OLED device with improved efficiency and lifetime
View Patent ↗An improved OLED structure that enhances both stability and luminance efficiency, includes a substrate; an anode and a cathode; a light-emitting layer disposed between the anode and cathode; and a hole-transporting structure disposed between the light-emitting layer and the anode including two or more sublayers; a first sublayer in contact with the light-emitting layer and including a first hole-transporting material and a first stabilizing dopant, and a second sublayer including a second hole-transporting material and a second stabilizing dopant, and a third dopant having a bandgap that is smaller than each of the bandgaps of the second hole-transporting material and the second stabilizing dopant, respectively.
1. An organic electroluminescent device, comprising:
a) a substrate;
b) an anode and a cathode;
c) a light-emitting layer disposed between the anode and cathode including a host and a light-emitting dopant according to formula M1;
wherein:
A and A′ represent independent azine ring systems corresponding to 6-membered aromatic ring systems containing at least one nitrogen;
(X a ) n and (X b ) m represent one or more independently selected substituents and include acyclic substituents or we joined to form a ring fused to A or A′;
m and n are independently (I) to 4;
Z a and Z b are independently selected substituents;
1,2,3,4,1′,2′,3′,4′ are independently selected as either carbon or nitrogen atoms; and provided that X a , X b , Z a and Z b , 1,2,3,4,1′,2′,3′,4′ are selected to provide blue luminescence; and
d) a hole-transporting structure disposed between the light-emitting layer and the anode including three sublayers, a first sublayer in contact with the light-emitting layer and including a first hole-transporting material and a first stabilizing dopant which is an anthracene, and a second sublayer in contact with the first sublayer including a second hole-transporting material and a second stabilizing dopant which is an anthracene, and a third dopant having a bandgap that is smaller than each of the bandgaps of the second hole-transporting material and the second stabilizing dopant, respectively and the third sublayer including a hole-transporting material disposed between the second sublayer and the anode.
2. The organic electroluminescent device of claim 1 wherein the third dopant is a Rubrene derivative.
3. The organic electroluminescent device of claim 1 wherein the third dopant is a red emitting dopant including a diindenoperylene compound of the following structure Q1:
wherein X 1 -X 16 are independently selected as hydrogen or substituents selected to provide red luminescence.
4. The organic electroluminescent device of claim 3 wherein the third dopant includes diindenoperylene compound selected from the following structures:
5. The organic electroluminescent device of claim 1 wherein the thickness of the first sublayer is in a range of from 5 nm to 50 nm.
6. The organic electroluminescent device of claim 1 wherein the first and second hole-transporting materials are the same and wherein the first and second stabilizing dopants are the same.
7. The organic electroluminescent device of claim 1 further including a hole injecting layer including a fluorocarbon compound, hexaazatriphenylene derivatives, porphyrinic compounds, m-MTDATA (4,4′,4″-tris[(3-methylphenyl)phenyl-amino]triphenylamine), or inorganic oxides including vanadium oxide (VOx), molybdenum oxide (MoOx), nickel oxide (NiOx) or tungsten oxide (WOx).