Producing method of fullerene derivative, fullerene derivative, proton conductor and electrochemical device
View Patent ↗Provided are a method of efficiently procuding fullerene into which a OH group or a SO 3 H group is introduced, such as fullerenol, or a derivative thereof, the fullerene and its derivative being preferable as a proton conductor, and a novel and usable proton conductor obtained by the method. Further, provided is an electrochemical device using the proton conductor such as a fuel cell or the like. In the producing method of the fullerene derivative, halogated fullerene, which is obtained through halogating a fullerene molecule is used as a precursor, the fullerene derivative is produced through introducing one or more proton dissociative group into at least one carbon atom of a fullerene molecule. Moreover, in a producing method of a polymerized fullerene derivative, a plurality of fullerene derivatives are bonded to one another by an aromatic group of an aromatic compound through reacting the plurality of fullerene derivatives with the aromatic compound. The fullerene derivative obtained by any of these method functions as a proton conductor, and an electrochemical device using the proton conductor such as a fuel cell can be downsized and simplified without atmosphere constraints.
1. A method for producing a fullerene derivative as a proton conductor, comprising the steps of:
reacting a fullerene molecule with at least one halogen atom so as to produce a halogenated fullerene; and
reacting the halogenated fullerene with a hydroxide or sulfite so as to produce a fullerene derivative as a proton conductor, wherein one or more proton (H + ) dissociative group is introduced into at least one carbon atom of the fullerene molecule, wherein,
the hydroxide is represented as MOH, and the sulfite is represented as M 2 SO 3 where M is an alkali metal atom.
2. The method of claim 1 , wherein
hydroxylated fullerene is obtained by the MOH, and sulfonated fullerene is obtained by the M 2 SO 3 .
3. The method of claim 2 , wherein
a hydroxyl group of the hydroxylated fullerene is further inverted into at least one of —OSO 3 H and —OPO(OH) 2 .
4. The method of claim 1 , wherein
the fullerene molecule is a spherical carbon cluster molecule Cm where m is any of 36, 60, 70, 76, 78, 80, 82 and 84, or a natural number capable of constituting a cluster molecule.
5. The method of claim 1 , wherein
the halogenated fullerene is reacted with the hydroxide or the sulfite in an organic solvent.
6. The method of claim 5 , wherein
the organic solvent with at least one of crown ether and a Lewis acid catalyst added thereto is used to react the halogenated fullerene with the hydroxide or the sulfite.
7. The method of claim 5 , wherein
at least one of a phase-transfer catalyst and a Lewis acid catalyst is used to react the fullerene derivative with the hydroxide or the sulfite in a two-phase system of a solution of the hydroxide or the sulfite and the organic solvent.
8. The method of claim 1 , wherein the halogen atom is selected from the group consisting of a fluorine atom (F), a chlorine atom (Cl) and a bromine atom (Br).