Water-immersion indicator indicia and articles bearing such indicia
There are described articles bearing indicia applied with an ink composition which comprises two or more color-changing or color-forming components which combine, or become diluted, upon exposure to water for a sufficient period of time to cause a change in the appearance of the indicia. Also described are printing ink compositions for forming such indicia and methods for forming such articles.
1 . An indicia-bearing article, said indicia comprising an ink composition comprising two or more color-forming components which cause a change in the appearance of the indicia upon exposure to water for a sufficient period of time, wherein one of said color-forming components is an acid-sensitive leuco dye and the other of said components is an acid developer, and wherein said indicia are initially colored.
2 . The article according to claim 1 which is a golf ball.
3 . (canceled)
4 . The article according to claim 2 wherein said indicia change to another color upon exposure to water for a sufficient period of time.
5 . (canceled)
6 . The article as defined in claim 2 wherein said indicia become colorless or substantially colorless upon exposure to water for a sufficient period of time.
7 . (canceled)
8 . (canceled)
9 . (canceled)
10 . (canceled)
11 . A method for forming an indicia-bearing article comprising imprinting on an article indicia comprising an ink composition comprising two or more color-forming components which cause a change in the appearance of the indicia upon exposure to water for a sufficient period of time, wherein one of said color-forming components is an acid-sensitive leuco dye and the other of said components is an acid developer, and wherein said indicia are initially colored.
12 . The method as defined in claim 11 wherein said ink composition comprises said two or more components in an organic solvent.
13 . The method as defined in claim 12 wherein said ink composition further includes a binder material.
14 . The method as defined in claim 11 wherein said article is a golf ball.
15 . (canceled)
16 . The method as defined in claim 14 wherein said indicia change to another color upon exposure to water for a sufficient period of time.
17 . The method as defined in claim 14 wherein said indicia become substantially colorless or colorless upon exposure to water for a sufficient period of time.
18 - 28 . (canceled)