Method of producing high strength, high stiffness and high ductility titanium alloys
View Patent ↗A method of producing a high strength, high stiffness and high ductility titanium alloy, comprising combining the titanium alloy with boron so that the boron concentration in the boron-modified titanium alloy does not exceed the eutectic limit. The carbon concentration of the boron-modified titanium alloy is maintained below a predetermined limit to avoid embrittlement. The boron-modified alloy is heated to a temperature above the beta transus temperature to eliminate any supersaturated excess boron. The boron-modified titanium alloy is deformed at a speed slow enough to prevent microstructural damage and reduced ductility.
1. A method of producing a high strength, high stiffness and high ductility titanium alloy, the method comprising:
alloying a titanium alloy with boron so that the boron concentration in the boron-modified titanium alloy does not exceed the eutectic limit;
maintaining the carbon concentration of the boron-modified titanium alloy below a predetermined limit to avoid embrittlement of the boron-modified titanium alloy;
heating the boron-modified alloy to a temperature above the beta transus temperature to force supersaturated boron out of a titanium lattice of the boron-modified titanium alloy and to increase an inter-particle spacing of a titanium boride microconstituent; and
deforming the boron-modified titanium alloy at a speed that avoids damage to the titanium boride microconstituent of the boron-modified titanium alloy.
2. The method of claim 1 wherein the boron is added to a molten titanium alloy and the melt is atomized to obtain boron-containing titanium alloy powder.
3. The method of claim 2 wherein the boron-containing titanium alloy powder is consolidated and/or formed by hot isostatic pressing, forging, extrusion or rolling.
4. The method of claim 2 wherein the boron is in liquid or powder form.
5. The method of claim 1 wherein the titanium alloy is selected from the group consisting of Ti-6Al-4V, Ti-5Al-2.5Sn and Ti-6Al-2Sn-4Zr-2Mo-0.1Si.
6. The method of claim 1 wherein the boron-modified alloy heated above the beta transus temperature is cooled at a rate slow enough to prevent reduced ductility.
7. The method of claim 1 , wherein the steps of heating the boron-modified titanium alloy and deforming the boron-modified titanium alloy are conducted simultaneously.
8. The method of claim 1 , wherein deforming the boron-modified titanium alloy comprises at least one of forging, extruding, and rolling the boron-modified titanium alloy.
9. The method of claim 8 , wherein deforming the boron-modified titanium alloy comprises extruding the boron-modified titanium alloy at a ram speed no greater than 15 inch/mm.
10. The method of claim 1 , wherein the carbon concentration of the boron-modified titanium alloy is no greater than 0.1 weight percent.
11. A method of processing a titanium alloy, the method comprising:
alloying a molten titanium alloy with boron to form a boron-modified titanium alloy melt, wherein the concentration of boron in the melt is below the eutectic limit of boron in the titanium alloy;
atomizing the melt to form a boron-containing titanium alloy powder;
heating the boron-containing titanium alloy powder to a temperature above a beta transus temperature of the boron-containing titanium alloy powder to force supersaturated boron out of a titanium lattice of the boron-containing titanium alloy powder and to increase an inter-particle spacing in a distribution of titanium boride particles in the boron-containing titanium alloy powder.
12. The method of claim 11 , further comprising maintaining the carbon concentration of the boron-containing titanium alloy powder below a predetermined limit to avoid embrittlement.
13. The method of claim 12 , wherein the predetermined limit is no greater than 0.1 weight percent.
14. The method of claim 11 , further comprising cooling the boron-containing titanium alloy powder from the temperature above the beta transus temperature at a rate slow enough to prevent reduced ductility.
15. The method of claim 11 , wherein heating further comprises consolidating the boron-containing titanium alloy powder at a deformation rate that avoids damage to the titanium boride particles of the boron-containing titanium alloy powder, to provide a consolidated boron-modified titanium alloy powder.
16. The method of claim 15 , wherein consolidating the boron-modified titanium alloy powder comprises at least one of hot isotactic pressing and extruding the boron-containing titanium alloy powder.
17. The method of claim 16 , wherein consolidating the boron-modified titanium alloy powder comprises extruding the boron-modified titanium alloy powder at a ram speed no greater than 15 inch/mm.
18. The method of claim 15 , further comprising thermomechanically processing the consolidated boron-containing titanium alloy powder at a deformation rate that avoids damage the titanium boride particles of the consolidated boron-containing titanium alloy powder.
19. The method of claim 18 , wherein thermomechanically processing the consolidated boron-modified titanium alloy powder comprises at least one of forging, extruding, and rolling the consolidated boron-modified titanium alloy powder.
20. The method of claim 18 , wherein thermomechanically processing the consolidated boron-modified titanium alloy powder comprises extruding the consolidated boron-modified titanium alloy powder at a ram speed no greater than 15 inch/mm.
21. The method of claim 11 , further comprising, subsequent to heating the boron-containing titanium alloy powder above the beta transus temperature, consolidating the boron-containing titanium alloy powder at a deformation rate that avoids damage to the titanium boride particles of the boron-containing titanium alloy powder.
22. The method of claim 21 , wherein consolidating the boron-containing titanium alloy powder comprises one of hot isotactic pressing and extruding the boron-containing titanium alloy powder.
23. The method of claim 22 , wherein consolidating the boron-containing titanium alloy powder comprises extruding the consolidated boron-modified titanium alloy powder at a ram speed no greater than 15 inch/mm.
24. The method of claim 21 , further comprising thermomechanically processing the consolidated boron-containing titanium alloy powder at a deformation rate that avoids damage the titanium boride particles of the titanium alloy.
25. The method of claim 24 , wherein thermomechanically processing the consolidated boron-containing titanium alloy powder comprises at least one of forging, extruding, and rolling the consolidated boron-containing titanium alloy powder.
26. The method of claim 25 , wherein thermomechanically processing the consolidated boron-containing titanium alloy powder comprises extruding the boron-modified titanium alloy powder at a ram speed no greater than 15 inch/mm.
27. The method of claim 11 , wherein the boron is in liquid or powder form.
28. The method of claim 11 , wherein the molten titanium alloy is selected from the group consisting of Ti-6Al-4V alloy, Ti-5Al-2.5Sn alloy, and Ti-6Al-2Sn-4Zr-2Mo-0.1Si alloy.
29. A method of processing a titanium alloy, the method comprising:
alloying a molten titanium alloy with boron to form a boron-modified titanium alloy melt, wherein the concentration of boron in the melt is below the eutectic limit of boron in the titanium alloy;
atomizing the melt to form a boron-containing titanium alloy powder;
consolidating the boron-containing titanium alloy powder to form a consolidated boron-containing titanium alloy powder; and
heating the consolidated boron-containing titanium alloy powder above a beta transus temperature of the consolidated boron-containing alloy powder to force supersaturated boron out of a titanium lattice of the boron-containing titanium alloy powder and to increase an inter-particle spacing in a distribution of titanium boride particles in the consolidated boron-containing titanium alloy powder.
30. The method of claim 29 , further comprising maintaining the carbon concentration of the consolidated boron-containing titanium alloy powder below a predetermined limit to avoid embrittlement.
31. The method of claim 30 , wherein the predetermined limit is no greater than 0.1 weight percent.
32. The method of claim 29 , further comprising cooling the consolidated boron-containing titanium alloy powder from the temperature above the beta transus temperature at a rate slow enough to prevent reduced ductility.
33. The method of claim 29 , further comprises thermomechanically processing the consolidated boron-containing titanium alloy powder at a deformation rate that does not damage the titanium boride particles of the consolidated boron-containing titanium alloy powder.
34. The method of claim 33 , wherein the steps of heating the consolidated boron-containing titanium alloy powder above the beta transus temperature and thermomechanically processing the consolidated boron containing titanium alloy powder occur simultaneously.
35. The method of claim 33 , wherein thermomechanically processing the consolidated boron-containing titanium alloy powder comprises at least one of forging, extruding, and rolling the consolidated boron-containing titanium alloy powder.
36. The method of claim 33 , wherein thermomechanically processing the consolidated boron-containing titanium alloy powder comprises extruding the consolidated boron-containing titanium alloy powder at a ram speed no greater than 15 inch/mm.
37. The method of claim 29 , wherein the boron is in liquid or powder form.
38. The method of claim 29 , wherein the molten titanium alloy is selected from the group consisting of Ti-6Al-4V alloy, Ti-5Al-2.5Sn alloy, and Ti-6Al-2Sn-4Zr-2Mo-0.1Si alloy.