IP Library Granted Patent US 7,594,430
Granted Patent B2
US 7,594,430 · App. 11/393,823 · Granted Sep 29, 2009

Methods for monitoring fouling of aqueous systems including enhanced heat exchanger tubes

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Quick Facts
Patent No.
US 7,594,430
App. No.
11/393,823
Granted
Sep 29, 2009
Kind
B2
Abstract

Novel methods for monitoring and recording fouling of aqueous systems are disclosed. The methods employ a heat transfer test assembly including an outer tube member, a heating rod positioned within the outer tube member, a ribbed tube sleeve fitted over the heating rod and thermocouples for sensing the wall temperature of heating rod. The heat transfer test assembly is connected to a monitoring and recording assembly that is connected to or includes a piping assembly. The piping assembly and the heat transfer test assembly are placed in fluid communication with a heat exchanger. Fouling determinations of fluid flowing through the piping assembly are made at varying flow rates with simultaneous monitoring and recording of the flow rates together with data, such as corrosion, pH, conductivity, and the like.

Claims (44)

1. A process for monitoring the biofouling of a fluid flowing through a heat exchanger containing one or more internally enhanced tubes, wherein said process utilizes a heat test transfer assembly having an externally enhanced tube sleeve, said method comprising the steps of:

(a) connecting a heat transfer test assembly to a recording and monitoring assembly including or connected to a piping assembly having a fluid test zone, such that said heat transfer test assembly and said monitoring and recording assembly are in fluid flow communication with the fluid flowing through the heat exchanger having one or more internally enhanced tubes;

(b) measuring a temperature of said fluid as said fluid enters the test zone;

(c) energizing the heating rod in the test zone;

(d) measuring the wall temperature of the heating rod during passage of said fluid through said test zone;

(e) measuring the flow rate of said fluid through said test zone;

(f) monitoring and measuring a parameter of said fluid in said test zone, wherein said parameter is selected from the group consisting of corrosion, pH, ORP and conductivity;

(g) recording data from steps (b), (d) and (f); and

(h) computing a u-coefficient and/or fouling factor;

wherein the heat transfer test assembly comprises:

an outer tube member;

a heating rod positioned coaxially within the outer tube member, said heating rod comprising means for sensing a wall temperature of said heating rod;

a ribbed tube sleeve having ribs on an outside surface thereof coaxially fitted over the heating rod within the outer tube member; and

an annular fluid flow passageway disposed between the tube sleeve and the outer tube member.

2. The process of claim 1 comprising adding a biodispersant to said fluid passing through said heat exchanger to maintain fouling of said heat exchanger within predetermined limits.

3. The process of claim 2 wherein said monitoring and recording assembly is an integrated cooling water analyzer comprising said heat transfer test assembly.

4. The process of claim 3 wherein said monitoring and recording assembly is a mobile assembly.

5. The process of claim 1 , wherein the outer tube member is constructed of a transparent material.

6. The process of claim 1 , wherein the means for sensing the wall temperature of said heating rod comprise at least one thermocouple.

7. The process of claim 1 , wherein the ribbed tube sleeve is constructed of a material selected from the group consisting of: stainless steel, copper, copper alloy, titanium and carbon steel.

8. The process of claim 1 , wherein the heating rod comprises a tubular member in which a heating element is embedded within an insulating matrix.

9. The process of claim 1 where in the process is continuously monitored with a programmable logic controller.

10. A process for monitoring the biofouling of a fluid flowing through a heat exchanger containing one or more internally enhanced tubes, wherein said process utilizes a heat test transfer assembly having an externally enhanced tube sleeve, said method comprising the steps of:

(a) connecting a heat transfer test assembly to a recording and monitoring assembly including or connected to a piping assembly having a fluid test zone, such that said heat transfer test assembly and said monitoring and recording assembly are in fluid flow communication with the fluid flowing through a heat exchanger having one or more internally enhanced tubes;

(b) measuring a temperature of said fluid in the test zone;

(c) energizing the heating rod in the test zone;

(d) measuring the wall temperature of the heating rod during passage of said fluid through said test zone;

(e) measuring the flow rate of said fluid through said test zone;

(f) monitoring and measuring a parameter of said fluid in said test zone, wherein said parameter is selected from the group consisting of corrosion, pH, ORP and conductivity;

(g) recording data from steps (b), (d) and (f); and

(h) computing a u-coefficient and/or fouling factor;

wherein the heat transfer test assembly comprises:

an outer tube member;

a heating rod positioned coaxially within the outer tube member, said heating rod comprising means for sensing a wall temperature of said heating rod;

a tube sleeve assembly coaxially fitted over the heating rod within the outer tube member, wherein said tube sleeve assembly comprises a ribbed sleeve section having ribs on an outside surface thereof, an upstream flow transition section positioned upstream of and butted against an upstream end of the ribbed sleeve section, and a downstream flow transition section positioned downstream of and butted against a downstream end of the ribbed sleeve section; and

an annular fluid flow passageway disposed between the tube sleeve assembly and the outer tube member.

11. The process of claim 10 , comprising adding a biodispersant to said fluid passing through said heat exchanger to maintain fouling of said heat exchanger within acceptable limits.

12. The process of claim 11 wherein said monitoring and recording assembly is an integrated cooling water analyzer comprising said heat transfer test assembly.

13. The process of claim 12 wherein said monitoring and recording assembly is a mobile assembly.

14. The process of claim 10 , wherein the outer tube member is constructed of a transparent material.

15. The process of claim 10 , wherein the means of sensing the wall temperature of said heating rod comprise at least one thermocouple.

16. The process of claim 10 , wherein the tube sleeve assembly is constructed of a material selected from the group consisting of: stainless steel, copper, copper alloy, titanium and carbon steel.

17. The process of claim 10 , wherein the heating rod comprises a tubular member in which a heating element is embedded within an insulating matrix.

18. The process of claim 10 where in the process is continuously monitored with a programmable logic controller.

Assignments (25)
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058856/0724 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CITIBANK, N.A.
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058848/0636 →
SECOND LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 046629/0213 →
INTELLECTUAL PROPERTY FIRST LIEN SECURITY AGREEMENT RELEASE Recorded Jul 20, 2018
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 046594/0252 →
INTELLECTUAL PROPERTY SECOND LIEN SECURITY AGREEMENT RELEASE Recorded Jul 20, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 047058/0800 →
FIRST LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CITIBANK, N.A., COLLATERAL AGENT
Reel/Frame 046595/0241 →
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS (SECOND LIEN) Recorded Aug 14, 2014
From: SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 033535/0847 →
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Aug 14, 2014
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 033535/0806 →
U.S. ASSIGNMENT OF PATENTS Recorded Aug 4, 2014
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 033471/0048 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Sep 15, 2011
From: BANK OF AMERICA, N.A.
To: ASHLAND, INC.; ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
Reel/Frame 026927/0247 →
SECURITY AGREEMENT Recorded Apr 14, 2010
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 024225/0289 →
RELEASE OF SECURITY INTEREST Recorded Apr 13, 2010
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
Reel/Frame 024218/0928 →
SUPPLEMENTAL PATENT SECURITY AGREEMENT Recorded Nov 23, 2009
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 023556/0362 →