IP Library Granted Patent US 7,795,375
Granted Patent B2
US 7,795,375 · App. 11/483,566 · Granted Sep 14, 2010

Fluoropolyether compound

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Quick Facts
Patent No.
US 7,795,375
App. No.
11/483,566
Granted
Sep 14, 2010
Kind
B2
Abstract

It is to provide a compound which has a low vapor pressure and low viscosity, which is less problematic in deterioration during its use and which is useful as e.g. a lubricant, a surface modifier or a surfactant. A fluoropolyether compound represented by the formula (X—) x Y(—Z) z , wherein X is a group represented by the formula HO—(CH 2 CH 2 O)a.(CH 2 CH(OH)CH 2 O) b —(CH 2 ) c —CF 2 O(CF 2 CF 2 O) d — (wherein “a” is an integer of from 0 to 100, b is an integer of from 0 to 100, c is an integer of from 1 to 100, and d is an integer of from 1 to 200), Z is a group represented by the formula R F O(CF 2 CF 2 O) g — (wherein R F is e.g. a C 1-20 perfluoroalkyl group having an etheric oxygen atom inserted between carbon-carbon atoms, and g is an integer of from 3 to 200), Y is e.g. a (x+z) valent perfluorinated saturated hydrocarbon group, x is an integer of at least 2, z is an integer of at least 0, and (x+z) is an integer of from 3 to 20.

Claims (53)

1. A fluoropolyether compound of the following formula (A):

(X—) x Y(—Z) z   (A)

wherein

X is a group of formula (X)

HO—(CH 2 CH 2 O) a —(CH 2 CH(OH)CH 2 O) b —(CH 2 ) c —CF 2 O(CF 2 CF 2 O) d —  (X)

wherein

a is an integer of from 0 to 100,

b is an integer of from 0 to 100,

c is an integer of from 1 to 100, and

d is an integer of from 1 to 200;

Z is a group of formula (Z):

R F O(CF 2 CF 2 O) g —  (Z)

wherein

R F is a C 1-20 perfluoroalkyl group or a group having an etheric oxygen atom inserted between carbon-carbon atoms of such a perfluoroalkyl group with the proviso that the group has no —OCF 2 O— structure, and

g is an integer of from 3 to 200,

Y is a (x+z) valent perfluorinated saturated hydrocarbon group, or a (x+z) valent perfluorinated saturated hydrocarbon group having an etheric oxygen atom inserted between carbon-carbon atoms, having no —OCF 2 O— structure;

wherein

x is an integer of at least 2,

z is an integer of at least 0, and

(x+z) is an integer of from 3 to 20, provided that when x is at least 2, groups represented by the formula (X) may be the same or different, and when z is at least 2, groups represented by the formula (Z) may be the same or different.

2. The compound according to claim 1 , wherein (X) is any group selected from the group consisting of

HOCH 2 CF 2 O(CF 2 CF 2 O) d —  (X-1)

HOCH 2 CH(OH)CH 2 OCH 2 CF 2 O(CF 2 CF 2 O) d —  (X-2)

HOCH 2 CH 2 CF 2 O(CF 2 CF 2 O) d —  (X-3)

HOCH 2 CH 2 OCH 2 CF 2 O(CF 2 CF 2 O) d —  (X-4)

wherein

d is an integer of from 1 to 200.

3. The compound according to claim 2 , wherein the compound of formula (A) is a compound of formula (A-1) or (A-2):

(X 10 —) 3 Y 3   (A-1)

(X 10 —) 4 Y 4   (A-2)

wherein

X 10 is any group selected from the groups consisting of (X-1) to (X-4),

Y 3 is a trivalent perfluoroalkyl group, and

Y 4 is a tetravalent perfluoroalkyl group.

4. The compound according to claim 2 , wherein the compound of formula (A) is a compound of formula (A-3):

(X 10 —) 2 Y 3 —Z   (A-3)

wherein

X 10 is any group selected from the group consisting of (X-1) to (X-4), and

Y 3 is a trivalent perfluoroalkyl group.

5. The fluoropolyether compound according to claim 1 , wherein the compound of formula (A) has a molecular weight of from 500 to 1,000,000 as measured by gel permeation chromatography and has a molecular weight distribution of from 1.0 to 1.5.

6. A solution composition, comprising:

the fluoropolyether compound as defined in claim 1 ; and

an organic solvent.

7. The solution composition according to claim 6 , wherein

a concentration of the fluoropolyether compound is from 0.01 to 50 mass %.

8. A lubricant, a surface modifier or a surfactant, comprising the fluoropolyether compound as defined in claim 1 .

9. The compound according to claim 3 , wherein the compound of formula (A) is a compound according to formula (A-1), wherein

Y 3 is —CF 2 —CF—CF 2 — or CF(CF 2 —) 3 .

10. The compound according to claim 3 , wherein the compound of formula (A) is a compound according to formula (A-2), wherein

Y 4 is C(CF 2 —) 4 .

11. The compound according to claim 4 , wherein

Y 3 is —CF 2 —CF—CF 2 — or CF(CF 2 —) 3 .

12. The solution composition according to claim 6 , wherein the solvent is a perfluoroamine or a perfluoroalkane.

Assignments (2)
CHANGE OF NAME Recorded Aug 7, 2018
From: ASAHI GLASS COMPANY, LIMITED
To: AGC INC.
Reel/Frame 046730/0786 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 11, 2006
From: SHIRAKAWA, DAISUKE; OHARU, KAZUYA; OKAZOE, TAKASHI
To: ASAHI GLASS COMPANY, LIMITED
Reel/Frame 018100/0598 →