IP Library Granted Patent US 9,023,530
Granted Patent B2
US 9,023,530 · App. 11/371,286 · Granted May 5, 2015

Non-aqueous electrolyte secondary battery

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Quick Facts
Patent No.
US 9,023,530
App. No.
11/371,286
Granted
May 5, 2015
Kind
B2
Abstract

To improve high temperature storage characteristic of a non-aqueous electrolyte secondary battery suitable for high input/output application, the structure of a positive electrode active material is optimized. The non-aqueous electrolyte secondary battery includes a positive electrode; a negative electrode; a separator interposed between the positive and negative electrodes; and a non-aqueous electrolyte. The positive electrode active material includes secondary particles, each formed of an aggregate of primary particles. A value (V Pr ) defined by the formula: V Pr =(1−C/D)/(A 2 ×B 3 ) is not less than 0.0005 and not greater than 0.04, where an average particle size of the primary particles is A μm, an average particle size of the positive electrode active material is B μm, a tap density of the positive electrode active material is C g/ml, and a true specific gravity of the positive electrode active material is D g/ml.

Claims (17)

1. A non-aqueous electrolyte secondary battery comprising:

a positive electrode including a positive electrode active material;

a negative electrode including a negative electrode active material;

a separator interposed between said positive electrode and said negative electrode; and

a non-aqueous electrolyte,

wherein said positive electrode active material comprises secondary particles, each comprising an aggregate of primary particles, said primary particles comprising a transition metal-containing composite oxide capable of intercalating and deintercalating lithium ions, and

wherein a value (V Pr ) defined by the formula:

V Pr =(1−C/D)/(A 2 ×B 3 ), is not less than 0.0005 and not greater than 0.04,

where an average particle size of said primary particles is A μm,

an average particle size of said positive electrode active material is B μm,

a tap density of said positive electrode active material is C g/ml, and

a true density of said positive electrode active material is D g/ml,

provided that C is from 2.4 to 2.6,

wherein, said composite oxide is represented by the formula: Li x Ni 1-(y+z) Co y M z O 2 , where 1.01≦x≦1.05, 0.1≦y≦0.2, and 0.02≦z≦0.1, and said element M represents Al.

2. The non-aqueous electrolyte secondary battery in accordance with claim 1 ,

wherein said average particle size of said primary particles A is from 0.1 to 1.5 μm, and

said average particle size of said positive electrode active material B is from 3 to 15 μm.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE ERRONEOUSLY FILED APPLICATION NUMBERS 13/384239, 13/498734, 14/116681 AND 14/301144 PREVIOUSLY RECORDED ON REEL 034194 FRAME 0143. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 24, 2020
From: PANASONIC CORPORATION
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 056788/0362 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 10, 2014
From: PANASONIC CORPORATION
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 034194/0143 →
CHANGE OF NAME Recorded Nov 24, 2008
From: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
To: PANASONIC CORPORATION
Reel/Frame 021897/0671 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 6, 2006
From: SAITO, TAKAYA; KOGETSU, YASUTAKA; TAKEUCHI, TAKASHI; HIRATSUKA, HIDEKAZU
To: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
Reel/Frame 017884/0201 →