IP Library Granted Patent US 8,808,874
Granted Patent B2
US 8,808,874 · App. 11/444,590 · Granted Aug 19, 2014

Organic electroluminescent element, illuminator and display

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Quick Facts
Patent No.
US 8,808,874
App. No.
11/444,590
Granted
Aug 19, 2014
Kind
B2
Abstract

An organic electroluminescent element containing an anode and a cathode having therebetween a light emitting layer, wherein the light emitting layer contains a guest compound having a substructure represented by Formula (AA): wherein A represents a group of atoms necessary to form an aromatic hydrocarbon ring or an aromatic heterocycle, B represents a group of atoms necessary to form a 5-membered aromatic heterocycle containing nitrogen or a 5-membered heterocycle containing nitrogen and M represents Ir or Pt, and a host compound represented by Formula (1):

Claims (25)

1. An organic electroluminescent element comprising an anode and a cathode having therebetween a light emitting layer, wherein the light emitting layer comprises a guest compound represented by one of Formulae (A-1) through (A-9) and a host compound represented by Formula (1):

wherein Ra represents an alkyl group, an aromatic hydrocarbon group or a heteroaromatic group, Rb and Rc each represent a hydrogen atom or a substituent selected from the group consisting of an alkyl group, an aromatic hydrocarbon group, an alkoxy group and a halogen atom; A1 represents a benzene ring or a pyridine ring;

wherein a plurality of A1 are the same or different, a plurality of Ra are the same or different, a plurality of Rb are the same or different and a plurality of Rc are the same or different, in each of Formulae (A-1) through (A-9);

wherein Ra 1 represents a phenyl group; R 1 and R 2 each represent a phenyl group or a pyridyl group; R 5 represents a substituent selected from Group 1; and n1, n2 and n5 each represent an integer of 0 to 4,

wherein the Group 1 substituent is selected from the group consisting of

an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocycle group, a heterocycle group, an alkoxy group, a cycloalkoxyl group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, an acyl group, an acyloxy group, an amide group, a carbamoyl group, an ureido group, a sulfinyl group, an alkylsulfonyl group, an arylsulfonyl group, an amino group, a halogen atom, a hydrofluorocarbon group, a cyano group, a nitro group, a hydroxyl group, a mercapto group and a silyl group.

2. The organic electroluminescent element of claim 1 , wherein the aromatic hydrocarbon ring represented by A1 in any one of Formula (A-1) through (A-9) is a benzene ring.

3. The organic electroluminescent element of claim 1 which emits blue light.

4. The organic electroluminescent element of claim 1 which emits white light.

5. A display comprising the organic electroluminescent element of claim 1 .

6. An illuminator comprising the organic electroluminescent element of claim 1 .

7. A display comprising the illuminator of claim 6 and a liquid crystal cell as a display means.

8. The organic electroluminescent element of claim 1 , wherein R 5 in Formula (1) represents an aromatic hydrocarbon group or an aromatic heterocycle group.

9. An organic electroluminescent element comprising an anode and a cathode having therebetween a light emitting layer, wherein the light emitting layer comprises a guest compound represented by one of Formula (B-1) through (B-3) and a host compound represented by Formula (1):

wherein Ra represents an alkyl group or an aromatic hydrocarbon group; Rb, Rc, Rb 1 and Rc 1 each represent a hydrogen atom; A1 represents a benzene ring; M represents Ir;

Formula (1)

wherein Ra 1 represents a phenyl group; R 1 and R 2 each represent a phenyl group or a pyridyl group, R 5 represents a substituent selected from Group 1; and n1, n2 and n5 each represent an integer of 0 to 4,

wherein the Group 1 substituent is selected from the group constituting of

an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocycle group, a heterocycle group, an alkoxy group, a cycloalkoxyl group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, an acyl group, an acyloxy group, an amide group, a carbamoyl group, an ureido group, a sulfinyl group, an alkylsulfonyl group, an arylsulfonyl group, an amino group, a halogen atom, a hydrofluorocarbon group, a cyano group, a nitro group, a hydroxyl group, a mercapto group and a silyl group.

10. An organic electroluminescent element comprising an anode and a cathode having therebetween a light emitting layer, wherein the light emitting layer comprises a guest compound represented by one of Formulae (C-1) through (C-3) and a host compound represented by Formula (I):

wherein Ra represents an alkyl group or an aromatic hydrocarbon group; Rb, and Rc each represent a hydrogen atom or an alkyl group; A1 represents a benzene ring; M represents Ir;

wherein Ra 1 represents a phenyl group; R 1 and R 2 each represent a phenyl group or a pyridyl group, R 5 represents a substituent selected from Group 1; and n1, n2 and n5 each represent an integer of 0 to 4,

wherein the Group 1 substituent is selected from the group consisting of

an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocycle group, a heterocycle group, an alkoxy group, a cycloalkoxyl group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, an acyl group, an aryloxy group, an amide group, a carbamoyl group, an ureido group, a sulfinyl group, an alkylsulfonyl group, an arylsulfonyl group, an amino group, a halogen atom, a hydrofluorocarbon group, a cyano group, a nitro group, a hydroxyl group, a mercapto group and a silyl group.

11. The organic electroluminescent element of claim 10 , wherein R 5 in Formula (1) represents an aromatic hydrocarbon group or an aromatic heterocycle group.

Assignments (5)
NUNC PRO TUNC ASSIGNMENT Recorded Feb 10, 2026
From: MERCK PATENT GMBH
To: UDC IRELAND LIMITED
Reel/Frame 073741/0073 →
NUNC PRO TUNC ASSIGNMENT Recorded Oct 7, 2021
From: KONICA MINOLTA INC
To: MERCK PERFORMANCE MATERIALS GERMANY GMBH
Reel/Frame 057748/0075 →
NUNC PRO TUNC ASSIGNMENT Recorded Oct 7, 2021
From: MERCK PERFORMANCE MATERIALS GERMANY GMBH
To: MERCK PATENT GMBH
Reel/Frame 057748/0146 →
CHANGE OF NAME Recorded Mar 23, 2020
From: KONICA MINOLTA HOLDINGS, INC.
To: KONICA MINOLTA, INC.
Reel/Frame 052207/0010 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 1, 2006
From: OTSU, SHINYA; NISHIZEKI, MASATO; KATOH, EISAKU; OSHIYAMA, TOMOHIRO
To: KONICA MINOLTA HOLDINGS, INC.
Reel/Frame 017938/0324 →