Composite film
View Patent ↗A composite film useful for image supporting media, including: a first layer containing a thermoplastic polymer and optionally containing a whitening agent; a second layer containing a thermoplastic polymer and a whitening agent; a third layer containing a thermoplastic polymer and a cavitating agent, wherein the third layer is a cavitated layer; optionally a fourth layer containing a thermoplastic polymer and optionally a whitening agent; and optionally a fifth layer containing a thermoplastic polymer and optionally a whitening agent; wherein the second layer is between the first layer and the third layer, the third layer is between the second layer and the optional fourth layer, and the optional fourth layer is between the third layer and the optional fifth layer. Embodiments may have the advantage(s) of improved outer surface characteristics, compressibility, thermal insulation, whiteness, and/or stiffness.
1. A composite film useful as an image-support film, comprising:
a first layer including a thermoplastic polymer;
a second layer comprising a thermoplastic polymer and at least about 25 wt % of a whitening agent, based upon the total weight of the second layer;
a third layer comprising a thermoplastic polymer and a cavitating agent, wherein the third layer is a cavitated layer; and
a fourth layer comprising a thermoplastic polymer and a whitening agent,
wherein the second layer is between the first layer and the third layer, and the fourth layer is on a side of the third layer opposite from the second layer.
2. The composite film of claim 1 , further comprising a fifth layer on a side of the fourth layer opposite the third layer, wherein the fifth layer comprises a thermoplastic polymer.
3. The composite film of claim 2 , wherein the fifth layer optionally further comprises a whitening agent, and the amount of the whitening agent in the fourth layer is greater than the amount of the whitening agent in the fifth layer.
4. The composite film of claim 3 , wherein the fifth layer further comprises a whitening agent and the amount of the whitening agent in the fourth layer is more than 10 times greater than the amount of the whitening agent in the fifth layer.
5. The composite film of claim 2 , wherein the fifth layer is free of any whitening agent.
6. The composite film of claim 1 , wherein the fourth layer comprises a whitening agent in an amount of up to 35 wt %, based on the total weight of the fourth layer.
7. The composite film of claim 1 , wherein the fourth layer comprises a whitening agent and the amount of the whitening agent in the second layer is greater than the amount of the whitening agent in the fourth layer.
8. The composite film of claim 1 , wherein the third layer has a density of from 0.35 to 0.55 g/cm 3 .
9. The composite film of claim 1 , wherein the third layer has a void percentage of from 40 to 60%, based upon the bulk volume of the third layer.
10. The composite film of claim 1 , wherein an outer surface of the first layer has a 45-degree gloss of from 5 to 70%, as measured according to ASTM D 2457.
11. The composite film of claim 1 , wherein at least one of the second layer and the fourth layer has a thickness of from 1.25 to 7.75 μm.
12. The composite film of claim 11 , wherein each of the second layer and the fourth layer independently has a thickness of from 1.25 to 7.75 μm.
13. The composite film of claim 1 , wherein the thermoplastic polymer of the third layer comprises a polypropylene.
14. The composite film of claim 1 , wherein the whitening agent of the second layer comprises titanium dioxide.
15. The composite film of claim 1 , wherein the cavitating agent of the third layer comprises at least one of polybutylene terephthalate and calcium carbonate.
16. The composite film of claim 1 , wherein the first layer comprises from about 0.02 wt % to about 0.20 wt % of a whitening agent, based upon the total weight of the first layer.
17. The composite film of claim 1 , wherein the second layer comprises at least about 30 wt % of whitening agent, based upon the total weight of the second layer.
18. The composite film of claim 1 , wherein the second layer comprises at least about 40 wt % of whitening agent, based upon the total weight of the second layer.
19. The composite film of claim 1 , wherein the first layer is free of any whitening agent.
20. The composite film of claim 1 , wherein the polymer of the second layer consists of polypropylene.
21. The composite film of claim 1 , wherein the second layer may include at least 10 times the amount of whitening agent as in the first layer, based upon the total weight of the second layer.
22. A dye-receiving element, comprising:
a base and a dye-image receiving layer, the base comprising:
a composite film and a support, wherein the dye-image receiving layer is on the composite film side of the base, and the composite film comprises:
a first layer comprising a thermoplastic polymer and from about 0.02 wt % to about 0.20 wt % of a whitening agent, based upon the total weight of the first layer;
a second layer comprising a thermoplastic polymer and at least about 25 wt % of a whitening agent, based upon the total weight of the second layer; and
a third layer comprising a thermoplastic polymer and a cavitating agent, wherein the third layer is a cavitated layer;
wherein the second layer is between the first layer and the third layer;
further comprising a fourth layer on a side of the third layer opposite from the second layer, wherein the fourth layer comprises a thermoplastic polymer.
23. The composite film of claim 22 , further comprising a fifth layer on a side of the fourth layer opposite the third layer, wherein the fifth layer comprises a thermoplastic polymer.
24. A dye-receiving element, comprising:
a base and a dye image-receiving layer, the base comprising:
a composite film and a support, wherein the dye image-receiving layer is on the composite film side of the base, and the composite film comprises:
a first layer comprising a thermoplastic polymer;
a second layer comprising a thermoplastic polymer and at least about 25 wt % of a whitening agent, based upon the total weight of the second layer; and
a third layer comprising a thermoplastic polymer and a cavitating agent, wherein the third layer is a cavitated layer;
wherein the second layer is between the first layer and the third layer; and
wherein the first layer is free of any whitening agent;
further comprising: a fourth layer on a side of the third layer opposite from the second layer, wherein the fourth layer comprises a thermoplastic polymer.
25. The dye-receiving element film of claim 24 , further comprising:
a fifth layer on a side of the fourth layer opposite the third layer, wherein the fifth layer comprises a thermoplastic polymer.
26. The dye-receiving element of claim 25 , wherein the fifth layer is free of any whitening agent.
27. A label structure, comprising a composite film and an adhesive layer, wherein the composite film comprises:
a first layer comprising a thermoplastic polymer;
a second layer comprising a thermoplastic polymer and at least about 25 wt % of a whitening agent, based upon the total weight of the second layer;
a third layer comprising a thermoplastic polymer and a cavitating agent, wherein the third layer is a cavitated layer;
a fourth layer comprising a thermoplastic polymer; and
a fifth layer comprising a thermoplastic polymer,
wherein the second layer is between the first layer and the third layer, the third layer is between the second layer and the fourth layer, and the fourth layer is between the third layer and the fifth layer, and
wherein the first layer is free of any whitening agent.
28. The label structure of claim 27 , wherein the adhesive layer comprises a pressure-sensitive adhesive.
29. The label structure of claim 27 , wherein the adhesive layer comprises a cold glue adhesive.
30. The label structure of claim 27 , wherein the adhesive layer comprises a hot melt adhesive.
31. The label structure of claim 27 , further comprising:
a dye image-receiving layer, such that the label structure comprises the dye image-receiving layer, the composite film, and the adhesive layer.
32. The label structure of claim 27 , further comprising a liner on a side of the adhesive layer opposite the composite film.
33. The label structure of claim 27 , further comprising a fourth layer on a side of the third layer opposite the second layer.
34. The label structure of claim 27 , wherein the fourth layer further comprises at least 15 wt % whitening agent.
35. The composite film of claim 27 , wherein the second layer may include at least 10 times the amount of whitening agent as in the first layer, based upon the total weight of the second layer.