Toughened poly(lactic acid) compositions
View Patent ↗Toughened poly(lactic acid) resin compositions comprising poly(lactic acid) and an impact modifier comprising an ethylene copolymer made from monomers (a) ethylene; (b) one or more olefins of the formula CH 2 ═C(R 1 )CO 2 R 2 , where R 1 is hydrogen or an alkyl group with 2-8 carbon atoms and R 2 is an alkyl group with 1-8 carbon atoms, such as methyl, ethyl, or butyl; and (c) one or more olefins of the formula CH 2 ═C(R 3 )CO 2 R 4 , where R 3 is hydrogen or an alkyl group with 1-6 carbon atoms, such as methyl, and R 4 is glycidyl. The ethylene copolymer may further be made from carbon monoxide monomers. The compositions may further comprise one or more ethylene/acrylate and/or ethylene/vinyl ester polymers, ionomers, and cationic grafting agents.
1. A poly(lactic acid) composition comprising
(i) about 60 to about 99.5 weight % poly(lactic acid), and
(ii) about 0.5 to about 40 weight % of an impact modifier comprising an ethylene copolymer derived from copolymerizing:
(a) about 20 to about 95 weight % ethylene;
(b) about 3 to about 70 weight % of one or more olefins of the formula CH 2 ═C(R 1 )CO 2 R 2 , where R 1 is hydrogen or an alkyl group with 1-8 carbon atoms and R 2 is an alkyl group with 1-8 carbon atoms; and
(c) about 0.5 to about 25 weight % of one or more olefins of the formula CH 2 ═C(R 3 )CO 2 R 4 , where R 3 is hydrogen or an alkyl group with 1-6 carbon atoms, and R 4 is glycidyl,
wherein the weight % of the poly(lactic acid) and the impact modifier are based on the total weight of the poly(lactic acid) and the impact modifier.
2. The composition of claim 1 , wherein the impact modifier is present in the composition in about 0.2 to about 20 weight %.
3. The composition of claim 1 , wherein the impact modifier is present in the composition in about 0.5 to about 3 weight %.
4. The composition of claim 1 , wherein (a) is about 40 to about 90 weight % ethylene.
5. The composition of claim 1 , wherein (a) is about 50 to about 80 weight % ethylene.
6. The composition of claim 1 , wherein (b) is about 20 to about 35 weight % of one or more olefins of the formula CH 2 ═C(R 1 )CO 2 R 2 , where R 1 is hydrogen or an alkyl group with 1-8 carbon atoms and R 2 is an alkyl group with 1-8 carbon atoms.
7. The composition of claim 1 , wherein (c) is about 3 to about 17 weight % of at least one olefin of the formula CH 2 ═C(R 3 )CO 2 R 4 , where R 3 is hydrogen or an alkyl group with 1-6 carbon atoms, and R 4 is glycidyl.
8. The composition of claim 1 , wherein the ethylene copolymer is further derived from copolymerizing (d) 0 to about 20 weight % carbon monoxide.
9. The composition of claim 1 wherein (b) is butyl acrylate and (c) is glycidyl methacrylate.
10. The composition of claim 1 wherein the impact modifier (ii) further comprises about 1 to about 75 weight % of one or more ionomers, based on the total weight of the impact modifier.
11. The composition of claim 1 , wherein the impact modifier (ii) further comprises 10 to 50 weight % of one or more ionomers, based on the total weight of the impact modifier.
12. The composition of claim 1 , wherein the impact modifier (ii) further comprises up to about 90 weight % of one or more copolymers of ethylene and an acrylate ester or vinyl acetate, based on the total weight of the impact modifier.
13. The composition of claim 1 , wherein the impact modifier (ii) further comprises up to about 75 weight % of one or more copolymers of ethylene and an acrylate ester or vinyl acetate, based on the total weight of the impact modifier.
14. The composition of claim 1 , wherein the impact modifier (ii) further comprises up to about 50 weight % of one or more copolymers of ethylene and an acrylate ester or vinyl acetate, based on the total weight of the impact modifier.
15. The composition of claim 1 , further comprising one or more cationic grafting catalysts.
16. The composition of claim 12 , wherein the cationic grafling catalysts are selected from the group consisting of salts of hydrocarbon mono-, di-, or polycarboxylic acids.
17. The composition of claim 12 wherein the cationic grafling catalysts are one or more of stannous octanoate, zinc stearate, and zinc diacetate.
18. A molded article comprising the composition of claim 1 .
19. An extruded article comprising the composition of claim 1 .
20. A thermoformed article comprising the composition of claim 1 .