Method of making multilayer structures using tapes on non-densifying substrates

1. A method for applying a ceramic coating to a substrate comprising:

a. applying a tackifying resin to at least one of a green ceramic tape and a rigid substrate,

i. wherein the green ceramic tape comprises a solids portion and an organics portion,

ii. wherein the solids portion comprises a glass component,

iii. wherein the organics portion comprises a polymer resin,

iv. wherein the tackifying resin is selected from the group consisting of rosin resins, terpene resins, hydrocarbon resins and combinations thereof, and

v. wherein the thermal degradation initiation temperature of the tackifying resin is lower than the thermal degradation initiation temperature of the polymer resin,

vi. wherein the thermal degradation completion temperature of the tackifying resin is no greater than that of the resin used in the green ceramic tape,

b. laminating together at a lamination pressure of less than about 100 psi, the green ceramic tape and the substrate to form a monolith, and

c. firing the monolith at a temperature and a time sufficient to flow and densify the glass component,

d. wherein the green ceramic tape exhibits less than 5% area shrinkage during firing.

2. The method of claim 1 , wherein the substrate comprises a material selected from the group consisting of metal, glass, ceramic, glass-ceramic, and combinations thereof.

3. The method of claim 1 , wherein the tackifying resin is selected from the group consisting of (a) dehydroabietyl alcohol, (b) a substance having chemical abstracts service registry number 65997-05-9, and combinations thereof.

4. The method of claim 1 , wherein, prior to applying the tackifying resin, at least one layer of a thick film resistor paste or a thick film conductor paste is deposited on the substrate.

5. The method of claim 1 , wherein the glass component comprises at least one glass composition selected from the group consisting of glass composition 1, glass composition 2, glass composition 3, glass composition 4, glass composition 5, glass composition 6, glass composition 7, and glass composition 8, and combinations thereof, wherein,

a. glass composition 1 comprises:

i. about 30 to about 80 wt % BaO and

ii. about 20 to about 70 wt % SiO 2 ;

b. glass composition 2 comprises:

i. about 40 to about 70 wt % BaO, and

ii. about 5 to about 40 wt % SiO 2

c. glass composition 3 comprises:

i. about 1 to about 40 wt % ZnO, and

ii. about 20 to about 70 wt % SiO 2 ,

d. glass composition 4 comprises:

i. about 1 to about 40 wt % ZnO,

ii. about 20 to about 55 wt % SiO 2 , and

iii. about 1 to about 30 wt % B 2 O 3 ,

e. glass composition 5 comprises:

i. about 25 to about 85 wt % SiO 2 ,

ii. about 10 to about 30 wt % B 2 O 3 , and

iii. about 0.1 to about 40 wt % (Li 2 O+Na 2 O+K 2 O),

f. glass composition 6 comprises:

i. about 20 to about 75 wt % SiO 2 ,

ii. about 0.2 to about 40 wt % (Li 2 O+Na 2 O+K 2 O),

iii. about 0.1 to about 30 wt % (TiO 2 +ZrO 2 ), and

iv. about 0.1 to about 30 wt % (V 2 O 5 +P 2 O 5 ),

g. glass composition 7 comprises:

i. about 30 to about 80 wt % SiO 2 ,

ii. about 0.1 to about 20 wt % BaO,

iii. about 5 to about 40 wt % ZnO, and

iv. about 2 to about 30 wt % B 2 O 3 , and

h. glass composition 8 comprises:

i. about 5 to about 50 wt % SiO 2 ,

ii. about 15 to about 45 wt % CaO,

iii. about 25 to about 40 wt % Al 2 O 3 , and

iv. about 15 to about 35 wt % B 2 O 3 .

6. The method of claim 5 wherein the solids portion further comprises a filler selected from the group consisting of: alumina, anorthite, quartz, fused silica, amorphous silica, cristobalite, cordierite, forsterite, gahnite, aluminum phosphate, boron phosphate, eucryptite, silicates of alkaline earth metals, titanates of alkaline earth metals, titania, cobalt oxide, chromium oxide, tungsten oxide, willemite, zircon, zirconia, and combinations thereof.

7. The method of claim 5 , wherein the glass component comprises at least one glass composition selected from the group consisting of glass composition 1, glass composition 2, glass composition 3, and combinations thereof, and further comprises a filler selected from the group consisting of quartz, amorphous SiO 2 , zircon, zirconia, alumina, titania, cristobalite, and combinations thereof.

8. The method of claim 5 , wherein the glass component comprises glass composition 4 and further comprises a filler selected from the group consisting of quartz, amorphous SiO 2 , zircon, zirconia, alumina, cristobalite, and combinations thereof.

9. The method of claim 5 , wherein the glass component comprises glass composition 5 and a filler selected from the group consisting of the phosphates of Al, B, and Zr, amorphous SiO 2 , cordierite, lithium aluminosilicate, β-eucryptite, and combinations thereof.

10. The method of claim 5 , wherein the glass component comprises glass composition 6 and a filler selected from the group consisting of crystalline SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 , and combinations thereof.

11. The method of claim 5 , wherein the glass component comprises glass composition 7 and a filler selected from the group consisting of crystalline SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 , and combinations thereof.

12. The method of claim 1 , wherein the solids portion further comprises a metal selected from the group consisting of aluminum, copper, silver, gold, platinum, palladium, nickel, and combinations thereof.

13. The method of claim 1 , wherein the substrate is a ceramic selected from the group consisting of ceramic tiles, decorative glass, automotive glass, glass-ceramic cook tops, and combinations thereof.

14. The method of claim 1 , wherein the solids portion comprises an alkali containing glass frit, α-cristobalite and a filler selected from the group consisting of TiO 2 , Al 2 O 3 , ZrO 2 , and combinations thereof.

15. The method of claim 14 , wherein the substrate comprises aluminum or an aluminum alloy.

16. The method of claim 14 wherein the alkali-containing glass frit comprises:

a. about 0.2 wt % to about 40 wt % (Li 2 O+Na 2 O+K 2 O),

b. about 20 wt % to about 75 wt % SiO 2 , and

c. about 0.1 wt % to about 30 wt % TiO 2 .

17. The method of claim 1 wherein the solids portion comprises alkali-free glass frit, α-cristobalite, and a filler selected from the group consisting of TiO 2 , Al 2 O 3 , ZrO 2 , and combinations thereof.

18. The method of claim 17 , wherein the substrate comprises a material selected from the group consisting of stainless steel, aluminum, copper, copper alloys, and combinations thereof.

19. The method of claim 17 , wherein the alkali-free glass frit comprises:

a. about 40 to about 70 wt % BaO,

b. about 0.1 to about 35 wt % B 2 O 3 , and

c. about 10 to about 40 wt % SiO 2 .

20. The method of claim 17 , wherein the alkali-free glass frit comprises

a. about 50 to about 60 wt % BaO,

b. about 15 to about 30 wt % B 2 O 3 ,

c. about 10 to about 40 wt % SiO 2 ,

d. about 1 to about 10 wt % TiO 2 and

e. about 5 to about 15 wt % Al 2 O 3 .

21. The method of claim 17 wherein the solids portion further comprises a glass composition comprising:

a. about 5 to about 50 wt % SiO 2 ,

b. about 15 to about 45 wt % CaO,

c. about 25 to about 40 wt % Al 2 O 3 , and

d. about 15 to about 35 wt % B 2 O 3 .

22. The method of claim 1 , wherein the solids portion comprises alkali-free glass frit and quartz.

23. The method of claim 22 , wherein the substrate comprises a steel selected from the group consisting of stainless steel, and mild steel, and combinations thereof.

24. The method of claim 1 , wherein the green ceramic tape comprises alkali-containing glass frit, α-cristobalite, and at least one filler selected from the group consisting of TiO 2 , Al 2 O 3 , ZrO 2 , and combinations thereof.

25. The method of claim 24 , wherein the alkali-containing glass frit comprises:

a. about 1 to about 40 wt % ZnO,

b. about 1 to about 35 wt % B 2 O 3 , and

c. about 20 to about 55 wt % SiO 2 .

26. The method of claim 24 , wherein the substrate comprises a steel selected from the group consisting of stainless steel, and mild steel, and combinations thereof.

27. A method for applying a porcelain enamel coating to a substrate comprising:

a. applying a tackifying resin to at least one of a green ceramic tape and a rigid substrate,

i. wherein the tackifying resin is selected from the group consisting of dehydroabietyl alcohol and a substance having chemical abstracts service registry number 65997-05-9, and

ii. wherein the green ceramic tape is made from a slurry comprising

1. about 50 to about 70 wt % of a glass composition,

2. about 0.1 to about 10 wt % of a dispersant,

3. about 20 to about 40 wt % of an organic solvent,

4. about 0.1 to about 10 wt % of a polymer resin

5. about 0.1 to about 10 wt % of a plasticizer,

b. laminating together at a lamination pressure of less than about 100 psi, the green ceramic tape and the substrate to form a monolith, and

c. firing the monolith at a temperature of about 500° C. to about 1050° C. for about 1 to about 60 minutes,

d. wherein the green ceramic tape exhibits less than 5% area shrinkage during firing.