Method for fabricating a medical device that includes a capacitor that does not require oxide reformation
View Patent ↗A therapeutic medical device system comprising an electrolytic capacitor including an anode, cathode and an electrolyte. The anode is anodized in an electrolyte comprises an aqueous solution of alkanol amine, phosphoric acid and an organic solvent preferably defined by formula 1: CH 3 —(OCH 2 CH 2 ) m —OCH 3 Formula 1 wherein m is an integer from 3 to 10.
1. A method for fabricating a medical device comprising:
forming a capacitor comprising the steps of:
preparing a metal anode from a valve metal powder comprising anodizing the metal anode with an aqueous anodizing electrolyte comprising phosphoric acid, at least one organic solvent and alkanolamine;
providing a cathode;
activating said anode and said cathode with a working electrolyte;
incorporating said capacitor into a circuit; and
incorporating said circuit in said medical device without oxide reformation.
2. A method according to claim 1 wherein said anode comprises a metal selected from a group consisting of titanium, tungsten, chromium, aluminium, zirconium, hafnium, zinc, vanadium, niobium, bismuth, antimony and tantalum.
3. A method according to claim 2 wherein said anode is tantalum.
4. A method according to claim 1 wherein said cathode is a conductive metal provided with a semiconductive or metal-like conductive coating.
5. A method according to claim 4 wherein said cathode is at least one material chosen from a group consisting of carbon or an oxide, nitride, or carbide of a metal.
6. A method according to claim 5 wherein said cathode comprises a metal selected from a group consisting of tantalum, titanium, nickel, iridium, platinum, palladium, gold, silver, cobalt, molybdenum, ruthenium, manganese, tungsten, iron, zirconium, hafnium, rhodium, vanadium, osmium and niobium.
7. A method according to claim 6 wherein said cathode comprises a porous ruthenium oxide film provided on a titanium substrate.
8. A method according to claim 1 wherein said anodizing electrolyte has a pH of about 4 to about 9.
9. A method according to claim 1 wherein said anodizing electrolyte comprises about 0.1% to about 2.0%, by weight, phosphoric acid, about 1% to about 70%, by weight, of at least one organic solvent and about 0.1% to about 10%, by weight, of at least one alkanolamine.
10. A method according to claim 9 wherein said anodizing electrolyte comprises about 0.1% to about 6%, by weight, of said alkanolamine.
11. A method according to claim 9 wherein said anodizing electrolyte comprises about 5% to about 35%, by weight of said organic solvent.
12. A method according to claim 9 wherein said anodizing electrolyte comprises about 50% to about 70%, by weight of said organic solvent.
13. A method according to claim 1 wherein said organic solvent is selected from the group consisting of monomeric glycols, glycerine, polyethylene glycols, polyethylene glycol monomethyl ethers, polyethylene glycol dimethyl ethers, 2-methyl-1,3-propanediol, diethylene glycol, N-alkyl-2-pyrrolidones and mixtures thereof.
14. A method according to claim 13 wherein said organic solvent is a compound of Formula 1:
CH 3 —(OCH 2 CH 2 ) m —OCH 3 Formula 1
wherein m is an integer from 3 to 10.
15. A method according to claim 14 wherein said m is an integer from 3 to 5.
16. A method according to claim 15 wherein said m is 4.
17. A method according to claim 1 wherein said alkanolamine is selected from a group consisting of monoethanol amine, diethanol amine, triethanol amine, ethyl diethanolamine, diethyl ethanolamine, dimethyl ethanolamine and dimethyl amino ethoxy ethanol.
18. A method according to claim 1 comprising about 25 to about 50%, by weight, said organic solvent.
19. A method according to claim 1 wherein said anodizing electrolyte has a pH of about 3 to about 9.