Clear polycarbonate polyester blend
View Patent ↗An optically clear thermoplastic resin composition is disclosed which comprises structural units derived from substituted or unsubstituted polycarbonate and substituted or unsubstituted polyester, wherein said polyester comprises structural units derived from terephthalic acid and a mixture of 1,4-cyclohexane dimethanol and ethylene glycol, wherein said ethylene glycol is greater than about 60 mole percent based on total moles of 1,4-cyclohexane dimethanol and ethylene glycol. In addition the composition disclosed possess good environmental stress cracking resistance, flow and thermal properties.
1. A method for preparing an optically clear thermoplastic resin composition comprising the steps of:
(a) melting a polycarbonate and a polyester to form a molten mixture, wherein the polyester comprises structural units derived from terephthalic acid and a mixture of 1,4-cyclohexane dimethanol and ethylene glycol, and said ethylene glycol is greater than 60 mole percent based on total moles of 1,4-cyclohexane dimethanol and ethylene glycol,
(b) extruding said molten mixture in an extruder to form an extrudate, wherein the extruder is a low torque extruder comprising a plurality of screw elements extending from an upstream feed end to a downstream exit end, and wherein screw elements disposed between the feed end and a first kneading block are progressively compressed in the direction of the first kneading block to increase fill at the first kneading block, and wherein molten mixture is formed and extruded without addition of supplemental catalyst; and
(c) molding the extrudate into an optically clear thermoplastic resin composition.
2. The method of claim 1 , wherein the extruder comprises a first vent section disposed downstream from the first kneading block and upstream from a second kneading block.
3. The method of claim 2 , wherein the extruder comprises a third kneading block disposed downstream from the second kneading block, and a plurality of mixing elements between the third kneading block and the exit end.
4. The method of claim 3 , wherein the extruder comprises a second vent section disposed downstream from the third kneading block.
5. The method of claim 1 , wherein the molten mixture comprises 10-90 weight percent of the polycarbonate component, and 90-10 percent by weight of the polyester component.
6. The method of claim 5 , wherein the molten mixture comprises about 25-75 weight percent polycarbonate and 75-25 weight percent of the polyester component.
7. The method of claim 6 , wherein the extruder comprises a plurality of screw elements extending from a upstream feed end to a downstream exit end, and wherein screw elements disposed between the feed end and a first kneading block are progressively compressed in the direction of the first kneading block to increase fill at the first kneading block.
8. The method of claim 7 , wherein the extruder comprises a first vent section disposed downstream from the first kneading block and upstream from a second kneading block.
9. The method of claim 8 , wherein the extruder comprises a third kneading block disposed downstream from the second kneading block, and a plurality of mixing elements between the third kneading block and the exit end.
10. The method of claim 9 , wherein the extruder comprises a second vent section disposed downstream from the third kneading block.