Polycarbonate compositions and articles formed therefrom
View Patent ↗A polycarbonate composition is disclosed having zero or minimum halogen content, while also exhibiting improved fire-retardance and/or drip-resistant characteristics. The composition comprises an effective amount of a polycarbonate, an anti-dripping agent, an aromatic sulfone sulfonate, an aromatic sulfonate, a synergistic combination of an elastomer-modified graft copolymer and a polysiloxane-polycarbonate copolymer, and an optional siloxane oligomer. The polycarbonate composition is useful for manufacture of electronic and mechanical articles, among others.
1. A composition comprising
(i) 100 parts by weight of polycarbonate;
(ii) from about 0 to about 0.26 parts by weight of an anti-drip agent;
(iii) from about 1×10 −4 parts to about 0.1 parts by weight of an aromatic sulfone sulfonate of Formula K-1:
wherein R 1 , R 2 , and R 3 are independently selected from a C 1 -C 6 alkyl group; M is a metal; n is an integer and 1≦n≦3; w is an integer and 0≦w≦5; p and q are integers, p≧0, q≧0, and p+q≧4;
(iv) from about 1×10 −5 parts to about 0.1 parts by weight of an aromatic sulfonate;
(v) from about 0.1 parts to about 10 parts by weight of an elastomer-modified graft copolymer;
(vi) from about 0.1 parts to about 12 parts by weight of a polysiloxane-polycarbonate copolymer, and
(vii) optionally from about 0.1 parts to about 5 parts by weight of a siloxane oligomer;
wherein the halogen content from the anti-drip agent is from 0 to less than about 0.1 percent by weight based on the total weight of the composition; and
wherein a molded sample of the composition has a UL 94 flammability V0rating at 1.2 mm.
2. The composition according to claim 1 , wherein the halogen content from the anti-drip agent is less than about 0.075 percent by weight based on the total weight of the composition.
3. The composition according to claim 2 , wherein the halogen content from the anti-drip agent is less than about 0.05 percent by weight based on the total weight of the composition.
4. The composition according to claim 1 , wherein the halogen-containing anti-drip agent comprises Teflon-grafted styrene-acrylonitrile copolymer (TSAN).
5. The composition according to claim 1 , wherein the aromatic sulfone sulfonate comprises a formula (K-2) compound or potassium diphenylsulfone sulfonate (KSS):
6. The composition according to claim 1 , wherein the amount of the aromatic sulfone sulfonate is from about 5×10 −4 parts to about 7×10 −2 parts by weight.
7. The composition according to claim 1 , wherein the aromatic sulfonate comprises a formula (N-1) compound:
wherein R 4 is selected from a C 1 -C 6 alkyl group; M is a metal; n is an integer and 1≦n≦3; y is an integer and 0≦y≦5.
8. The composition according to claim 1 , wherein the aromatic sulfonate comprises a formula (N-2) compound or a sodium salt of toluene sulfonic acid (NaTS):
9. The composition according to claim 1 , wherein the amount of the aromatic sulfonate is from about 5×10 −5 parts to about 5×10 −2 parts by weight.
10. The composition according to claim 1 , wherein the elastomer-modified graft copolymer comprises a rubbery polymer substrate comprising an elastomeric copolymer of a polymer of monovinylacromatic monomers with a conjugated diene; and a rigid polymer grafted to the rubbery polymer substrate comprising a polymer of C 1-8 alkyl(meth)acrylate optionally with monovinylaromatic monomers.
11. The composition according to claim 10 , wherein the elastomer-modified graft copolymer comprises methyl methacrylate-butadiene-styrene copolymer (MBS).
12. The composition according to claim 1 , wherein the amount of the elastomer-modified graft copolymer is from about 0.5 parts to about 5 parts by weight.
13. The composition according to claim 1 , wherein the polysiloxane-polycarbonate copolymer comprises repeating siloxane units of formula (S-1):
wherein each occurrence of R 1 is same or different, and is a C 1-13 monovalent organic radical; and D may have an average value of 2 to 1,000.
14. The composition according to claim 1 , wherein the polysiloxane-polycarbonate copolymer comprises from about 2 weight percent to about 30 weight percent siloxane units.
15. The composition according to claim 1 , wherein the amount of the polysiloxane-polycarbonate copolymer is from about 0.5 parts to about 6 parts by weight.
16. The composition according to claim 1 , wherein the siloxane oligomer comprises a formula (P-1) compound:
wherein R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R a and R b are independently selected from a C 1 -C 8 alkyl group such as methyl and ethyl, or an arylalkyl group such as phenylmethyl, phenylethyl, and phenylpropyl, or an aryl group such as phenyl; x is an integer; and 1≦x≦10.
17. The composition according to claim 1 , wherein the siloxane oligomer comprises a formula (P-2) compound:
18. The composition according to claim 1 , wherein the amount of the siloxane oligomer is from about 0.2 parts to about 3 parts by weight.
19. The composition according to claim 1 , wherein the polycarbonate comprises repeating structural carbonate units of the formula (A-1):
wherein each of A 1 and A 2 is a monocyclic divalent aryl radical and Y 1 is a bridging radical having one or two atoms that separate A 1 from A 2 .
20. The composition according to claim 1 , wherein the polycarbonate comprises repeating structural carbonate units of the formula (A-2):
wherein R a and R b each represent a halogen atom or a monovalent hydrocarbon group and may be the same or different; p and q are each independently integers of 0 to 4; and X a represents one of the groups of formula (5):
wherein R c and R d each independently represent a hydrogen atom or a monovalent linear or cyclic hydrocarbon group and R e is a divalent hydrocarbon group.
21. The composition according to claim 1 , wherein the polycarbonate comprises repeating structural carbonate units of the formula (A-3):
22. The composition according to claim 1 , in which the polycarbonate comprises a mixture of high flow polycarbonate and normal flow polycarbonate.
23. The composition according to claim 1 , further comprising one or more optional additives selected from the group consisting of hydrolysis stabilizer, filler/reinforcing agent, visual effect enhancer, antioxidant, heat stabilizer, light stabilizer, ultraviolet light absorber, plasticizer, mold release agent, lubricant, antistatic agent, pigment, dye, processing aid, radiation stabilizer; and combinations thereof.
24. The composition according to claim 1 , further comprising from about 0.03 parts to about 0.05 parts by weight of tris(2,4-di-tert-butylphenyl) phosphite.
25. A flame retardant article made from the composition according to claim 1 .
26. The article of claim 25 , which is an electronic or a mechanical part.
27. A flame retardant article formed from a composition comprising an effective amount of a polycarbonate, a fluoro-containing anti-drip agent, an aromatic sulfone sulfonate, an aromatic sulfonate, a synergistic combination of an elastomer-modified graft copolymer and a polysiloxane-polycarbonate copolymer, and an optional siloxane oligomer, wherein the fluorine content of the anti-drip agent is less than about 0.1 percent by weight based on the total weight of the composition, and wherein the article exhibits a UL 94 flammability V0 rating at 1.2 mm.