Process for the production of isocyanates
View Patent ↗Isocyanates are produced by a) reacting at least one amine with phosgene, optionally in the presence of a solvent to produce the corresponding isocyanate and a stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances is obtained, b) separating the stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances in an at least two-stage sequence of absorption steps that includes (1) at least one isothermal absorption step and (2) at least one adiabatic absorption step, to obtain (i) a hydrogen chloride stream containing phosgene in concentrations of at most 0.5 wt. % (based on the weight of the hydrogen chloride stream) and (ii) a liquid phosgene stream, and c) recycling the liquid phosgene stream (ii) to the reaction of amine with phosgene.
1. A process for the production of an isocyanate comprising:
a) reacting at least one amine with phosgene, optionally in the presence of a solvent, to produce a corresponding isocyanate and a stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances,
b) separating the stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances in an at least two-stage sequence of absorption steps comprising (1) at least one isothermal absorption step and (2) at least one adiabatic absorption step to obtain (i) a hydrogen chloride stream containing no more than 0.5 wt. % phosgene, based on total weight of the hydrogen chloride stream and (ii) a liquid phosgene stream, and
c) recycling the liquid phosgene stream (ii) to step a).
2. The process of claim 1 in which the reaction in step a) is carried out in the gaseous phase.
3. The process of claim 2 in which the liquid phosgene stream (ii) contains from 20 to 80 wt. % of phosgene, based on total weight of the liquid phosgene stream.
4. The process of claim 2 in which phosgene is separated by desorption from the liquid phosgene stream (ii) and the separated phosgene is used in step a).
5. The process of claim 1 in which the reaction in step a) is carried out in the liquid phase in the presence of a solvent.
6. The process of claim 5 in which the solvent used in step a) is used in step b) as an absorption agent in the at least one isothermal absorption step and the at least one adiabatic absorption step.
7. The process of claim 6 in which the liquid phosgene stream (ii) contains from 20 to 80 wt. % of phosgene, based on total weight of the liquid phosgene stream.
8. The process of claim 7 in which the liquid phosgene stream (ii) is used in step a).
9. The process of claim 5 in which phosgene is partially condensed out from the stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances before separation in the at least two-stage sequence of absorption steps.
10. The process of claim 9 in which vapors from the partial condensation of the phosgene are washed in co-current with the solvent used in step a).
11. The process of claim 5 in which the isothermal absorption (1) and the adiabatic absorption (2) are carried out in counter-current.
12. The process of claim 5 in which the hydrogen chloride stream (i) is used in step a).
13. The process of claim 1 in which the liquid phosgene stream (ii) is purified by stripping hydrogen chloride and low-boiling compounds from the liquid phosgene stream (ii) and the purified phosgene stream is used in step a).