1′ each independently represent a hydrogen atom or a group substituting for a hydrogen atom on a benzene ring.

5 . The photothermographic material according to claim 3 , wherein the reducing agent contained in the color image forming layer comprises a compound represented by the following formula (I):

herein R 1 , R 2 , R 3 and R 4 each independently represent a hydrogen atom or a substituent; R 5 and R 6 each independently represent one selected from an alkyl group, an aryl group, a heterocyclic group, an acyl group, or a sulfonyl group; members in at least one combination of R 1 and R 2 , R 3 and R 4 , R 5 and R 6 , R 2 and R 5 , and R 4 and R 6 may bond to each other to form a 5-, 6-, or 7-membered ring; R 7 represents R 11 —O—CO—, R 12 —CO—CO—, R 13 —NH—CO—, R 14 —SO 2 —, R 15 —W—C(R 16 )(R 17 )—, R 19 —SO 2 NHCO—, R 20 —CONHCO—, R 21 —SO 2 NHSO 2 —, R 22 —CONHSO 2 —, or (M) 1/n OSO 2 —; R 11 , R 12 , R 13 , R 14 , R 19 , R 20 , R 21 , and R 22 each independently represent one selected from an alkyl group, an aryl group, or a heterocyclic group; R 15 represents a hydrogen atom or a block group; W represents an oxygen atom, a sulfur atom, or —N(R 18 )—; R 16 , R 17 and R 18 each independently represent one selected from a hydrogen atom or an alkyl group; and M represents a cation having a valency of n.

6 . The photothermographic material according to claim 5 , wherein R 7 in formula (I) represents R 11 —O—CO— or R 19 —SO 2 NHCO—.

7 . The photothermographic material according to claim 3 , wherein the reducing agent contained in the color image forming layer is a compound represented by the following formula (II):

wherein R 101 and R 102 each independently represent a substituted or unsubstituted alkyl group, aryl group, heterocyclic group, acyl group, alkylsulfonyl group, or arylsulfonyl group; R 103 , R 104 , R 105 , R 106 , and R 107 each independently represent a hydrogen atom or a substituent; members in at least one combination of R 101 and R 102 , R 103 and R 104 , R 105 and R 106 , and R 107 and X may bond to each other to form a 5-, 6-, or 7-membered ring; X represents a halogen atom or a substituent having a heteroatom through which the substituent bonds to the benzene ring; n represents an integer of from 0 to 4; and when n represents 2 or more, a plurality of R 107 may be the same or different from one another and may bond to each other to form a 5-, 6-, or 7-membered ring.

8 . The photothermographic material according to claim 3 , wherein the reducing agent contained in the color image forming layer is a compound represented by the following formula (III):

wherein R 201 , R 202 , and R 203 each independently represent a hydrogen atom or a substituent; R 204 represents one selected from an alkyl group, an aryl group, or a heterocyclic group; members in at least one combination of R 201 and R 202 , and R 202 and R 204 may bond to each other to form a 5-, 6-, or 7-membered ring; Z represents a non-metallic atomic group for forming a 5-, 6-, or 7-membered ring together with a nitrogen atom and two carbon atoms in a benzene ring; R 205 represents one selected from an alkyl group, an aryl group, or a heterocyclic group; and no hydroxy group, carboxy group, or sulfo group is contained in any of R 201 to R 204 .

9 . The photothermographic material according to claim 8 , wherein R 205 in formula (III) is a group represented by the following formula (IV):

wherein X represents a halogen atom or a group which substitutes for a hydrogen atom on a benzene ring through a heteroatom; R 206 represents a substituent; n represents an integer of from 0 to 4; and when n represents 2 or more, a plurality of R 206 may be the same or different from one another, and two adjacent groups thereamong may bond to each other to form a 5-, 6-, or 7-membered carbon ring or heterocycle.

10 . The photothermographic material according to claim 1 , wherein the binder of the silver image forming layer comprises a polymer latex.

11 . The photothermographic material according to claim 1 , wherein the binder of the color image forming layer comprises a polymer latex.

12 . The photothermographic material according to claim 1 , wherein the photothermographic material comprises the silver image forming layer on one side of the support and the color image forming layer on the other side of the support.

13 . The photothermographic material according to claim 1 , wherein the silver image forming layer and the color image forming layer are disposed on the same side of the support.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2007
From: FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO. LTD.)
To: FUJIFILM CORPORATION
Reel/Frame 019331/0493 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 21, 2006
From: OHZEKI, TOMOYUKI
To: FUJI PHOTO FILM CO., LTD.
Reel/Frame 017597/0527 →