Silver halide photographic emulsion and silver halide photosensitive material using thereof
View Patent ↗A silver halide photographic emulsion, wherein 70% or more of the total projected area of silver halide grains is occupied by silver halide grains satisfying the following requirements (a) to (d). (a) It is composed of a tabular silver halide host grain with an aspect ratio of 12 or more having two mutually parallel principal planes and a silver halide protrusion portion bonded by epitaxial junction on the surface of the host grain. (b) The silver bromide content rates of the host grain and the protrusion portion both are 70 mol % or more. (c) When the average silver iodide content rate of all grains is I mol %, the average silver iodide content rate of the region of 8%, based on the silver amount of the host grain, of the outer shell of the host grain is (I+12) mol % or less.
1. A silver halide photographic emulsion, wherein 70% or more of the total projected area of silver halide grains is occupied by silver halide grains satisfying the following requirements (a) to (d) and (f):
(a) said silver halide grains comprise a tabular silver halide host grain with an aspect ratio of 12 or more having two mutually parallel principal planes and a silver halide protrusion portion bonded by epitaxial junction on the surface of the host grain;
(b) a silver bromide content of the host grain and the protrusion portion both are 70 mol % or more;
(c) when an average silver iodide content of all grains is I mol %, the average silver iodide content of the region of 8%, based on the silver amount of the host grain, of the outer shell of the host grain is (I+12) mol % or less;
(d) the protrusion portion contains pseudo-halides; and
(f) when the average silver iodide content of all grains is I mol %, the silver iodide content of the protrusion portion is I mol % or less.
2. The silver halide photographic emulsion according to claim 1 , wherein 70% or more of the total projected area of silver halide grains is occupied by silver halide grains satisfying the following requirement (e) in addition to the above requirements (a) to (d) and (f):
(e) a silver chloride content of the host grain and the protrusion portion both are 1 mol % or less.
3. The silver halide photographic emulsion according to claim 1 , wherein 70% or more of the total projected area of silver halide grains is occupied by silver halide grains satisfying the following requirement (g) in addition to the above requirements (a) to (d) and (f):
(g) the protrusion portion contains an iridium compound.
4. The silver halide photographic emulsion according to claim 2 , wherein 70% or more of the total projected area of silver halide grains is occupied by silver halide grains satisfying the following requirement (g) in addition to the above requirements (a) to (f):
(g) the protrusion portion contains an iridium compound.
5. The silver halide photographic emulsion according to claim 1 , containing calcium.
6. The silver halide photographic emulsion according to claim 1 , chemically sensitized using a compound releasing AuCh— ion (wherein Ch represents S, Se or Te).
7. A silver halide photosensitive material comprising a photosensitive layer containing a silver halide photographic emulsion according to claim 1 .