High IV melt phase polyester polymer catalyzed with antimony containing compounds
View Patent ↗A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.
1. A process for forming bottle preforms or trays having a b* ranging from −5 to +5 and an L* of at least 70 comprising
forming a polyester polymer composition comprising a melt phase product containing antimony residues and having an It.V. of at least 0.70 dL/g;
feeding the polyester polymer composition to an extruder;
melting the polyester polymer composition to produce a molten polyester polymer;
extruding the molten polyester polymer composition through a die; and
obtaining bottle preforms or trays having a b* ranging from −5 to +5 and an L* of at least 70;
with the proviso that said process does not comprise solid state polymerization.
2. A process for making polyester polymer articles having a b* ranging from −5 to +5 and an L* of at least 70 comprising:
a) forming pellets comprising melt phase products having a degree of crystallinity of at least 25% and an It.V. of at least 0.7 dL/g and comprising antimony containing residues;
b) drying said pellets in said drying zone at a temperature of at least 140° C.;
c) introducing said pellets into an extrusion zone and forming a molten polyester polymer composition;
d) forming a polyester polymer article comprising a sheet, strand, fiber, or a molded part directly or indirectly from the extruded molten polyester polymer; and
e) obtaining a polyester polymer article having a b* ranging from −5 to +5 and an L* of at least 70;
with the proviso that said prooess does not comprise solid state polymerization.
3. The process of claim 2 , wherein the pellets are substantially free of titanium residues.
4. The process of claim 2 , wherein the melt phase products comprise
(a) a carboxylic acid component comprising at least 60 mole % of the residues of terephthalic acid or derivates of terephthalic acid, based on 100 mole percent of carboxylic acid component residues in the product.
5. The process of claim 2 , wherein the polyester polymer article comprise:
(a) a carboxylic acid component comprising at least 92 mole % of the residues of terephthalic acid or derivates of terephthalic acid, and
(b) a hydroxyl component comprising at least 92 mole % of the residues of ethylene glycol,
based on 100 mole percent of carboxylic acid component residues and 100 mole percent of hydroxyl component residues in the polyester polymer melt phase product.
6. The process of claim 1 , wherein the bottle preforms or trays have an L* of 74 or more.
7. The process of claim 1 , wherein the bottle preforms or trays have an L* of 76 or more.
8. The process of claim 2 , wherein the polyester polymer article has an L* of 74 or more.
9. The process of claim 2 , wherein the polyester polymer article has an L* of 76 or more.