Polyethylene terephthalate resins and process for producing polyester resin moldings
View Patent ↗Provided in this invention are polyethylene terephthalate resins which can suppress the formation of acetaldehyde as a by-product in melt molding of the resins and can provide the molded products reduced in acetaldehyde content. A polyethylene terephthalate resin which has an intrinsic viscosity [η 2 ] of not less than 0.70 dl/g and not more than 1.50 dl/g and an acetaldehyde content [AA 0 (ppm by weight)] of not more than 10 ppm by weight, and has such properties that the acetaldehyde content [AA 1 (ppm by weight)] of the molded product obtained by injection molding the resin at 280° C. with its moisture content adjusted to 30±20 ppm by weight and the acetaldehyde content [AA 2 (ppm by weight)] of the molded product obtained by injection molding the resin at 280° C. with its moisture content adjusted to 120±20 ppm by weight satisfy the following formula (1): [( AA 1 −AA 2 )/ AA 1 ]×100≧30 (1).
1. A process for producing a molded polyester resin article which process comprises molding a polyethylene terephthalate resin comprising uses, as starting material, a polyester resin mixture (c) with its moisture content adjusted to 60 to 300 ppm by weight, said mixture comprising, a polyester resin (a) having a moisture content of less than 60 ppm by weight and a polyester resin (b) other than the polyester resin (a) and having a moisture content of not less than 60 ppm by weight wherein the ratio of the polyester resin (a) to the polyester resin (b) is from >1 to ≦200 by resin weight, wherein the moisture content of the mixture (c) is a value calculated from the weighted means of the moisture content and the amount blended of the polyester resin (a) and the moisture content and the amount blended of the polyester resin (b), and
wherein the article is molded using an injection or extrusion molding machine, wherein a mixture (c) is formed at a point between a material charging hopper attached to the molding machine and a material feeding section of a screw in the molding machine, and the temperature of the polyester resin (a) offered to the formation of the mixture (c) is not lower than 60° C. and not higher than 170° C.
2. The process according to claim 1 , wherein intrinsic viscosity (IV 0 ) of the mixture (c) and intrinsic viscosity (IV 1 ) of the molded product satisfy the following formula:
0.75 ≦IV 1 /IV 0 ≦0.95.
3. The process according to claim 1 , wherein the polyester resin (a) is a polyethylene terephthalate resin having an intrinsic viscosity of not less than 0.70 dl/g and not more than 1.50 dl/g and an acetaldehyde content of not more than 10 ppm by weight, and the polyester resin (a) has such properties that the acetaldehyde content [AA 1 (ppm by weight)] of the molded product obtained by injection molding the resin at 280° C. with its moisture content adjusted to 30±20 ppm by weight and the acetaldehyde content [AA 2 (ppm by weight)] of the molded product obtained by injection molding the resin at 280° C. with its moisture content adjusted to 120±20 ppm by weight satisfy the following formula (I):
[ AA 1 −AA 2 /AA 1 ]×100≧30 (1).