IP Library Granted Patent US 7,521,096
Granted Patent B2
US 7,521,096 · App. 11/437,751 · Granted Apr 21, 2009

Method of making a low-E coated article including heat bending

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Quick Facts
Patent No.
US 7,521,096
App. No.
11/437,751
Granted
Apr 21, 2009
Kind
B2
Abstract

A coated article is provided which may be heat treated (e.g., thermally tempered) and/or heat bent in certain example instances. In certain example embodiments, an interlayer of or including a metal oxide such as tin oxide is provided under an infrared (IR) reflecting layer so as to be located between respective layers of or including silicon nitride and zinc oxide. It has been found that the use of such a tin oxide inclusive interlayer results in significantly improved bendability of the coated article in applications such as vehicle windshields with deep bends. In certain example instances, an overcoat of a material such as zirconium oxide may also be provided.

Claims (10)

1. A method of making a coated article, the method comprising:

providing a coating on a glass substrate, the coating comprising first and second layers comprising silver with at least a layer comprising tin oxide therebetween, wherein the layer comprising tin oxide is located between and contacting a layer comprising silicon nitride and a layer comprising zinc oxide, wherein the layer comprising zinc oxide is located over and contacting the layer comprising tin oxide, and the layer comprising silicon nitride is located under and contacting the layer comprising tin oxide; and

heat bending the glass substrate with the coating thereon to an extent so as to have a centerline convex value “x” of at least about 28 mm without experiencing significant mottling damage due to the heat bending.

2. The method of claim 1 , wherein the coated article has a visible transmission of at least about 75% and a sheet resistance (R S ) of less than or equal to 3.0 ohms/square.

3. The method of claim 2 , wherein the coated article comprises a vehicle windshield, and wherein the vehicle windshield as a glass side reflective a* color of from −2.5 to +2.5, and glass side reflective b* color of from −15.0 to 0.

4. A method of making a coated article, the method comprising:

heat treating a glass substrate with a coating thereon, the coating comprising first and second layers comprising silver with at least a layer comprising tin oxide therebetween, wherein the layer comprising tin oxide is located between and contacting a layer comprising silicon nitride and a layer comprising zinc oxide, wherein the layer comprising zinc oxide is located over and contacting the layer comprising tin oxide and the layer comprising silicon nitride is located under and contacting the layer comprising tin oxide; and

heat bending the glass substrate with the coating thereon to an extent so as to have a centerline convex value “x” of at least about 28 mm without experiencing significant mottling damage due to the heat bending.

5. The method of claim 4 , wherein the coated article has a visible transmission of at least about 75% and a sheet resistance (R S ) of less than or equal to 3.0 ohms/square.

6. The method of claim 4 , wherein the coated article comprises a vehicle windshield, and wherein the vehicle windshield as a glass side reflective a* color of from −2.5 to +2.5, and glass side reflective b* color of from −15.0 to 0.

Assignments (4)
MERGER Recorded May 30, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
To: GUARDIAN EUROPE S.À R.L.
Reel/Frame 046834/0495 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME AND ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED ON REEL 044900 FRAME 0321. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Feb 28, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
Reel/Frame 045870/0001 →
CHANGE OF NAME Recorded Dec 18, 2017
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À.R.L.
Reel/Frame 044900/0321 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2017
From: GUARDIAN INDUSTRIES CORP.
To: GUARDIAN GLASS, LLC.
Reel/Frame 044053/0318 →