Organic electroluminescent device and method of manufacturing the same
Provided is an organic EL device including a light-emitting layer between a first electrode and a second electrode, wherein the light-emitting layer includes a matrix polymer, two or more phosphorescent host materials, and at least one phosphorescent dopant. The organic EL device can increase an energy transfer efficiency by use of a mixture of phosphorescent host materials, and thus have better efficiency and lifetime characteristics, and can be produced by a solution process such as spin-coating.
1 . An organic EL device comprising a light-emitting layer between a first electrode and a second electrode,
wherein the light-emitting layer comprises a matrix polymer, two or more phosphorescent host materials, and at least one phosphorescent dopant.
2 . The organic EL device of claim 1 , wherein the matrix polymer is at least one selected from polyphenylenevinylene (PPV), polyvinylcarbazole (PVK), polyfluorene, and derivatives thereof.
3 . The organic EL device of claim 1 , wherein the content of the matrix polymer ranges from about 50 to about 200 parts by weight, based on the total weight 100 parts by weight of the two or more phosphorescent host materials.
4 . The organic EL device of claim 1 , wherein the two or more phosphorescent host materials are composed of a first host material and a second host material, and the first host material and the second host material are different in at least one of a HOMO level and a LUMO level.
5 . The organic EL device of claim 4 , wherein each of the first host material and the second host material has a triplet energy level of about 2.3 to about 3.5 eV.
6 . The organic EL device of claim 4 , wherein at least one of the two or more phosphorescent host materials is a carbazole compound.
7 . The organic EL device of claim 6 , wherein the carbazole compound is selected from the group consisting of 1,3,5-triscarbazolylbenzene, 4,4′-biscarbazolylbiphenyl (CBP), m-biscarbazolylphenyl, 4,4′-biscarbazolyl-2,2′-dimethylbiphenyl (dmCBP), 4,4′,4″-tris(N-carbazolyl)triphenylamine, 1,3,5-tris(2-carbazolylphenyl)benzene, 1,3,5-tris(2-carbazolyl-5-methoxyphenyl)benzene, and bis(4-carbazolylphenyl)silane.
8 . The organic EL device of claim 4 , wherein at least one of the two or more phosphorescent host materials is selected from an organometallic complex, a spirofluorene compound, an oxadiazole compound, a phenanthroline compound, a triazine compound, and a triazole compound.
9 . The organic EL device of claim 8 , wherein the organometallic complex is bis(8-hydroxyquinolato)biphenoxy aluminum (III), bis(8-hydroxyquinolato)phenoxy aluminum (III), bis(2-methyl-8-hydroxyquinolato)biphenoxy aluminum (III), bis(2-methyl-8-hydroxyquinolato)naphthoxy aluminum (III), bis(2-methyl-8-hydroxyquinolato)phenoxy aluminum (III), bis(2-(2-hydroxyphenyl)quinolato) zinc (II), or bis(2-methyl-8-quinolinolato)(para-phenyl-phenolato) aluminum (III).
10 . The organic EL device of claim 8 , wherein the spirofluorene compound is 2,5-dispirobifluorene-1,3,4-oxadiazole, the oxadiazole compound is (4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole, and the phenanthroline compound is 2,9-dimethyl-4,7-diphenyl-9,10-phenanthroline.
11 . The organic EL device of claim 8 , wherein the triazine compound is 2,4,6-tris(diarylamino)-1,3,5-triazine, 2,4,6-tris(diphenylamino)-1,3,5-triazine, 2,4,6-tricarbazolo-1,3,5-triazine, 2,4,6-tris(N-phenyl-2-naphthylamino)-1,3,5-triazine, 2,4,6-tris(N-phenyl-1-naphthylamino)-1,3,5-triazine, or 2,4,6-trisbiphenyl-1,3,5-triazine, and the triazole compound is 3 -phenyl-4-(1-naphthyl)-5-phenyl-1,2,4-triazole.
12 . The organic EL device of claim 4 , wherein the mixed weight ratio of the first host material to the second host material ranges from about 9:1 to about 1:9.
13 . The organic EL device of claim 1 , wherein the phosphorescent dopant is at least one selected from the group consisting of bisthienylpyridine acetylacetonate Iridium, bis(benzothienylpyridine)acetylacetonate Iridium, bis(2-phenylbenzothiazole)acetylacetonate Iridium, bis(1-phenylisoquinoline) Iridium acetylacetonate, tris(1-phenylisoquinoline) Iridium, and tris(2-biphenylpyridine) Iridium.
14 . The organic EL device of claim 1 , wherein the content of the phosphorescent dopant ranges from about 1 to about 45 parts by weight, based on the total weight 100 parts by weight of the two or more phosphorescent host materials.
15 . The organic EL device of claim 1 , wherein the matrix polymer is polyvinylcarbazole (PVK), the phosphorescent host materials are CBP and Balq, and the phosphorescent dopant is bis(1-phenylisoquinoline) iridium (III) acetylacetonate [pq2Ir(acac)].
16 . The organic EL device of claim 1 , further comprising at least one selected from a hole injection layer and a hole transport layer between the first electrode and the light-emitting layer.
17 . The organic EL device of claim 1 , further comprising at least one selected from a hole blocking layer, an electron transport layer, and an electron injection layer between the light-emitting layer and the second electrode.
18 . A method of manufacturing an organic EL device comprising a light-emitting layer between a first electrode and a second electrode, the method comprising:
mixing a matrix polymer, two or more host materials, and at least one phosphorescent dopant material to prepare a composition for forming the light-emitting layer; and
coating the composition onto the first electrode.
19 . The method of claim 18 , wherein a solvent used for preparing the composition is at least one selected from the group consisting of benzene, toluene, and chlorobenzene.
20 . The method of claim 18 , wherein coating the composition onto the first electrode is performed by one selected from the group consisting of spin-coating, inkjet printing, dip-coating, doctor-blading, and thermal transfer.