Propylene polymer catalyst donor component
View Patent ↗A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins containing magnesium, titanium, and halogen further contains an internal electron donor comprising a compound containing electron donating substituents with a structure: wherein D 1 and D 2 are selected individually from and R, R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 individually are hydrocarbon or substituted hydrocarbon groups containing 1 to 20 carbon atoms and R 2 , R 3 , R 4 , R 6 , and R 7 may be hydrogen; R 4 may be —NR 2 ; and wherein groups R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 3 and R 5 , and groups R 6 and R 7 may be joined to form a cyclic structure.
1. A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins containing magnesium, titanium, and halogen further containing an internal electron donor comprising at least one internal electron donor comprising a compound containing electron donating substituents with a structure:
wherein D 1 and D 2 are selected individually from
and R, R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 individually are hydrocarbon or substituted hydrocarbon groups containing 1 to 20 carbon atoms and R 2 , R 3 , R 4 , R 6 , and R 7 may be hydrogen; R 4 may be —NR 2 ; and
wherein groups R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 3 and R 5 , and groups R 6 and R 7 may be joined to form a cyclic structure.
2. A catalyst component of claim 1 wherein R is an alkyl group containing 1 to 8 carbon atoms.
3. A catalyst component of claim 1 wherein the electron donor containing compound is ethyl (phenylacetoxy) acetate.
4. A catalyst component of claim 1 wherein R 4 is not hydrogen.