Polycarbonate composition having improved scratch resistance, and articles formed therefrom
View Patent ↗A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
1. A thermoplastic composition comprising:
A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of:
a polycarbonate having the formula:
wherein the molar ratio of x to y is 25:75 to 100:0;
B) 5 to 75 parts by weight of a polyester-polycarbonate having the formula
wherein R 1 is a C 6-30 aromatic group, each R f is independently C 1-12 alkyl, or halogen, u is 0 to 4, and the molar ratio of m to n is 95:5 to 10:90, and
C) 0 to 65 parts by weight of a second polycarbonate,
wherein the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
2. The thermoplastic composition of claim 1 , wherein the polyester-polycarbonate consists essentially of the formula:
wherein R a , R b , and R f are each independently C 1-12 alkyl or halogen; R c and R d are each independently hydrogen, C 1-12 alkyl, cyclic C 1-12 alkyl, C 7-12 arylalkyl, C 1-12 heteroalkyl, or cyclic C 7-12 heteroarylalkyl, p, q, and u are independently 0 to 4, 1 is 0 to 30 mol %, m is 10 to 95 mol %, and n is 5 to 90 mol %, and the sum of l, m, and n is 100 mol %.
3. The thermoplastic composition of claim 2 , wherein the polyester-polycarbonate consists essentially of the formula:
wherein the molar ratio of m to n is 95:5 to 10:90.
4. The thermoplastic composition of claim 1 , wherein the first carbonate unit is present in the first polycarbonate in an amount of 50 to 85 mol %, and the second carbonate unit is present in the first polycarbonate in an amount of 15 to 50 mol %.
5. The thermoplastic composition of claim 1 , wherein the second polycarbonate comprises carbonate units of the formula:
wherein R a and R b are each independently C 1-12 alkyl, or halogen; R c and R d are each independently hydrogen, C 1-12 alkyl, cyclic C 1-12 alkyl, C 7-12 arylalkyl, C 1-12 heteroalkyl, or cyclic C 7-12 heteroarylalkyl; and p and q are each independently 0 to 4.
6. The thermoplastic composition of claim 1 , wherein the thermoplastic composition has a molar amount of arylate ester of greater than or equal to 10 mol %, and a molar amount of alkyl-substituted bisphenol carbonate of greater than or equal to 25 mol %.
7. The thermoplastic composition of claim 1 , wherein a molded article consisting of the thermoplastic composition has, after xenon arc lamp weathering for 500 hours according to ISO 4892-2A, a gloss retention of greater than 50% as measured at an angle of 60 degrees and calibrated using a black glass standard of 100 GU according to ASTM D2457-03.
8. The thermoplastic composition of claim 1 , wherein a molded article consisting of the thermoplastic composition has a scratch depth measured at an angle of 90 degrees of less than or equal to 19 micrometers, measured at 6 Newtons downward force.
9. The thermoplastic composition of claim 1 , wherein a molded article consisting of the thermoplastic composition has a pencil scratch hardness of HB or harder according to ASTM D3363-92a.
10. The thermoplastic composition of claim 1 , further comprising an additive including a filler, an ionizing radiation stabilizer, an antioxidant, a heat stabilizer, a light stabilizer, an ultraviolet light absorber, a plasticizer, a lubricant, a mold release agent, an antistatic agent, a pigment, a dye, a flame retardant, an anti-drip agent, or a combination comprising at least one of the foregoing additives, wherein the type and amount of additive is selected such that the desired properties of the thermoplastic composition are not substantially adversely affected.
11. The thermoplastic composition of claim 10 wherein the thermoplastic composition comprises a black colorant.
12. An article comprising the thermoplastic composition of claim 1 .
13. A thermoplastic composition consisting essentially of:
A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of:
a polycarbonate having the formula:
wherein the molar ratio of x to y is 25:75 to 100:0;
B) 5 to 75 parts by weight of a polyester-polycarbonate having the formula:
wherein R 1 is a C 6-30 aromatic group, each R f is independently C 1-12 alkyl, or halogen, u is 0 to 4, and the molar ratio of m to n is 95:5 to 10:90,
C) 0 to 65 parts by weight of a second polycarbonate, and
D) an additive,
wherein the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
14. A thermoplastic composition comprising:
A) 25 to 95 parts by weight of a first polycarbonate comprising the formula:
wherein the molar ratio of x to y is 25:75 to 100:0, and
B) 5 to 75 parts by weight of a polyester-polycarbonate comprising the formula
wherein R a , R b , and R f are each independently C 1-12 alkyl or halogen; R c and R d are each independently hydrogen, C 1-12 alkyl, cyclic C 1-12 alkyl, C 7-12 arylalkyl, C 1-12 heteroalkyl, or cyclic C 7-12 heteroarylalkyl; p, q, and u are independently 0 to 4, and the molar ratio of m to n is 95:5 to 10:90, and
C) 0 to 65 parts by weight of a second polycarbonate,
wherein the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
15. The thermoplastic composition of claim 14 , wherein a molded article consisting of the thermoplastic composition has, after xenon arc lamp weathering for 500 hours according to ISO 4892-2A, a gloss retention of greater than 50% as measured at an angle of 60 degrees and calibrated using a black glass standard of 100 GU according to ASTM D2457-03.
16. The thermoplastic composition of claim 14 , wherein a molded article consisting of the thermoplastic composition has a scratch depth measured at an angle of 90 degrees of less than or equal to 19 micrometers, measured at 6 Newtons downward force.
17. The thermoplastic composition of claim 14 , wherein a molded article consisting of the thermoplastic composition has a pencil scratch hardness of HB or harder according to ASTM D3363-92a.
18. An article comprising the thermoplastic composition of claim 13 .