Surface treatment methods for implants made of titanium or titanium alloy
View Patent ↗A method of producing a generally uniformly roughened surface on Ti 6/4 alloy or titanium for contact with living bone comprises exposing the Ti 6/4 alloy or titanium in an aqueous solution of citric acid and hydrofluoric acid for a suitable time period to remove the native oxide from the Ti 6/4 alloy or titanium so as to expose the Ti 6/4 or titanium metal surface and create the desired surface topography.
1. A method of producing a generally uniformly roughened surface on Ti 6/4 alloy for contact with living bone comprising the act of exposing the Ti 6/4 alloy in an aqueous solution of citric acid and hydrofluoric acid for a suitable time period to remove the native oxide from the Ti 6/4 alloy so as to expose the Ti 6/4 metal surface and create the desired surface topography, the aqueous solution comprises from about 1 to about 50 wt. % citric acid.
2. The method of claim 1 further including rinsing the desired surface topography so as to remove the residual aqueous solution.
3. The method of claim 1 wherein the aqueous solution comprises from about 16.0 to about 17.3 wt. % citric acid.
4. The method of claim 1 wherein the aqueous solution comprises from about 0.1 to about 1.0 wt. % hydrofluoric acid.
5. The method of claim 4 wherein the aqueous solution comprises from about 0.16 to about 0.20 wt. % hydrofluoric acid.
6. The method of claim 1 wherein the aqueous solution comprises from about 16 to about 17.3 wt. % citric acid and from about 0.16 to about 0.20 wt. % hydrofluoric acid.
7. The method of claim 1 wherein all of the native oxide is removed from the Ti 6/4 alloy.
8. The method of claim 1 wherein the Ti 6/4 alloy is a Ti 6/4 E.L.I. alloy.
9. The method of claim 1 wherein the method of producing a generally uniformly roughened surface on Ti 6/4 alloy for contact with living bone includes no additional acts.
10. A method of producing a generally uniformly roughened surface on Ti 6/4 alloy for contact with living bone comprising the act of exposing the Ti 6/4 alloy to an aqueous solution of citric acid and hydrofluoric acid for a suitable time period to remove the native oxide from the Ti 6/4 alloy so as to expose the Ti 6/4 metal surface and etch the exposed metal to achieve a roughened surface having irregularities with peak-to-valley heights of less than about 10 microns.
11. The method of claim 10 wherein the roughened surface has irregularities with peak-to-peak distances of from about 1 to about 3 microns.
12. The method of claim 11 wherein the roughened surface has irregularities with peak-to-valley heights of less than about 3 microns.
13. The method of claim 10 wherein the roughened surface has irregularities with peak-to-valley heights of less than about 5 microns.
14. A method of preparing a surface of a Ti 6/4 alloy implant that is surgically implantable in living bone, the surface having a native oxide layer thereon, the method comprising the act of:
exposing the Ti 6/4 alloy to an aqueous solution of citric acid and hydrofluoric acid for a suitable time period,
wherein the aqueous solution of citric acid and hydrofluoric acid removes substantially all of the native oxide from the Ti 6/4 alloy and forms a modified surface with substantially uniform array of irregularities having peak-to-valley heights less than about 10 microns.
15. The method of claim 14 wherein the substantially uniform array of irregularities has peak-to-peak distances of from about 1 to about 3 microns.
16. The method of claim 14 wherein the substantially uniform array of irregularities has peak-to-valley heights of less than about 5 microns.
17. The method of claim 14 wherein the aqueous solution comprises from about 16.0 to about 17.3 wt. % citric acid.
18. A method of preparing a surface of a Ti 6/4 alloy implant that is surgically implantable in living bone, the surface having a native oxide layer thereon, the method comprising the acts of:
performing an initial treatment that removes substantially all of the native oxide from the surface of the Ti 6/4 alloy; and
after performing the initial treatment, exposing the Ti 6/4 alloy to an aqueous solution of citric acid and hydrofluoric acid for a suitable time period to achieve a roughened surface having irregularities with peak-to-valley heights of less than about 10 microns.
19. A method of producing a generally uniformly roughened surface on titanium for contact with living bone comprising the act of exposing the titanium in an aqueous solution of citric acid and hydrofluoric acid for a suitable time period to remove the native oxide from the titanium so as to expose the titanium metal surface and create the desired surface topography, the aqueous solution comprises from about 1 to about 50 wt. % citric acid.
20. The method of claim 19 wherein the aqueous solution comprises from about 22 to about 23 wt. % citric acid.