Magnetic disk drive having a surface coating on a magnetic disk
View Patent ↗A magnetic disk is produced with improved yield by forming a DLC protective film by a d.c. magnetron sputtering process conducted in a sputtering atmosphere containing oxygen. The magnetic disk carries a lubricating film on the DLC film wherein a fluorocarbon resin constituting the lubricating film contains photocrosslinking groups. A lubricating film having non-polar end groups is also disclosed.
1. A fluorocarbon resin composition, comprising: a resin skeleton; and
a tri-organosilyl group not causing hydrolysis or dehydration condensation, represented by a general formula
wherein R 1 , R 2 , R 3 represent independently or commonly any of an alkyl group, an aryl group and an aralkyl group, including those substituted with halogen or nitrogen, as an endcap group of said resin skeleton.
2. A fluorocarbon resin composition as claimed in claim 1 , wherein at least one of said functional groups R 1 , R 2 and R 3 is selected from the group consisting of an alkenyl group having 2-20 carbon atoms, an aryl group having 6-30 carbon atoms, and an aralkyl group having 7-30 carbon atoms.
3. A fluorocarbon resin composition as claimed in claim 1 , wherein said functional groups R 1 , R 2 and R 3 are selected from the group consisting of a phenyl group and a benzyl group.
4. A method of forming a fluorocarbon resin having an endcap group represented by a formula
(R 1 , R 2 , R 3 represent independently or commonly any of an alkyl group, an aryl group and an aralkyl group, including those substituted with halogen or nitrogen),
said method comprising the step of:
silylzing a fluorocarbon resin having OH at an end gap group by any of chlorosilane, silylamine and silylamide.
5. A method as claimed in claim 4 , wherein said step of silylzing comprises the steps of: dissolving a fluorocarbon resin having a hydroxyl endcap group and an amine catalyst into a solvent having a C—F bond and further one of a C—H bond and a C—Cl bond to form a solution; and adding tri-organo chlorosilane further to said solution.