Secondary battery of improved lithium ion mobility and cell capacity
View Patent ↗Provided is a lithium secondary battery having improved discharge characteristics in a range of high-rate discharge while minimizing a dead volume and at the same time, having increased cell capacity via increased electrode density and electrode loading amounts, by inclusion of two or more active materials having different redox levels so as to exert superior discharge characteristics in the range of high-rate discharge via sequential action of cathode active materials in a discharge process, and preferably having different particle diameters.
1. A cathode active material for a lithium secondary battery, comprising:
a first active material; and
a second active material,
wherein the first and the second active materials have different redox levels,
wherein the average particle diameter of the first active material is less than 50% of the average particle diameter of the second active material; and
wherein the first active material is contained in an amount of 10 percent to 35 percent by weight, based on the total weight of the cathode active material, and wherein the first active material is selected from the group consisting of Formulas II and III, and wherein the second active material is represented by Formula IV:
Li 1+x Ni 1−y−z M y M′ z O 2 A a (II)
wherein −0.2<x<0.2; 0<y≦0.45; 0<z≦0.45; 0≦a≦0.05; ⅓≦1−y−z≦0.45; each M and M′ is independently a first row transition metal selected from the group consisting of Co, Mn, Fe, Cr, Ti, Zn, V, Al, and Mg; and A is an element of Group 6A or Group 7A selected from the group consisting of S, Se, F, Cl and I; and
wherein the materials of Formula II are active materials having electrochemical characteristics of Ni 3+ Ni 4+ oxidation-reduction in layered structures thereof;
Li 1+x Ni 1−y−z M y M′ z O 2 A a (III)
wherein −0.2<x<0.2; 0<y≦0.45; 0<z≦0.45; 0≦a≦0.05; ⅓≦1−y−z≦0.45; each M and M′ is independently a first row transition metal selected from the group consisting of Co, Mn, Fe, Cr, Ti, Zn, V, Al, and Mg; and A is an element of Group 6A or Group 7A selected from the group consisting of S, Se, F, Cl and I; and
wherein the materials of Formula III are active materials having electrochemical characteristics of Ni 2+ Ni 4+ oxidation-reduction in layered structures thereof; and
Li 1+x Mn 2−y M y O 4 A a (IV)
wherein −0.2<x<0.2; 0<y≦0.4; 0≦a≦0.05; M is Al; and A is an element of Group 6A or Group 7A selected from the group consisting of S, Se, F, Cl and I; and
wherein the materials of Formula IV are active materials having electrochemical characteristics of Mn 3+ Mn 4+ oxidation-reduction in spinel structures thereof.
2. The cathode active material according to claim 1 , wherein the redox level of the first and the second active materials is in the range of 3.5 to 4.5 V.
3. The cathode active material according to claim 1 , wherein the average particle diameter of the first active material is in the range of 10 to 35% of an average particle diameter of the second active material.
4. The cathode active material according to claim 1 , wherein the content of the first active material is in the range of 20 to 35% by weight, based on the total weight of the cathode active material.
5. An electrode comprising the cathode active material set forth in claim 1 .
6. A lithium secondary battery comprising the electrode of claim 5 .
7. The lithium secondary battery according to claim 6 , wherein the battery is a secondary battery in which an electrolyte acts as a limiting factor in the range of high-rate discharge.
8. The cathode active material according to claim 1 , wherein the first active material is LiNi 1/3 Mn 1/3 Co 1/3 O 2 , and the second active cathode is represented by the Formula IV.