Photothermographic material
The invention provides a photothermographic material having, on a surface of a substrate, an image forming layer and a non-photosensitive layer. The image forming layer has a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder. At least one of the image forming layer and the non-photosensitive layer has at least one selected from the group consisting of: modified polyvinyl alcohol A, which is a polyvinyl alcohol including an α-olefin having 1 to 4 carbon atoms as a copolymerized constituent thereof; modified polyvinyl alcohol B, which is a polyvinyl alcohol including, as a copolymerized constituent thereof, an ethylenic unsaturated carboxylic acid; and modified polyvinyl alcohol C, which is a polyvinyl alcohol including, as a copolymerized constituent thereof, an ethylenic unsaturated monomer having a primary amino group or a secondary amino group.
1 . A photothermographic material comprising, on a surface of a substrate, an image forming layer and a non-photosensitive layer, wherein:
the image forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder; and
at least one of the image forming layer and the non-photosensitive layer comprises at least one selected from:
modified polyvinyl alcohol A, which is a polyvinyl alcohol comprising an α-olefin having 1 to 4 carbon atoms as a copolymerized constituent thereof;
modified polyvinyl alcohol B, which is a polyvinyl alcohol comprising, as a copolymerized constituent thereof, an ethylenic unsaturated carboxylic acid; and
modified polyvinyl alcohol C, which is a polyvinyl alcohol comprising, as a copolymerized constituent thereof, an ethylenic unsaturated monomer having a primary amino group or a secondary amino group.
2 . The photothermographic material of claim 1 , wherein the image forming layer comprises at least one of the modified polyvinyl alcohols A to C.
3 . The photothermographic material of claim 1 , wherein the non-photosensitive layer comprises at least one of the modified polyvinyl alcohols A to C.
4 . The photothermographic material of claim 3 , wherein the non-photosensitive layer is provided over a side of the substrate on which the image forming layer is provided.
5 . The photothermographic material of claim 4 , wherein a non-photosensitive outermost layer is provided over a side of the substrate on which the image forming layer is provided, and a non-photosensitive intermediate layer comprising at least one of the modified polyvinyl alcohols A to C is provided between the image forming layer and the non-photosensitive outermost layer.
6 . The photothermographic material of claim 3 , wherein the non-photosensitive layer comprising at least one of the modified polyvinyl alcohols A to C is provided over a side of the substrate which is opposite to another side on which the image forming layer is provided.
7 . The photothermographic material of claim 1 , wherein the binder comprises a polymer latex.
8 . The photothermographic material of claim 3 , wherein the non-photosensitive layer comprises a polymer latex.
9 . The photothermographic material of claim 7 , wherein the non-photosensitive layer comprises a polymer latex.
10 . The photothermographic material of claim 7 , wherein the polymer latex is a polymer comprising the monomer constituent represented by the following Formula (M) in an amount of 10 to 70% by mass:
CH 2 ═CR 01 —CR 02 ═CH 2 Formula (M)
wherein R 01 and R 02 respectively represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.
11 . The photothermographic material of claim 8 , wherein the polymer latex is a polymer comprising the monomer constituent represented by the following Formula (M) in an amount of 10 to 70% by mass:
CH 2 ═CR 01 —CR 02 ═CH 2 Formula (M)
wherein R 01 and R 02 respectively represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.
12 . The photothermographic material of claim 9 , wherein the polymer latex is a polymer comprising the monomer constituent represented by the following Formula (M) in an amount of 10 to 70% by mass:
CH 2 ═CR 01 —CR 02 ═CH 2 Formula (M)
wherein R 01 and R 02 respectively represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.
13 . The photothermographic material of claim 10 , wherein both of R 01 and R 02 in Formula (M) represent a hydrogen atom, or one of R 01 and R 02 represents a hydrogen atom while the other represents a methyl group.
14 . The photothermographic material of claim 11 , wherein both of R 01 and R 02 in Formula (M) represent a hydrogen atom, or one of R 01 and R 02 represents a hydrogen atom while the other represents a methyl group.
15 . The photothermographic material of claim 12 , wherein both of R 01 and R 02 in Formula (M) represent a hydrogen atom, or one of R 01 and R 02 represents a hydrogen atom while the other represents a methyl group.
16 . The photothermographic material of claim 5 , wherein a non-photosensitive intermediate layer B is provided between the non-photosensitive intermediate layer and the non-photosensitive outermost layer, and at least one of the non-photosensitive outermost layer and the non-photosensitive intermediate layer B comprises a binder which comprises a hydrophilic polymer having 50% by mass or more of a protein which is derived from an animal.
17 . The photothermographic material of claim 16 , wherein the non-photosensitive intermediate layer B comprises the binder which comprises the hydrophilic polymer, and the non-photosensitive outermost layer comprises a binder having 50% by mass or more of a hydrophobic polymer.
18 . The photothermographic material of claim 16 , wherein the non-photosensitive outermost layer comprises the binder which comprises the hydrophilic polymer.
19 . The photothermographic material of claim 16 , wherein the hydrophilic polymer is gelatin.