Composites, method of manufacture thereof, and articles formed therefrom
View Patent ↗A method of forming a dielectric substrate comprises contacting a liquid crystalline polymer fibrous web having a thickness of 5 mils (127 micrometers) or less with a resin composition to form a dielectric composite. Contacting is carried out under vacuum, followed by pressure. The dielectric substrate is useful in circuit materials, circuits, and multi-layer circuits, economical to make, and has excellent dielectric strength.
1. A method of forming a composite, comprising
in a vacuum chamber, contacting a liquid crystalline polymer fibrous web having interfiber spaces and a thickness of less than or equal to about 5 mils (127 micrometers), co-wound with a carrier, with a resin composition that is substantially free of a solvent, in the presence of a vacuum effective to infiltrate the fibrous web with the resin composition to provide an infiltrated, co-wound liquid crystalline polymer fibrous web;
removing the vacuum; and
in the vacuum chamber, applying greater than atmospheric pressure to the infiltrated fibrous web to provide an impregnated liquid crystalline polymer fibrous web.
2. The method of claim 1 wherein the liquid crystalline polymer web comprises liquid crystalline polymer fibers and a binder.
3. The method of claim 1 wherein the liquid crystalline polymer fibrous web is non-woven.
4. The method of claim 1 wherein the liquid crystalline polymer fibrous web is a woven fabric.
5. The method of claim 1 wherein the carrier is porous.
6. The method of claim 1 wherein the resin composition comprises a thermosetting resin, a thermoplastic resin, or a combination comprising at least one of the foregoing resins.
7. The method of claim 6 wherein the resin composition comprises an epoxy resin, a polybutadiene, a polyisoprene, a polyester, a polyimide, a silicone, a bismaleimide triazine, a benzoxazine, a polystyrene, a poly(methacrylate), a polyacrylate, a poly(arylene ether), a polyaryletherketone, or a combination comprising at least one of the foregoing resins.
8. The method of claim 1 , wherein the resin composition comprises a curable epoxy resin.
9. The method of claim 1 , wherein the resin composition comprises a particulate filler dispersed in the resin composition.
10. The method of claim 1 , further comprising dispersing a particulate filler onto the liquid crystalline polymer web prior to contacting with the resin composition.
11. The method of claim 1 , further comprising dispersing a particulate filler onto the carrier prior to contacting liquid crystalline polymer web with the resin composition.
12. The method of claim 1 , wherein the resin composition is a thermosetting resin composition, the method further comprising partially or fully curing the thermosetting resin composition in the impregnated liquid crystalline polymer fibrous web.
13. The method of claim 1 , further comprising contacting the impregnated liquid crystalline polymer fibrous web with a conductive layer.
14. The method of claim 13 , wherein the contacting is by lamination.
15. The method of claim 1 wherein the carrier is made from a material having low adhesion to the infiltrated web.