Solid state deformation processing of crosslinked high molecular weight polymeric materials
View Patent ↗Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a desirable combination of physical and chemical properties. Crosslinked bulk materials are heated to a compression deformable temperature, and pressure is applied to change a transverse dimension of the material. After cooling and stress relieving, a treated bulk material is obtained that has enhanced tensile strength in the axial direction orthogonal to the dimension change. In preferred embodiments, medical implant bearing materials are machined from the treated bulk material with the in vivo load bearing axis substantially parallel or coincident with the axial direction of the treated bulk material.
1. A method for reducing the free radical concentration in irradiated crosslinked bulk polymer, the polymer being in the form of a bulk material elongated in an axial direction, the method comprising:
heating the crosslinked bulk material to a compression deformable temperature;
applying a force to deform the heated bulk material in a direction orthogonal to the axial direction by extruding the heated bulk material through an isoareal die; and
cooling the polymer to a solidification temperature.
2. A method according to claim 1 , wherein the bulk polymer is irradiated with gamma-irradiation.
3. A method according to claim 1 , wherein the bulk polymer comprises UHMWPE.
4. A method according to claim 3 , wherein the bulk polymer comprises a bar having a circular cross-section.
5. A method according to claim 4 , wherein the circular cross-section has a diameter of from 2-4 inches.
6. A method according to claim 5 , wherein the circular cross-section has a diameter of about 3 inches.
7. A method according to claim 1 , comprising multiple extrusion through a single die and/or extrusion through a plurality of dies.
8. A method according to claim 1 , wherein the compression deformable temperature is less than the crystalline melting point of the polymer.
9. A method of processing a crosslinked polymeric material, the material in a bulk form characterized by an axial direction, and further characterized by a cross section having an area A in a transverse section perpendicular to the axial direction, the method comprising
heating the polymeric material to a compression deformable temperature;
deforming the heated material by extruding it through a die that changes the dimensions of the cross-section, but that leaves the cross-sectional area A essentially unchanged; and
cooling the extruded material.
10. A method according to claim 9 , wherein the extruded material is characterized by a free radical concentration less than that of the crosslinked material before extrusion.
11. A method according to claim 9 , wherein the compression deformable temperature is below the melting point.
12. A method according to claim 9 , wherein the polymeric material is in the form of a cylinder.
13. A method according to claim 12 , wherein the cylinder has a circular cross-section perpendicular to the axial direction of the cylinder.
14. A method according to claim 9 , wherein the polymeric material comprises UHMWPE.
15. A method according to claim 14 , wherein the UHMWPE is crosslinked by gamma-irradiation at a dose of 1 to 100 MRad.
16. A method according to claim 14 , wherein the polymeric material is in the form of a cylinder.
17. A method according to claim 16 , wherein the cylinder has a circular cross- section perpendicular to the axial direction of the cylinder.
18. A method according to claim 14 , further comprising machining a medical implant bearing component from the extruded material, wherein the load bearing axis of the implant is substantially coincident with the axial direction of the polymeric material.
19. A method of making a medical implant bearing component, comprising:
crosslinking a UHMWPE bulk material to produce a free radical concentration greater than 0.06×10 15 spins per gram;
heating the crosslinked UHMWPE to a compression deformable temperature;
extruding the heated UHMWPE, in the form of an elongate bulk material comprising a main axis defining an axial direction, and further characterized by a cross-section perpendicular to the axial direction, the extruding being though a die that has a shape different from that of the cross-section, but having an area essentially the same as the area of the cross-section; and
further processing the extruded UHMWPE to make the bearing component.
20. A method according to claim 19 , comprising exposing the UHMWPE bulk material to gamma-irradiation at a dose of about 0.01 to about 100 MRad.
21. A method according to claim 19 , wherein the compression deformable temperature is less than the melting point.
22. A method according to claim 19 , wherein the compression deformable temperature is above 80° C. and less than the crystalline melting point of the UHMWPE.
23. A method according to claim 19 , wherein the cross-section of the UHMWPE bulk material is essentially circular.
24. A method according to claim 19 , wherein the shape of the die is a smooth convex shape.
25. A method according to claim 19 , wherein the shape of the die is elliptical.