Organic light-emitting device and method of manufacturing the same
Provided are an organic light-emitting device that includes a light-emitting layer interposed between a first electrode and a second electrode and a method of manufacturing the same. The light-emitting layer includes a mixed host of a naphthyl anthracene-based compound and a bianthracene-based compound and a dopant. The use of the mixed host of a naphthyl anthracene-based compound and a bianthracene-based compound and a dopant to form the light-emitting layer results in trapping of charges in the light-emitting layer. As a result, the organic light-emitting device is more stabilized and thus has a longer lifetime, excellent color characteristics, and high efficiency.
1 . An organic light-emitting device, comprising:
a first electrode;
a second electrode; and
a light-emitting layer interposed between the first electrode and the second electrode, the light-emitting layer comprising a host and a dopant, the host comprising a naphthyl anthracene-based compound and a bianthracene-based compound.
2 . The device of claim 1 , wherein the naphthyl anthracene-based compound is represented by Formula 1-1:
wherein R is selected from the group consisting of hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C6-C20 aryl group, a substituted or unsubstituted C6-C20 aryloxy group, and a substituted or unsubstituted C2-C20 heteroaryl group;
wherein x is one selected from the group consisting of a substituted or unsubstituted naphthyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthylphenyl group, and a substituted or unsubstituted anthracenylphenyl group.
3 . The device of claim 2 , wherein the bianthracene-based compound is represented by Formula 2:
wherein each of R 1 through R 6 is independently selected from the group consisting of hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C5-C10 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C6-C20 aryl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C6-C20 aryloxy group, a substituted or unsubstituted C1-C20 alkylamino group, a substituted or unsubstituted C6-C20 arylamino group, and a substituted or unsubstituted C2-C20 heterocyclic group, wherein one or more of R 1 through R 6 may form a ring by bonding to two or more benzene rings;
wherein each of a and b is independently an integer of 0, 1, 2, 3, 4 or 5;
wherein each of c, d, e, and f is independently an integer of 1, 2, 3 or 4; and
wherein L is selected from the group consisting of no atom, —O—. —S—, —N(R′)—, a C6-C20 arylene group and a C6-C20 aryl group, and R′ is a C1-C10 alkyl group.
4 . The device of claim 2 , wherein the compound represented by formula 1-1 is the compound represented by Formula 3 or Formula 4:
5 . The device of claim 1 , wherein the bianthracene-based compound is represented by Formula 2:
wherein each of R 1 through R 6 is independently selected from the group consisting of hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C5-C10 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C6-C20 aryl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C6-C20 aryloxy group, a substituted or unsubstituted C1-C20 alkylamino group, a substituted or unsubstituted C6-C20 arylamino group, and a substituted or unsubstituted C2-C20 heterocyclic group, wherein one or more of R 1 through R 6 may form a ring by bonding to two or more benzene rings;
wherein each of a and b is independently an integer of 0, 1, 2, 3, 4 or 5;
wherein each of c, d, e, and f is independently an integer of 1, 2, 3 or 4; and
wherein L is selected from the group consisting of no atom, —O—. —S—, —N(R′)—, a C6-C20 arylene group and a C6-C20 aryl group, and R′ is a C1-C10 alkyl group.
6 . The device of claim 5 , wherein the compound represented by Formula 2 is the compound represented by Formula 5 or Formula 6:
7 . The device of claim 1 , wherein the dopant comprises a blue light-emitting material.
8 . The device of claim 1 , wherein the dopant comprises a compound represented by Formula 8:
wherein R 1 , R 2 , R 5 , and R 6 are each independently a substituted or unsubstituted C6-C20 aryl group; and
wherein R 3 and R 4 are each independently a substituted or unsubstituted C6-C20 arylene group.
9 . The device of claim 8 , wherein the dopant is one selected from the group consisting of
a compound of Formula 8, in which each of R 1 , R 2 , R 5 , and R 6 is a phenyl group, and each of R 3 and R 4 is a phenylene group;
a compound of Formula 8, in which each of R 1 and R 5 is a phenyl group, each of R 2 and R 6 is a naphthyl group, and each of R 3 and R 4 is a phenylene group; and
a compound of Formula 8, in which each of R 1 and R 5 is a naphthyl group, each of R 2 and R 6 is a phenyl group, and each of R 3 and R 4 is a naphthalene group.
10 . The device of claim 8 , wherein the dopant comprises the compound represented by Formula 7:
11 . The device of claim 1 , wherein a weight ratio of the naphthyl anthracene-based compound to the bianthracene-based compound is from about 10:90 to about 90:10.
12 . The device of claim 11 , wherein the weight ratio is from about 25:75 to about 75:25.
13 . The device of claim 1 , wherein the dopant is in an amount from about 3 to about 7 parts by weight based on 100 parts by weight of the host.
14 . The device of claim 1 , wherein the light-emitting layer comprises a compound represented by Formula 3 and a compound represented by Formula 5:
15 . The device of claim 14 , wherein a weight ratio of the compound represented by Formula 3 to the compound represented by Formula 5 is from about 75:25 to about 25:75.
16 . The device of claim 14 , wherein the light-emitting layer further comprises a dopant represented by Formula 7
17 . The device of claim 16 , wherein the dopant is in an amount from about 3 to about 7 parts by weight based on 100 parts by weight of the host.
18 . The device of claim 1 , wherein the light-emitting layer comprises a compound represented by Formula 3 and a compound represented by Formula 6:
19 . The device of claim 18 , wherein the light-emitting layer further comprises a dopant represented by Formula 7:
20 . The device of claim 1 , wherein the light-emitting layer comprises a compound represented by Formula 4 and a compound represented by Formula 5:
21 . The device of claim 20 , wherein the light-emitting layer further comprises a dopant represented by Formula 7:
22 . The device of claim 1 , wherein the light-emitting layer comprises a compound represented by Formula 4 and a compound represented by Formula 6:
23 . The device of claim 22 , wherein the light-emitting layer further comprises a dopant represented by Formula 7:
24 . An electronic device comprising the organic light-emitting device of claim 1.