Method for activating an iron-based fischer-tropsch catalyst
View Patent ↗A method for transforming at least a part of the catalyst precursor hematite into χ-carbide (Fe 5 C 2 ) and ε′-carbide (FeC 2.2 ) without a large amount of fines generation. This method slows the transformation of the hematite to iron carbides by reducing the partial pressure of the synthesis gas by inert gas dilution. The activation time is about three to about five hours.
1. A method for activating an iron-based catalyst in a vessel, said method comprising:
providing in the vessel a slurry comprising an iron-based catalyst precursor;
contacting said slurry with an inert gas to suspend the catalyst precursor particles in the slurry medium and to heat and pressurize the slurry; and
activating the catalyst precursor particles to provide activated catalyst by introducing into the vessel an activation gas mixture comprising inert gas, hydrogen, and carbon monoxide
wherein said activation gas mixture comprises a ratio of said inert gas to a sum of said hydrogen and said carbon monoxide in the range of from about 3 to about 4.
2. The method of claim 1 , wherein said heated slurry has a temperature in the range of from about 270° C . to about 280° C .
3. The method of claim 1 , wherein the pressurized slurry has a Pressure in the range of from about 140 psia (0.97 MPaa) to about 160 psia (1.1 MPaa).
4. The method of claim 1 , wherein the molar ratio of hydrogen to carbon monoxide in said activation gas mixture is about 1.4.
5. The method of claim 1 , wherein the inert gas of said activation gas mixture is selected from the group consisting of nitrogen, methane, and natural gas.
6. The method of claim 1 , wherein the inert gas used to suspend the catalyst precursor particles is selected from the group consisting of nitrogen, methane, and natural gas.
7. The method of claim 1 , wherein said catalyst precursor further comprises copper and potassium as promoters.
8. The method of claim 1 , wherein said catalyst precursor is precipitated.
9. The method of claim 1 , wherein said catalyst precursor is spray dried.
10. The method of claim 1 , wherein the slurry medium comprises hydrocarbon.
11. The method of claim 1 , wherein the slurry medium comprises molten wax.
12. The method of claim 1 , wherein said activation gas mixture is introduced into the vessel at a space velocity in the range of from about 0.2 to about 0.3 NI/h/g cat.
13. The method of claim 1 , wherein said activated catalyst has an alpha value in the range of from about 0.83 to about 0.85.
14. The method of claim 1 , wherein activating the catalyst precursor particles yields a total carbon monoxide conversion in the range of from about 89% to about 92%.
15. The method of claim 1 , wherein the vessel comprises a bubble column reactor.
16. The method of claim 1 wherein activating the catalyst precursor particles to provide activated catalyst produces less than about 30 wt % fines, wherein fines are catalyst particles having a largest dimension less than about 10 microns.
17. The method of claim 1 wherein the iron-based catalyst precursor is unsupported.
18. The method of claim 12 wherein the activation gas mixture is introduced into the vessel for a time in the range of from about 3 to about 5 hours.