Coatings having low volatile organic compound content
View Patent ↗The present invention provides a method of making an aqueous coating composition comprising an aqueous dispersion of an epoxy acrylate resin and a polymerized reactive diluent. The aqueous coating composition preferably has a volatile organic compound content of no greater than 0.4 kilogram per liter of solids.
1. A coating composition comprising an interpenetrating polymer network, of a polymerized reactive diluent and an epoxy acrylate resin, dispersed in water;
the coating composition prepared by the steps comprising: dispersing a reactive diluent and said epoxy acrylate resin in water; and subsequently polymerizing the reactive diluent in the presence of the epoxy acrylate resin, yielding said interpenetrating polymer network dispersed in water;
wherein the epoxy acrylate resin is the reaction product of an epoxy material and an acrylic resin;
wherein the reactive diluent is essentially non-reactive with the epoxy material used to form the epoxy acrylate resin; and
wherein the coating composition has a volatile organic compound content of no greater than 0.4 kilogram per liter of solids.
2. The coating composition of claim 1 wherein the polymerized reactive diluent comprises a polymerized product of one or more reactive diluents, and wherein at least one of the one or more reactive diluents comprises ethyl acrylate, 2-ethylhexyl acrylate, methyl acrylate, butyl acrylate, isobutyl acrylate, tert-butyl acrylate, 2-hydroxyethyl acrylate, poly(ethylene glycol) acrylate, isobornyl acrylate, butyl methacrylate, methyl methacrylate, ethyl methacrylate, isobutyl methacrylate, 2-hydroxyethyl methacrylate, poly(ethylene glycol) methacrylate, poly(propylene glycol) methacrylate, styrene, substituted styrene, vinyl acetate, vinyl chloride, vinylidene chloride, acrylamide, acrylonitrile, or a combination thereof.
3. The coating composition of claim 1 wherein the polymerized reactive diluent comprises a polymerized product of reactive diluents comprising butyl acrylate and styrene.
4. The coating composition of claim 1 wherein the polymerized reactive diluent comprises a polymerized product of a reactive diluent comprising butyl acrylate.
5. The coating composition of claim 1 wherein the epoxy material comprises diglycidyl ether of bisphenol-A.
6. The coating composition of claim 1 wherein the epoxy material has a number average molecular weight of from 350 to 6,000.
7. The coating composition of claim 1 wherein the epoxy material has a number average molecular weight of from 1,500 to 4,000.
8. The coating composition of claim 1 wherein the acrylic resin comprises a polymeric backbone having at least one pendant or terminal carboxylic acid moiety.
9. The coating composition of claim 1 wherein the acrylic resin comprises a reaction product of one or more monomers, and wherein at least one of the one or more monomers is selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, crotonic acid, maleic acid, itaconic acid, and combinations thereof.
10. The coating composition of claim 1 wherein the acrylic resin comprises a reaction product of one or more monomers, and wherein at least one of the one or more monomers is selected from the group consisting of ethyl acrylate, methyl acrylate, butyl acrylate, ethyl methacrylate, methyl methacrylate, butyl methacrylate, styrene, substituted styrene, vinyl acetate, vinyl chloride, vinylidene chloride, 2-ethylhexyl acrylate, isobutyl acrylate, tert-butyl acrylate, 2-hydroxyethyl acrylate, poly(ethylene glycol) acrylate, isobornyl acrylate, acrylamide, acrylonitrile, and combinations thereof.
11. The coating composition of claim 1 wherein the acrylic resin comprises a reaction product of monomers comprising acrylic acid, styrene, and ethyl acrylate.
12. The coating composition of claim 1 wherein the volatile organic compound content of the coating composition is no greater than 0.3 kilogram per liter of solids.
13. The coating composition of claim 1 wherein the volatile organic compound content of the coating composition is no greater than 0.2 kilogram per liter of solids.
14. The coating composition of claim 1 wherein the volatile organic compound content of the coating composition is no greater than 0.1 kilogram per liter of solids.
15. The coating composition of claim 1 wherein the coating composition is substantially free of formaldehyde.
16. The coating composition of claim 1 , wherein the coating composition contains an amount of polymerized reactive diluent sufficient to achieve the volatile organic compound content of no greater than 0.4 kilograms per liter of solids.
17. The coating composition of claim 1 , wherein the coating composition comprises at least 5.7 weight percent of polymerized reactive diluent, based on the total weight of the composition.
18. A substrate coated with the coating composition according to claim 1 .
19. A method of coating a substrate, the method comprising: providing a substrate; and applying the coating composition according to claim 1 to at least a portion of the substrate.
20. The method of claim 19 further comprising hardening the applied coating composition.