Golf equipment formed from amine-adduct modified polyurea compositions
Golf equipment having at least one portion formed from amine-adduct modified polyurea compositions, including epoxy-silicone modified polyurea compositions, epoxy modified polyurea compositions, silicone modified polyurea compositions, and polyurea compositions including polyamine/carbonyl adducts and/or amine-modified adducts having backbones based on polyfunctional acrylates or methacrylates or caprolactone monomers or oligomers.
1. A golf ball comprising a core and a cover, wherein at least a portion of the golf ball is formed from a composition comprising:
a prepolymer comprising an isocyanate and at least one of an amine-terminated component or a hydroxy-terminated component; and
a curing agent comprising an adduct formed from the reaction product of an amine and a silicone having at least one end group comprising oxirane functionality.
2. The golf ball of claim 1 , wherein the silicone has oxirane functional end groups.
3. The golf ball of claim 1 , wherein the composition has a gel time of about 45 seconds or greater.
4. The golf ball of claim 3 , wherein the composition has a gel time of about 60 seconds or greater.
5. The golf ball of claim 1 , wherein the portion is the cover of the golf ball.
6. The golf ball of claim 5 , wherein the cover comprises an inner cover layer and an outer cover layer, and wherein the outer cover layer comprises the composition.
7. The golf ball of claim 6 , wherein the inner cover layer comprises thermoplastic or thermoset material.
8. The golf ball of claim 6 , wherein the inner cover layer comprises a highly neutralized polymer.
9. A golf ball comprising a core and a cover, wherein the cover is formed from a composition comprising:
a prepolymer comprising urea or urethane linkages and having terminal ends comprising hydroxy groups or amine groups; and
a curing agent comprising an adduct comprising a reaction product formed from an amine and a compound comprising a silicone backbone with oxirane functionality.
10. The golf ball of claim 9 , wherein the silicone backbone comprises dimethyl siloxane, 1,3-bis(3-aminopropyl)tetramethyl-di-siloxane, 1,4-bis(3-aminopropyldimethylsilyl)benzene, or mixtures thereof and.
11. The golf ball of claim 9 , wherein the prepolymer consists of urea linkages.
12. A method of forming a golf ball comprising a core and a cover, comprising the following steps:
providing a core;
providing a precursor formed from a silicone with at least one oxirane functional endcap;
forming an amine adduct by reacting an amine-terminated compound with the precursor, wherein the amine adduct comprises the precursor as the backbone;
forming a prepolymer comprising:
an isocyanate-containing component; and
a hydroxy-terminated component, an amine-terminated component, or a combination thereof;
reacting the amine adduct with the prepolymer to form a material; and
forming the cover from the material.
13. The method of claim 12 , wherein the step of providing a precursor comprises reacting a silicone compound with an oxirane functional resin.
14. The method of claim 13 , wherein the silicone compound is selected from the group consisting of dimethyl siloxane, 1,3-bis(3-aminopropyl)tetramethyl-di-siloxane, 1,4-bis(3-aminopropyldimethylsilyl)benzene, and mixtures thereof.
15. The method of claim 14 , wherein the oxirane functional resin is selected from the group consisting of 1,4-butanediol diglycidyl ether, diglycidyl ether of bisphenol A, cresyl diglycidyl ether, ethylhexyl glycidyl ether, and mixtures thereof.
16. The method of claim 12 , further comprising the step of forming a layer disposed about the core, and wherein the step of forming the cover from the material further comprises forming the cover about the layer.
17. The method of claim 16 , wherein the step of forming the layer comprises providing a thermoplastic material and forming the layer from the thermoplastic material.
18. The method of claim 17 , wherein the thermoplastic material comprises a highly neutralized polymer.