Flexible packaging laminate films including a block copolymer layer
View Patent ↗What is claimed is a flexible packaging film having improved toughness without compromise of other physical properties. The flexible packaging film is a laminate of at least two film layers of a polyolefin and at least one film layer of a block copolymer. The block copolymer employed in the present invention is a selectively hydrogenated high vinyl block copolymer.
1. A flexible packaging laminate film comprising at least two polyolefin layers and at least one block copolymer layer, wherein said block copolymer comprises a selectively hydrogenated high vinyl block copolymer having at least one A 1 block and at least one B 1 block and having the general formula:
A 1 -B 1 -A 1 ,(A 1 -B 1 ) n , (A 1 -B 1 ) n A 1 , or (A 1 -B 1 ) n X
or mixtures thereof, wherein
(1) each A 1 , prior to hydrogenation, is predominantly a polymerized monoalkenyl arene hydrocarbon block having a molecular weight of from 4,000 to 45,000;
(2) each B 1 , prior to hydrogenation, is predominantly a polymerized conjugated diene hydrocarbon block selected from the group consisting of polybutadiene, polyisoprene, polypentadiene, polyhexadiene and mixtures thereof, having a molecular weight of from 20,000 to 300,000 when the block copolymer is sequential and from 10,000 to 150,000 when the block copolymer is coupled;
(4) n has a value of 2 to 30 and X is a coupling agent residue;
(5) the monoalkenyl arene content of the block copolymer is from 8 to 40 weight percent;
(6) the vinyl content of the conjugated diene hydrocarbon block prior to hydrogenation is from 60 to 85 mol percent;
(7) subsequent to hydrogenation less than 50 percent of the monoalkenyl aromatic double bonds have been hydrogenated and at least 80 percent of the conjugated diene double bonds have been hydrogenated; and
(8) the melt index of the block copolymer is from 1 to 40 grams/10 minutes according to ASTM D1238 at 230° C. and 2,16 kg weight.
2. The flexible packaging laminate film of claim 1 wherein said laminate comprises from 3 to 15 layers.
3. The flexible packaging laminate film of claim 2 wherein A1 is styrene, B1 is butadiene, and each polyolefin layer independently comprises polyolefins selected from low density polyethylene (LDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), very low density polyethylene (VLDPE), medium density polyethylene (MDPE), polypropylene (PP), copolymers of ethylene and vinyl alcohol, or a copolymer of ethylene and vinyl acetate.
4. The flexible packaging laminate film of claim 3 wherein each A 1 , prior to hydrogenation, has a molecular weight of from 5,000 to 15,000; each B 1 , prior to hydrogenation, has a molecular weight of from 35,000 to 175,000 when the block copolymer is sequential and from 17,500 to 87,500 when the block copolymer is coupled.
5. The flexible packaging laminate film of claim 4 wherein the monoalkenyl arene content of the block copolymer is from 10 to 20 weight percent, and the melt index is from 1 gram/10 minutes to 25 grams/10 minutes.
6. The flexible packaging laminate film of claim 5 wherein said block copolymer layer comprises block copolymer and one or more polyolefins wherein the ratio of block copolymer to polyolefin in said block copolymer layer is from 30:70 to 90:10.
7. The flexible packaging laminate film of claim 6 wherein the ratio is from 40:60 to 60:40.
8. The flexible packaging laminate film of claim 5 wherein the melt flow index is from 3 grams/10 minutes to 10 grams/10 minutes.
9. The flexible packaging laminate film of claim 5 wherein the melt flow index is from 15 grams/10 minutes to 25 grams/10 minutes.
10. The flexible packaging laminate film of claim 5 wherein the block copolymer is a coupled block copolymer and n has a value of 2 to 6.
11. The flexible packaging laminate film of claim 5 wherein (1) the polyolefins are polypropylene and polyethylene; and (2) subsequent to hydrogenation from 0 to 30 percent of the monoalkenyl arene double bonds have been hydrogenated and at least 90 percent of the conjugated diene double bonds have been hydrogenated.
12. The flexible packaging laminate film of claim 3 wherein said polyolefin is present in a concentration from 50% to 90% and said styrenic block copolymer is present in a concentration from 10% to 50%, said percentages being by weight, based on the total weight of said packaging film.
13. The flexible packaging laminate film of claim 1 wherein said laminate film comprises one block copolymer layer and two polyolefin layers wherein said block copolymer layer is sandwiched between said two polyolefin layers.
14. The flexible packaging laminate film of claim 13 wherein A1 is styrene, B1 is butadiene and each polyolefin layer independently comprises polyolefins selected from low density polyethylene (LDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), very low density polyethylene (VLDPE), medium density polyethylene (MDPE), polypropylene (PP), copolymers of ethylene and vinyl alcohol, or a copolymer of ethylene and vinyl acetate.
15. The flexible packaging laminate film of claim 14 wherein each A1, prior to hydrogenation, has a molecular weight of from 5,000 to 15,000; each B1, prior to hydrogenation, has a molecular weight of from 35,000 to 175,000 when the block copolymer is sequential and from 17,500 to 87,500 when the block copolymer is coupled.
16. The flexible packaging laminate film of claim 15 wherein the monoalkenyl arene content of the block copolymer is from 10 to 20 weight percent and the melt index is from 1 gram/10 minutes to 25 grams/10 minutes.
17. The flexible packaging laminate film of claim 16 wherein said block copolymer layer comprises block copolymer and one or more polyolefins wherein the ratio of block copolymer to polyolefin in said block copolymer layer is from 30:70 to 90:10.
18. The flexible packaging laminate film of claim 17 wherein the ratio is from 40:60 to 60:40.
19. The flexible packaging laminate film of claim 16 wherein the melt flow index is from 3 grams/10 minutes to 10 grams/10 minutes.
20. The flexible packaging laminate film of claim 16 wherein the melt flow index is from 15 grams/10 minutes to 25 grams/10 minutes.
21. The flexible packaging laminate film of claim 16 wherein the block copolymer is a coupled block copolymer and n has a value of 2 to 6.
22. The flexible packaging laminate film of claim 16 wherein (1) the polyolefins are polypropylene and polyethylene; and (2) subsequent to hydrogenation from 0 to 30 percent of the inonoalkenyl arene double bonds have been hydrogenated and at least 90 percent of the conjugated diene double bonds have been hydrogenated.
23. The flexible packaging laminate film of claim 16 wherein said polyolefin layers are the same polyolefin.
24. The flexible packaging laminate film of claim 16 wherein said polyolefin layers are different polyolefins.
25. The flexible packaging laminate film of claim 14 wherein said polyolefin is present in a concentration from 50% to 90% and said styrenic block copolymer is present in a concentration from 10% to 50%, said percentages being by weight, based on the total weight of said packaging film.