Process for adsorber regeneration

1. A process for regenerating adsorbers in an adsorber station (A), which is used to purify a synthesis gas ( 3 ) flowing to a cryogenic gas separation unit (Z) of a synthesis gas installation, in which an oxo gas product ( 12 ) or a methanol synthesis gas ( 14 ) is obtained from said cryogenic gas separation unit ( 2 ), wherein a part-stream ( 5 ) is removed from the purified synthesis gas stream ( 4 ) downstream of an adsorber station (A) but upstream of said cryogenic gas separation unit (Z), and said part-stream ( 5 ) is returned to the adsorber station (A) as regeneration gas for regenerating the adsorbers, characterized in that the part-stream of synthesis gas ( 6 ) used as regeneration gas, after having passed through the adsorber(s) to be regenerated, is admixed with the oxo gas product ( 12 ) or the methanol synthesis gas ( 14 ).

2. A process according to claim 1 , said process being conducted in installations, in which methanol synthesis gas ( 14 ) is generated cryogenically from part of the purified synthesis gas, and a part of the synthesis gas ( 4 ′), following purification in the adsorber station (A), is returned to a CO 2 scrub (W).

3. A process according to claim 2 , characterized in that a part-stream ( 16 ) is removed from the synthesis gas stream ( 4 ) downstream of the adsorber station (A) but upstream of the CO 2 scrub (W) and is passed to the adsorbers of the adsorber station (A) downstream of the regeneration in order to cool said adsorbers and then the resultant warmed part-stream ( 16 ) is fed into the methanol synthesis gas ( 14 ).

4. A process according to claim 1 , being conducted in installations in which methanol synthesis gas is generated, the regeneration gas ( 5 ) is returned to the CO 2 scrub (W), is thereafter warmed against the crude synthesis gas ( 1 ) to be cooled, the adsorbers of the adsorber station (A) are regenerated with resultant warmed regeneration gas which is then fed into the methanol synthesis gas ( 14 ).

5. A process according to claim 4 , characterized in that cold synthesis gas ( 15 ), which is not warmed in the CO 2 scrub (W) is fed into the methanol synthesis gas ( 14 ), is then passed in heat exchange contact with the adsorbers of the adsorber station (A) so as to cool the adsorbers after the regeneration.

6. A process according to claim 1 , being conducted in synthesis gas installations which utilize gas from a cryogenic gas separation unit as regeneration gas, a part-stream of the synthesis gas is used as regeneration gas, with the synthesis gas after is has passed through the adsorber(s) to be regenerated is used as fuel gas or is added to a flare, or is passed into a pressure swing adsorption (PSA) installation to separate hydrogen.

7. A process according to claim 2 , wherein the synthesis gas ( 4 ′) returned to the CO 2 scrub is warmed against the crude synthesis gas ( 1 ) to be cooled and then passed to the cryogenic gas separation unit (Z), with a part-stream ( 5 ) being removed from the warmed synthesis gas stream ( 4 ) downstream of the CO 2 scrub (W) but upstream of its cryogenic separation (Z), and said part-stream is passed as regeneration gas for regenerating the adsorbers of the adsorber station (A), and resultant laden regeneration gas ( 6 ) is then fed into the methanol synthesis gas ( 14 ).

8. A process according to claim 6 , wherein the synthesis gas after passing through the adsorbers to be regenerated is passed to a pressure swing adsorption (PSA) to separate hydrogen.

9. A process according to claim 6 is conducted during start-up.