Interlayers comprising modified fumed silica
View Patent ↗The present invention includes polymer interlayers that are used in multiple layer glazing panels. Interlayers of the present invention comprise a thermoplastic polymer, a plasticizer, and a fumed silica that has been modified to impart hydrophobic character. Interlayers incorporating such components have improved tensile modulus, moisture resistance, creep performance, anticorrosion effect, glass adhesion, and are well suited to a variety of applications, including, but not limited to, acoustic applications.
1. An interlayer for use in a multiple layer glazing, comprising:
a thermoplastic polymer; and,
fumed silica, wherein said fumed silica is alkylated and wherein said interlayer comprises more than one polymer sheet.
2. The interlayer of claim 1 , wherein said fumed silica has a carbon content of at least 0.5 weight percent.
3. The interlayer of claim 1 , wherein said fumed silica is methylated.
4. The interlayer of claim 1 , wherein said fumed silica has an average aggregate length of 0.15 to 0.35 microns.
5. The interlayer of claim 1 , wherein said fumed silica has an average aggregate length of 0.2 to 0.3 microns.
6. The interlayer of claim 1 , wherein said interlayer comprises a polymer sheet having 10 to 70 parts per hundred resin of said plasticizer and 0.05 to 15 parts per hundred resin of said fumed silica.
7. The interlayer of claim 1 , wherein said interlayer comprises a polymer sheet having 20 to 60 parts per hundred resin of said plasticizer and 0.1 to 10 parts per hundred resin of said fumed silica.
8. The interlayer of claim 1 , wherein said thermoplastic polymer comprises a polymer selected from the group consisting of poly(vinyl butyral), poly(vinyl chloride), poly(ethylene-co-vinyl acetate), poly(ethylene-co-ethyl acrylate), ionomers of partially neutralized ethylene/(meth)acrylic acid copolymer, polyethylene, polyethylene copolymers, polyurethane, and poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester.
9. An interlayer for use in a multiple layer glazing, comprising:
a polymer sheet comprising:
poly(vinyl butyral);
plasticizer; and,
fumed silica, wherein said fumed silica is alkylated, wherein said interlayer comprises more than one polymer sheet, and wherein said interlayer comprises a polymer sheet having a glass transition temperature of less than 40° C.
10. The interlayer of claim 9 , wherein said fumed silica has a carbon content of at least 0.5 weight percent.
11. The interlayer of claim 9 , wherein said fumed silica is methylated.
12. The interlayer of claim 9 , wherein said fumed silica has an average aggregate length of 0.15 to 0.35 microns.
13. The interlayer of claim 9 , wherein said fumed silica has an average aggregate length of 0.2 to 0.3 microns.
14. The interlayer of claim 9 , wherein said interlayer comprises a polymer sheet having 10 to 70 parts per hundred resin of said plasticizer and 0.05 to 15 parts per hundred resin of said fumed silica.
15. The interlayer of claim 9 , wherein said interlayer comprises a polymer sheet having 20 to 60 parts per hundred resin of said plasticizer and 0.1 to 10 parts per hundred resin of said fumed silica.
16. A multiple layer glass panel comprising an interlayer, wherein said interlayer comprises:
a thermoplastic polymer; and,
fumed silica, wherein said fumed silica is alkylated and wherein said interlayer comprises more than one polymer sheet.
17. The panel of claim 16 , wherein said fumed silica has a carbon content of at least 0.5 weight percent.
18. The panel of claim 16 , wherein said fumed silica is methylated.
19. The panel of claim 16 , wherein said fumed silica has an average aggregate length of 0.15 to 0.35 microns.
20. The panel of claim 16 , wherein said fumed silica has an average aggregate length of 0.2 to 0.3 microns.
21. The panel of claim 16 , wherein said interlayer comprises a polymer sheet having 10 to 70 parts per hundred resin of plasticizer and 0.05 to 15 parts per hundred resin of said fumed silica.
22. The panel of claim 16 , wherein said interlayer comprises a polymer sheet having 20 to 60 parts per hundred resin of plasticizer and 0.1 to 10 parts per hundred resin of said fumed silica.
23. The panel of claim 16 , wherein said thermoplastic polymer comprises a polymer selected from the group consisting of poly(vinyl butyral), poly(vinyl chloride), poly(ethylene-co-vinyl acetate), poly(ethylene-co-ethyl acrylate), ionomers of partially neutralized ethylene/(meth)acrylic acid copolymer, polyethylene, polyethylene copolymers, polyurethane, and poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester.