Thermal method for fabricating a hydrogen separation membrane on a porous substrate
View Patent ↗A thermal method of making a hydrogen permeable composition is disclosed. A mixture of metal oxide powder and ceramic oxide powder and optionally a pore former is formed and pressed to form an article. The article is dried at elevated temperatures and then sintered in a reducing atmosphere to provide a dense hydrogen permeable portion near the surface of the sintered mixture. The dense hydrogen permeable portion has a higher initial concentration of metal than the remainder of the sintered mixture and is present in the range of from about 20 to about 80 percent by volume of the dense hydrogen permeable portion.
1. A method of making a hydrogen permeable composition, comprising
forming a mixture of metal oxide powder and ceramic oxide powder and optionally a pore former,
pressing the mixture to form an article,
pre-sintering the article at about 700° C. in air to remove at least some of the pore former if present and to impart mechanical integrity and porosity to the article, and thereafter providing a dense hydrogen permeable portion near the surface of the sintered mixture and a porous core having a lower density relative to the dense surface layer by sintering the article in a reducing atmosphere comprising hydrogen to reduce metal oxide near the surface of the article to a metal and leave metal oxide in the core of the article,
the dense hydrogen permeable portion having a higher initial concentration of metal than the remainder of the sintered mixture,
the metal oxide being selected from the oxides of Ni, Pd, Pd alloys, Nb, Ta, Zr, V or mixtures thereof,
the ceramic oxide being selected from yttria stabilized zirconia, shrinkable alumina, Y or Gd doped cerates, titanates, zirconates of barium or strontium or mixtures thereof,
wherein the dense hydrogen permeable portion has a metal concentration in the range of from about 20 to about 80 percent by volume.
2. The method of claim 1 , wherein the pore former is selected from graphite, corn starch, organic grains, glass beads or mixtures thereof.
3. The method of claim 1 , wherein the reducing atmosphere includes nitrogen.
4. The method of claim 1 , wherein the average diameters of the powders are in the range of from about 0.1 to about 5 microns.
5. The method of claim 4 , wherein the average diameters of the powders are in the range of from about 0.1 to about 1 micron.
6. The method of claim 1 , wherein the dense hydrogen permeable portion of composition is at least about 96% of theoretical density.
7. The method of claim 1 , wherein the metal oxide powder is selected from the oxides of Ni, Pd, Pd alloys, and mixtures thereof.
8. The method of claim 1 , wherein the ceramic oxide powder is selected from yttria stabilized zirconia, Y or Gd doped cerates of barium or strontium or mixtures thereof.
9. The method of claim 1 , wherein the metal oxide powder is selected from the oxides of Ni, Pd, Pd alloys and mixtures thereof and the ceramic oxide powder is selected from yttria stabilized zirconia, Y or Gd doped cerates of barium or strontium and mixtures thereof.
10. The method of claim 1 , wherein the coefficients of thermal expansion of the dense hydrogen permeable portion and the remainder of the composition are within about 10% of each other.
11. A method of making a hydrogen permeable composition, comprising
forming a mixture of metal oxide powder and ceramic oxide powder and a pore former,
pressing the mixture to form an article, pre-sintering the article at about 700° C. in air to remove at least some of the pore former if present and to impart mechanical integrity and porosity to the article, and thereafter providing a dense hydrogen permeable portion near the surface of the sintered mixture and a porous core having a lower density relative to the dense surface layer by sintering the article in a reducing atmosphere comprising hydrogen to reduce metal oxide near the surface of the article to a metal and leave metal oxide in the core of the article,
the dense hydrogen permeable portion having a higher initial concentration of metal than the remainder of the sintered mixture,
the metal oxide being selected from the oxides of Ni, Pd, Pd alloys, Nb, Ta, Zr, V or mixtures thereof,
the ceramic oxide being selected from yttria stabilized zirconia, shrinkable alumina, Y or Gd doped cerates, titanates, zirconates of barium or strontium or mixtures thereof,
wherein the dense hydrogen permeable portion has a metal concentration in the range of from about 20 to about 80 percent by volume.
12. The method of claim 11 , wherein the sintering takes place at temperatures greater than about 1000° C.
13. The method of claim 12 , wherein at least some of the sintering takes place at a temperature greater than about 1400° C.
14. The method of claim 11 , wherein the pore former is vaporizable at temperatures less than about 1000° C.