Automotive articles prepared from filled TPO compositions, and methods of making the same
View Patent ↗An automotive part containing at least one component formed from a composition comprising the following: (i) a crystalline, isotactic propylene homopolymer, (ii) an ethylene/α-olefin elastomeric impact modifier, and (iii) a reinforcing grade of filler, for example, talc. The crystalline isotactic propylene homopolymer has a flex modulus of greater than about 1930 MPa and a heat deflection temperature (HDT) of greater than about 100° C.; the ethylene/α-olefin interpolymer has a Tg of less than about −30° C., and a tan delta measured at 0.1 radians/s at 190° C. of less than about 2; and the filler has a HDT reinforcing efficiency of at least about 2. The automotive part has an HDT of greater than about 100° C. and a flex modulus of greater than about 1930 MPa.
1. An automotive part, comprising at least one component formed from a polyolefin composition having a heat deflection temperature (HDT) of greater than about 100° C. and flexural modulus of greater than about 1930 MPa, the composition comprising:
A) a crystalline isotactic propylene homopolymer having a flex modulus of greater than about 1930 MPa and an HDT of greater than about 100° C.;
B) an ethylene/α-olefin interpolymer having Tg of less than about −30° C., a tan delta measured at 0.1 radians/s at 190° C. of less than about 2, an HDT that is greater than, or equal to, the peak melting temperature of the ethylene/α-olefin interpolymer, measured by differential scanning calorimetry, and
C) a platy filler, and
wherein the weight ratio of homopolymer:interpolymer (A:B) is between about 9:1 and about 6:4, and
wherein the filler has an HDT efficiency factor greater than, or equal to, about 1.5, and a flexural modulus efficiency factor greater than about 3, and wherein each efficiency factor is determined by measuring the effect of a “20 weight percent addition of filler” on the respective HDT or flexural modulus of a blend of the crystalline isotactic propylene homopolymer and the ethylene/α-olefin interpolymer.
2. The automotive part of claim 1 , wherein the propylene homopolymer has a flex modulus of greater than 2070 MPa, and an HDT of greater than 110° C.
3. The automotive part of claim 1 , wherein the propylene homopolymer has a flex modulus of greater than 2210 MPa, and an HDT of greater than 120° C.
4. The automotive part of claim 1 , wherein the α-olefin of the ethylene/α-olefin interpolymer is a C3-C20 α-olefin.
5. The automotive part of claim 1 , wherein the α-olefin of the ethylene/α-olefin interpolymer is selected from the group consisting of propylene, 1-butene, 1-hexene and 1-octene.
6. The automotive part of claim 1 , wherein the filler is platy talc.
7. The automotive part of claim 4 , wherein the ethylene/α-olefin interpolymer has a Tg of less than 40° C.
8. The automotive part of claim 7 , wherein the difference between the HDT and the melting point Tm of the ethylene/α-olefin interpolymer is at least 4.
9. The automotive part of claim 7 , wherein the difference between the HDT and the melting point Tm of the ethylene/α-olefin interpolymer is at least 8.
10. The automotive part of claim 7 , wherein the tan delta, measured at 190° C. and 0.10 radians/second, of the ethylene/α-olefin interpolymer is 2 or less.
11. The automotive part of claim 7 , wherein the tan delta, measured at 190° C. and 0.10 radians/second, of the ethylene/α-olefin interpolymer is 1.8 or less.
12. The automotive part of claim 7 , comprising 30 weight percent of talc based on the total weight of the composition.
13. The automotive part of claim 1 , wherein the composition further comprising at least one additive selected from the group consisting of a pigment, a scratch and mar resistant additive, and combinations thereof.
14. The automotive part of claim 1 , wherein the part is selected from the group consisting of an instrument panel, a door panel, a dashboard, a valence panel, a body side molding, a trim molding, an armrest, a sun visor, a compartment case and an insulating mat.
15. A method of making the automotive pan of claim 1 , said method comprising injection molding the composition comprising the polypropylene homopolymer, the ethylene/α-olefin interpolymer and the platy filler.
16. The automotive part of claim 1 , wherein the weight percent of filler, based on the “sum weight of the propylene homopolymer, the ethylene/α-olefin interpolymer and filler,” is greater than the weight percent of the ethylene/α-olefin interpolymer, based on the “sum weight of the propylene homopolymer and the ethylene/α-olefin interpolymer.”
17. The automotive part of claim 1 , wherein the composition further comprises one or more other different ethylene/α-olefin interpolymers.
18. The automotive part of claim 17 , wherein the weight percent of filler, based on the “sum weight of the propylene homopolymer, the ethylene/α-olefin interpolymer, the one or more other different ethylene/α-olefin interpolymers, and filler,” is greater than the weight percent of the ethylene/α-olefin interpolymer and the one or more other different ethylene/α-olefin interpolymers, based on the “sum weight of the propylene homopolymer, the ethylene/α-olefin interpolymer and one or more other different ethylene/α-olefin interpolymers.”
19. The automotive part of claim 1 , wherein the at least one component is formed by injection molding.
20. The automotive part of claim 19 , wherein the injection molding is preformed using tooling designed for PC/ABS resins.
21. The automotive part of claim 1 , wherein the part is an instrument panel.
22. The automotive part of claim 1 , wherein the part is a door panel.
23. The automotive part of claim 1 , wherein the part is formed by injection molding, and wherein “out-of-tool” shrinkage of the pan in the x-y direction is 10 percent or less of the amount of shrinkage of the part in the x-y direction inside the tool cavity.
24. The automotive part of claim 1 , wherein polyolefin composition has a heat deflection temperature (HDT) of greater than about 120° C.
25. The automotive part of claim 1 , wherein the polyolefin composition further comprises at least one polydimethylsiloxane.