IP Library Granted Patent US 7,223,375
Granted Patent B1
US 7,223,375 · App. 11/474,794 · Granted May 29, 2007

Emission control systems and methods thereof

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Quick Facts
Patent No.
US 7,223,375
App. No.
11/474,794
Granted
May 29, 2007
Kind
B1
Abstract

A method and system for controlling one or more emissions includes introducing ammonia to react with at least a portion of sulfur trioxides in an exhaust emission and result in at least one or more ammoniated compounds. At least a portion of fly ash particles and the ammoniated compounds in the exhaust emission are precipitated. At least a portion of the ammonia from the precipitated ammoniated compounds is recovered with heat from the exhaust emission and the recovered ammonia is reused.

Claims (16)

1. A method for controlling one or more emissions, the method comprising:

introducing ammonia to react with at least a portion of sulfur trioxides in an exhaust emission and result in at least one or more ammoniated compounds;

precipitating at a least a portion of fly ash particles and the ammoniated compounds in the exhaust emission;

recovering at least a portion of ammonia from the precipitated ammoniated compounds with heat from the exhaust emission; and

reusing the recovered ammonia in the introducing the ammonia.

2. The method as set forth in claim 1 further comprising combusting coal which creates the exhaust emission.

3. The method as set forth in claim 1 wherein the introducing ammonia is at a rate wherein at least a majority of the resulting ammoniated compounds comprise ammonium sulfate.

4. The method as set forth in claim 1 further comprising:

introducing initial ammonia to react with at least a portion of nitrogen oxides and sulfur dioxides in the exhaust emission and result in at least sulfur trioxides before the introducing ammonia to react with at least the portion of sulfur trioxides;

wherein the recovering recovers at least a portion of the initial ammonia from the precipitated ammoniated compounds with heat from the exhaust emission;

wherein the reusing reuses the recovered ammonia and the recovered initial ammonia in at least one of the introducing the initial ammonia and the introducing the ammonia.

5. The method as set forth in claim 4 wherein at least one of the initial ammonia and the ammonia are introduced in a gaseous form and at least a partially liquid form.

6. The method as set forth in claim 4 further comprising reclaiming the heat from the exhaust emission from at least one of before the introducing the initial ammonia and from between introducing the ammonia and the introducing the additional ammonia.

7. The method as set forth in claim 6 wherein the reclaiming the heat from the exhaust emission from before the introducing the initial ammonia further comprises reclaiming the heat from the exhaust emission before a first reduction of temperature of the exhaust emission with a heat exchanger.

8. The method as set forth in claim 6 wherein the reclaiming the heat from the exhaust emission is from before the introducing the initial ammonia and between introducing the initial ammonia and the introducing the ammonia.

9. The method as set forth in claim 1 further comprising collecting the precipitated fly ash particles after the recovering.

Assignments (18)
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 67963/0364 Recorded Sep 16, 2025
From: MIZUHO BANK, LTD., AS AGENT
To: EM RESOURCES LLC
Reel/Frame 072872/0638 →
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 70696/0397 Recorded Sep 15, 2025
From: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
To: EM RESOURCES LLC
Reel/Frame 072910/0155 →
SECURITY INTEREST Recorded Apr 1, 2025
From: EM RESOURCES LLC
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 070696/0397 →
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 059002/0270 Recorded Feb 12, 2025
From: UMB BANK, N.A.
To: EM RESOURCES LLC (F/K/A BORAL RESOURCES LLC)
Reel/Frame 070191/0325 →
PATENT SECURITY AGREEMENT Recorded Jun 28, 2024
From: EM RESOURCES LLC
To: MIZUHO BANK, LTD.
Reel/Frame 067963/0364 →
RELEASE OF SECURITY INTEREST Recorded Jun 20, 2024
From: MUFG BANK, LTD
To: EM RESOURCES LLC (FORMERLY KNOWN AS BORAL RESOURCES LLC)
Reel/Frame 067799/0395 →
CHANGE OF NAME Recorded Mar 25, 2022
From: BORAL RESOURCES LLC
To: EM RESOURCES LLC
Reel/Frame 059510/0851 →
SECURITY INTEREST Recorded Feb 10, 2022
From: BORAL RESOURCES LLC
To: UMB BANK, N.A.
Reel/Frame 059002/0270 →
SECURITY INTEREST Recorded Feb 10, 2022
From: BORAL RESOURCES LLC
To: MUFG BANK, LTD.
Reel/Frame 059003/0211 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2018
From: PMI ASH TECHNOLOGIES, LLC
To: BORAL RESOURCES LLC
Reel/Frame 045924/0885 →
TERMINATION AND RELEASE OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 20, 2012
From: PROGRESS FUELS CORPORATION
To: PMI ASH TECHNOLOGIES, LLC
Reel/Frame 028607/0957 →
TERMINATION AND RELEASE OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 20, 2012
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: PMI ASH TECHNOLOGIES, LLC
Reel/Frame 028604/0551 →
SECURITY AGREEMENT Recorded Jan 8, 2010
From: PMI ASH TECHNOLOGIES, LLC
To: WACHOVIA BANK, NATIONAL ASSOCIATION
Reel/Frame 023768/0442 →
MERGER Recorded Jul 17, 2008
From: PMI TARGET, LLC
To: PMI ASH TECHNOLOGIES, LLC
Reel/Frame 021253/0132 →
CHANGE OF NAME Recorded Jun 6, 2008
From: PROGRESS MATERIALS, INC.
To: PMI TARGET, LLC
Reel/Frame 021050/0887 →
DOCUMENT PREVIOUSLY RECORDED ON REEL 020106 FRAME 0638 CONTAINED ERRORS IN PROPERTY NUMBER 05/160539 AND 07/7223375. DOCUMENT RERECORDED TO CORRECT ERRORS ON STATED REEL. Recorded Nov 21, 2007
From: PMI ASH TECHNOLOGIES, LLC
To: WACHOVIA BANK, NATIONAL ASSOCIATION
Reel/Frame 020166/0884 →
SECURITY AGREEMENT Recorded Nov 9, 2007
From: PMI ASH TECHNOLOGIES, LLC
To: PROGRESS FUELS CORPORATION
Reel/Frame 020092/0176 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2006
From: COCHRAN, JOE W.
To: PROGRESS MATERIALS, INC.
Reel/Frame 018016/0424 →