Cellulose ether composition
View Patent ↗A composition comprising cellulose ether, a superplasticizer and defoamer suitable for use as an additive in extruding inorganic compositions is disclosed. The inventive composition functions as a water retention agent, plasticizer and lubricant in the extrusion of inorganic compositions. The use of the inventive composition in the extrusion of building materials leads to improved processing properties, to a higher surface quality and product properties of the extruded article.
1. A cellulose ether composition comprising (A) 55-99.8% by weight of a cellulose ether having a viscosity between 75,000 and 200,000 mPas, measured in a 2% aqueous solution at 20° C. in a Haake rotary viscosimeter, (B) 0.19-45% by weight of a superplasticizer and (C) 0.01-25% by weight of a defoamer, the percents being relative to the weight of the cellulose composition.
2. The cellulose ether composition according to claim 1 , wherein the cellulose ether (A) is at least one member selected from the group consisting of carboxymethylcellulose and sulphoethylcellulose and salts of each.
3. The cellulose ether composition according to claim 1 , wherein cellulose ether (A) is at least one member selected from the group consisting of methylcellulose, methylhydroxyethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, methylhydroxyethylhydroxybutylcellulose and cellulose ethers which contain methyl groups and longer-chain hydrophobic side chains.
4. The cellulose ether composition according to claim 1 , wherein the superplasticizer is a synthetic polymer, comprising polymerized units of an unsaturated monomeric carboxylate ether, carboxylic acid ester and/or carboxylic acid and/or a salt of carboxylic acid.
5. The cellulose ether composition according to claim 1 , wherein the defoamer is a member selected from the group consisting of alkylene glycol homopolymers, alkylene glycol copolymers, alkylene glycol terpolymers, block copolymers based on ethylene oxide and block copolymers based on propylene oxide.
6. The cellulose ether composition according to claim 1 in powder form.
7. The cellulose ether composition according to claim 1 comprising (A) 60-99% by weight of the cellulose ether, (B) 0.9-39.9% by weight of the superplasticizer and (C) 0.1-20% by weight of defoamer, the percents being relative to the weight of the cellulose ether composition.
8. The cellulose ether composition according to claim 1 , wherein the cellulose ether has a viscosity between 75,000 and 85,000, measured in a 2% aqueous solution at 20°C. in a Haake rotary viscosimeter.
9. The cellulose ether composition according to claim 8 comprising (A) 60-99% by weight of the cellulose ether, (B) 0.9-39.9% by weight of the superplasticizer and (C) 0.1-20% by weight of defoamer, the percents being relative to the weight of the cellulose ether composition.
10. A process for making articles by extrusion comprising mixing a cellulose ether composition comprising (A) 55-99.8% be weight of aqueous solution at 20° C. in a Haake rotary viscosimeter, (B) 0.19-45% by weight of a superplasticizer and (C) 0.01-25% by weight of a defoamer, the percents being relative to the weight of the cellulose ether composition, with water and a mineralic mixture comprising 20 to 100 parts of binder, 0 to 70 parts of aggregates, 0 to 30 parts of lightweight aggregates, 0 to 20 parts of fibres and optional additives, to produce a homogeneous composition and extruding the homogeneous composition through a die of an extruder, said cellulose ether composition being present in an amount of 0.1 to 3 percent relative to the mineralic mixture.
11. The process according to claim 10 , wherein the cellulose ether composition comprises (A) 60-99% by weight of the cellulose ether, (B) 0.9-39.9% by weight of the superplasticizer and (C) 0.1-20% by weight of the defoamer, the percents being relative to the weight of the cellulose ether composition.
12. The process according to claim 10 , wherein the cellulose ether has a viscosity between 75,000 and 85,000, measured in a 2% aqueous solution at 20°C. in a Haake rotary viscosimeter.
13. The process according to claim 12 , wherein the cellulose ether composition comprises (A) 60-99% by weight of the cellulose ether, (B) 0.9-39.9% by weight of the superplasticizer and (C) 0.1-20% by weight of defoamer, the percents being relative to the weight of the cellulose ether composition.
14. An inorganic extrusion composition comprising a mineralic mixture comprising 20 to 100 parts by weight (pbw) of binder, 0 to 70 pbw of aggregates, 0 to 30 pbw of lightweight aggregates, 0 to 20 pbw of fibers and optional additives, and 0.1 to 3% by weight (based on the weight of the mineralic mixture) of a cellulose ether composition comprising (A) 55-99.8% by weight of a cellulose ether having a viscosity between 75,000 and 200,000 mPas, measured in a 2% aqueous solution at 20° C. in a Haake rotary viscosimeter, (B) 0.19-45% by weight ofa superplasticizer and (C) 0.01-25% by weight of a defoamer, the percents being relative to the weight of the cellulose ether composition.
15. The inorganic extrusion composition according to claim 14 , wherein the binder is cement, the amount of superplasticizer is 0.01 to 4% by weight and the amount of cellulose ether is 0.05 to 10% by weight, in each case based on the weight of said cement.
16. The inorganic extrusion composition according to claim 14 , wherein the cellulose ether composition comprised in the inorganic extrusion composition comprises (A) 60-99% by weight of the cellulose ether, (B) 0.9-39.9% by weight of the superplasticizer and (C) 0.1-20% by weight of defoamer, the percents being relative to the weight of the cellulose ether composition.
17. The inorganic extrusion composition according to claim 14 , wherein the cellulose ether has a viscosity between 75,000 and 85,000, measured in a 2% aqueous solution at 20° C. in a Haake rotary viscosimeter.
18. The inorganic extrusion composition according to claim 17 , wherein the cellulose ether has a viscosity between 75,000 and 85,000, measured in a 2% aqueous solution at 20° C. in a Haake rotary viscosimeter.