Liquid crystalline polymer barrier resin films and processes thereof
View Patent ↗Disclosed is a single layer or multilayer polymeric structures that comprise a liquid crystalline polymer barrier resin. Such films have improved optical clarity and lower surface roughness measurements, without sacrificing desired barrier properties. These structures are useful for many packaging applications including pouches and bags and lidding applications.
1. A film or sheet comprising a barrier resin wherein the outside surface of the film or sheet demonstrates a root mean square value for surface roughness in the range of about 0.7 μm or less, when measured using an optical profilometer at a field of view of 0.72×0.54 mm and with a data density of 640 pixels in the horizontal direction and 480 pixels in the vertical direction and the barrier resin comprising an LCP, which comprises or is produced from a polymer comprising repeat units of the formulae —C(O)—R 1 —C(O)— (formula I); —O—R 2 —O— (formula II); —O—R 4 —O— (formula V); —O—Ar—C(O)— (formula IIIA); and —O—NPh—C(O)— (formula IIIB) wherein
LCP is liquid crystalline polymer;
Ar is an arylene group;
NPh is a naphthylene group,
from 90 to 100 mole percent of R 1 is p-phenylene, and from 0 to 10 mole percent of R 1 is m-phenylene;
from 90.0 to 100 mole percent of R 2 is —CH 2 CH 2 — and from 0 to 10.0 mole percent of R 2 is —CH 2 CH 2 OCH 2 CH 2 —;
each R 4 is 4,4′-biphenylene;
formula V is about 1 to about 3 mole % of the total of formula I %;
the molar ratio of formula I to the sum of formula II and formula V is about 1:1; and the total amount of the repeat unit (formula I+formula V) plus the repeat unit (formula I+formula II) is from about 25 to about 35 mole % of the LCP;
the amount of formula IIIA is from about 45 to about 55 mole % of the LCP; and
the amount of formula IIIB is from about 15 to about 25 mole % of the LCP.
2. The film or sheet of claim 1 wherein the total amount of the repeat unit (formula I+formula V) plus the repeat unit (formula I+formula II) is from about 28 to about 32 mole % of the LCP.
3. The film or sheet of claim 1 wherein the amount of formula IIIA is from about 48 to about 52 mole % of said LCP.
4. The film or sheet of claim 1 wherein the amount of formula IIIB is from about 18 to about 22 mole % of the LCP.
5. The film or sheet of claim 1 wherein the sheet or film has contact or read-through clarity.
6. The film or sheet of claim 1 wherein the barrier resin is the LCP; the total amount of the repeat unit (formula I+formula V) plus the repeat unit (formula I+formula II) is from about 28 to about 32 mole % of the LCP; the amount of (formula IIIA) is from about 48 to about 52 mole % of the LCP; and the amount of (formula IIIB) is from about 18 to about 22 mole % of the LCP.
7. The film or sheet of claim 6 wherein the sheet or film has contact or read-through clarity.
8. The film or sheet of claim 6 wherein the barrier resin comprises repeat units derived from about 2.3 to about 2.9% 4,4′-biphenol, about 41.1 to about 40.8% 4-hydroxy-benzoic acid, about 22.4 to about 22.2% 6-hydroxy-2-naphthalene dicarboxylic acid, and about 34.3 to about 34% poly(ethylene terephthalate), all by weight of the resin.
9. The film or sheet of claim 8 wherein the barrier resin consisting essentially of the repeat units and the sheet or film has contact or read-through clarity.
10. The film or sheet of claim 1 having adhered or bonded thereto a substrate wherein
the film or sheet is present in one or more layers of a multilayer structure; and
the substrate is (1) paper, paperboard, aluminum foil, fabric, non-woven material, or combinations of two or more thereof or (2) a film substrate and the film substrate (cast or oriented), which is poly(vinylidene fluoride), nylon, polypropylene, poly(ethylene terephthalate), poly(ethylene naphthalate) , polylactic acid, polyglycolic acid, poly(metaxyxyleneadipamide), cellulosic, polyvinylchloride, poly(ethylene vinyl acetate), polyvinyl alcohol, polystyrene, polycarbonate, polyimide, polyketone, copolymers with tetrafluoroethylene, polyethylene, polypropylene copolymer, polyvinylidene copolymer, polyethylene copolymer, acid copolymer, ionomer of the acid copolymer, or combinations of two or more thereof or both (1) and (2).
11. The film or sheet of claim 10 wherein the barrier resin is the LCP and the barrier resin comprises repeat units derived from about 2.3 to about 2.9% 4,4′-biphenol, about 41.1 to about 40.8% 4-hydroxy-benzoic acid, about 22.4 to about 22.2% 6-hydroxy-2-naphthalene dicarboxylic acid, and about 34.3 to about 34% poly(ethylene terephthalate), all by weight.
12. The film or sheet of claim 11 wherein the multilayer structure is in direct contact with the substrate and the sheet or film has contact or read-through clarity.
13. The film or sheet of claim 10 comprising an outermost structural layer, an inner barrier layer, and an optional innermost seal layer wherein the baffler layer comprises the film or sheet which comprises repeat units derived from about 2.3 to about 2.9% 4,4′-biphenol, about 41.1 to about 40.8% 4-hydroxy-benzoic acid, about 22.4 to about 22.2% 6-hydroxy-2-naphthalene dicarboxylic acid, and about 34.3 to about 34% poly(ethylene terephthalate), all by weight.
14. The film or sheet of claim 13 wherein the sheet or film has contact or read-through clarity and the substrate is paper, paperboard, aluminum foil, fabric, non-woven material, oriented film, cellulosic film or combinations of two or more thereof.