Polymerizable liquid crystal composition and optically anisotropic thin film
View Patent ↗In order to obtain such a liquid crystal thin film having optical anisotropy that suffers less change in optical characteristics thereof under heating to 200° C., the following polymerizable liquid crystal composition is provided as a raw material therefor. The composition contains Compound (1) and at least one of Compound (2) and Compound (3), with a proportion of Compound (1) being from 50 to 99% by weight, a proportion of Compound (2) being from 0 to 50% by weight, and a proportion of Compound (3) being from 0 to 50% by weight: wherein R is alkyl; each of W 1 and W 2 is independently hydrogen, chlorine, fluorine or —CH 3 ; each of W 3 and W 4 is independently hydrogen, chlorine, fluorine, —CH 3 or —CF 3 ; W 5 is alkyl having, alkoxy, chlorine, fluorine, —CN or —OCF 3 ; X is a single bond, —CH═CH— or —CH 2 CH 2 —; Z is a single bond, —COO—, —OCO— or —CH 2 CH 2 —; and q is an integer of from 1 to 20.
1. A composition comprising a compound represented by Formula (1) and at least one of a compound represented by Formula (2) and a compound represented by Formula (3), with a proportion of the compound represented by Formula (1) being from 50 to 99% by weight, and a total proportion of the compound represented by Formula (2) and the compound represented by Formula (3) being from 1 to 50% by weight, based on a total amount of the compound represented by Formula (1), the compound represented by Formula (2) and the compound represented by Formula (3):
wherein R is alkyl having from 1 to 4 carbon atoms; each of W 1 and W 2 is independently hydrogen, chlorine, fluorine or —CH 3 ; each of W 3 and W 4 is independently hydrogen, chlorine, fluorine, —CH 3 or —CF 3 ; W 5 is alkyl having from 1 to 10 carbon atoms, alkoxy having from 1 to 10 carbon atoms, chlorine, fluorine, —CN or —OCF 3 ; X is a single bond, —CH═CH— or —CH 2 CH 2 —; Z is a single bond, —COO—, —OCO— or —CH 2 CH 2 —; and q is an integer of from 1 to 20.
2. A polymerizable liquid crystal composition comprising a compound represented by Formula (4) and at least one of a compound represented by Formula (5) and a compound represented by Formula (6), with a proportion of the compound represented by Formula (4) being from 50 to 90% by weight, and a total proportion of the compound represented by Formula (5) and the compound represented by Formula (6) being from 10 to 50% by weight, based on a total amount of the compound represented by Formula (4), the compound represented by Formula (5) and the compound represented by Formula (6):
wherein W 2 is hydrogen or fluorine; and q is an integer of from 2 to 10.
3. The polymerizable liquid crystal composition according to claim 2 , wherein the proportion of the compound represented by Formula (4) is from 50 to 80% by weight, the proportion of the compound represented by Formula (5) is from 10 to 40% by weight, the proportion of the compound represented by Formula (6) is from 10 to 40% by weight, and the total proportion of the compound represented by Formula (5) and the compound represented by Formula (6) is from 20 to 50% by weight.
4. The polymerizable liquid crystal composition according to claim 2 , wherein the proportion of the compound represented by Formula (4) is from 50 to 80% by weight, the proportion of the compound represented by Formula (5) is from 10 to 40% by weight, the proportion of the compound represented by Formula (6) is from 10 to 40% by weight, the total proportion of the compound represented by Formula (5) and the compound represented by Formula (6) is from 20 to 50% by weight, and W 2 is hydrogen.
5. The polymerizable liquid crystal composition according to claim 2 , wherein the proportion of the compound represented by Formula (4) is from 50 to 90% by weight, the proportion of the compound represented by Formula (5) is from 10 to 50% by weight, and the proportion of the compound represented by Formula (6) is 0% by weight.
6. The polymerizable liquid crystal composition according to claim 2 , wherein the proportion of the compound represented by Formula (4) is from 50 to 90% by weight, the proportion of the compound represented by Formula (5) is 0% by weight, the proportion of the compound represented by Formula (6) is from 10 to 50% by weight.
7. The polymerizable liquid crystal composition according to claim 1 , wherein the composition further comprises a compound represented by Formula (7), and a proportion of the compound represented by Formula (7) is from 1 to 20% by weight based on the total weight of the composition:
wherein R is alkyl having from 1 to 8 carbon atoms; R 3 is alkyl having from 1 to 8 carbon atoms; Y is alkylene having from 1 to 20 carbon atoms; and n is an integer of from 0 to 2.
8. The polymerizable liquid crystal composition according to claim 2 , wherein the composition further comprises a compound represented by Formula (7), and a proportion of the compound represented by Formula (7) is from 1 to 20% by weight based on the total weight of the composition:
wherein R 2 is alkyl having from 1 to 8 carbon atoms; R 3 is alkyl having from 1 to 8 carbon atoms; Y is alkylene having from 1 to 20 carbon atoms; and n is an integer of from 0 to 2.
9. The polymerizable liquid crystal composition according to claim 8 , wherein Y is trimethylene, R 3 is ethyl, and n is 0; and the proportion of the compound represented by Formula (7) is from 1 to 10% by weight.
10. A polymerizable liquid crystal layer formed by applying the polymerizable liquid crystal composition of claim 1 on a glass substrate.
11. The polymerizable liquid crystal layer according to claim 10 , wherein the glass substrate is a glass substrate having a treated surface.
12. The polymerizable liquid crystal layer according to claim 11 , wherein the glass substrate having a treated surface is a glass substrate having a polyimide alignment layer subjected to a rubbing treatment.
13. A polymerizable liquid crystal layer formed by applying the polymerizable liquid crystal composition of claim 2 on a glass substrate having a polyimide alignment layer subjected to a rubbing treatment.
14. A polymerizable liquid crystal layer formed by applying the polymerizable liquid crystal composition of claim 3 on a glass substrate having a polyimide alignment layer subjected to a rubbing treatment, and having an alignment state of homogeneous alignment.
15. A polymerizable liquid crystal layer formed by applying the polymerizable liquid crystal composition of claim 4 on a glass substrate having a polyimide alignment layer subjected to a rubbing treatment, and having an alignment state of homogeneous alignment.
16. A polymerizable liquid crystal layer formed by applying the polymerizable liquid crystal composition of claim 5 on a glass substrate having a polyimide alignment layer subjected to a rubbing treatment, and having an alignment state of homogeneous alignment.
17. A polymerizable liquid crystal layer formed by applying the polymerizable liquid crystal composition of claim 6 on a glass substrate having a polyimide alignment layer subjected to a rubbing treatment, and having an alignment state of hybrid alignment.
18. A polymerizable liquid crystal layer comprising the polymerizable liquid crystal composition of claim 8 on a glass substrate, and having an alignment state of homeotropic alignment.
19. An optically anisotropic liquid crystal thin film having fixed alignment obtained by polymerizing the polymerizable liquid crystal layer of claim 13 .
20. The optically anisotropic liquid crystal thin film according to claim 19 , wherein the thickness of the film is from 0.05 to 5 μm.
21. An optical device comprising the optically anisotropic liquid crystal thin film of claim 19 .
22. A phase retardation plate comprising the optically anisotropic liquid crystal thin film of claim 19 .
23. A polarizing plate comprising the optically anisotropic liquid crystal thin film of claim 19 .
24. An optical device comprising the phase retardation plate of claim 22 .
25. An optical device comprising the polarizing plate of claim 23 .
26. A display device comprising the phase retardation plate of claim 22 .
27. A display device comprising the polarizing plate of claim 23 .
28. A liquid crystal display device comprising the phase retardation plate of claim 22 .
29. A liquid crystal display device comprising the polarizing plate of claim 23 .
30. A liquid crystal display device comprising the optically anisotropic liquid crystal thin film of claim 19 formed on an inner surface of a liquid crystal cell.